A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework

A.D. Burrows, S.O. Hunter, M.F. Mahon, C. Richardson

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.
Original languageEnglish
Pages (from-to)990-992
Number of pages3
JournalChemical Communications
Volume49
Issue number10
Early online date17 Dec 2012
DOIs
Publication statusPublished - 1 Feb 2013

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