A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework

A.D. Burrows; S.O. Hunter; M.F. Mahon; C. Richardson

doi:10.1039/c2cc38176a

A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework

A.D. Burrows, S.O. Hunter, M.F. Mahon, C. Richardson

University of Wollongong

Research output: Contribution to journal › Article › peer-review

25 Citations (SciVal)

Abstract

Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained.

Original language	English
Pages (from-to)	990-992
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	10
Early online date	17 Dec 2012
DOIs	https://doi.org/10.1039/c2cc38176a
Publication status	Published - 1 Feb 2013

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abstract = "Direct heating of a metal-organic framework provides a simple, controllable way of effecting a covalent post-synthetic modification. Herein we report that an allyloxy-tagged zinc metal-organic framework undergoes a thermally-promoted aromatic Claisen rearrangement through which the framework connectivity and porosity are maintained. ",

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A reagentless thermal post-synthetic rearrangement of an allyloxy-tagged metal-organic framework

Abstract

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