Abstract
Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.
| Original language | English |
|---|---|
| Pages (from-to) | 990-992 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 10 |
| Early online date | 17 Dec 2012 |
| DOIs | |
| Publication status | Published - 1 Feb 2013 |
Fingerprint
Dive into the research topics of 'A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework'. Together they form a unique fingerprint.Cite this
- APA
- Standard
- Harvard
- Vancouver
- Author
- BIBTEX
- RIS