A quick and selective rhodamine based “smart probe” for “signal-on” optical detection of Cu2+ and Al3+ in water, cell imaging, computational studies and solid state analysis

Abhishek Rai, Alok Kumar Singh, Kamini Tripathi, Avinash Kumar Sonkar, Brijesh Singh Chauhan, S. Srikrishna, Tony D. James, Lallan Mishra

Research output: Contribution to journalArticle

23 Citations (Scopus)
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Abstract

A novel rhodamine hydrazone 1 has been synthesized by the condensation of rhodamine B hydrazide with allylsalicylaldehyde and has been fully characterized using various physicochemical techniques including single crystal XRD. Probe 1 can detect Cu2+ and Al3+ ions in aqueous media and displays a turn-on response in absorbance with a high degree of selectivity amongst other common interfering analytes. Al3+ ions lead to fluorescence enhancementby the opening of the spirolactum ring resulting in chelation enhanced fluorescence. DFT and TDDFT calculations support the experimental results. The 1-Al3+ ensemble acts as secondary sensor for pyrophosphate anion due to metal ion induced decomplexation resulting in a low detection limit. Probe 1 can be utilized for bio imaging and displays morphological transformations from crystalline to amorphous state with associated color changes due to mechanical switching. In the solid state, probe 1 displays distinct color changes with emission at different wavelengths in particular Al3+ and Hg2+result in a red shift of the CIE-diagram. While the band gap of probe 1can be tuned from 2.08 eV to 1.60 eV.Probe 1 meets many real-world-challenges in that it is prepared using simple synthetic methods, produces fast and distinct response towards multiple-ions, observed by the “naked eye” in solution and on a TLC plate, and can be exploited for binary data storage.
Original languageEnglish
Pages (from-to)95-105
Number of pages11
JournalSensors and Actuators B: Chemical
Volume266
Early online date5 Feb 2018
DOIs
Publication statusPublished - 1 Aug 2018

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Keywords

  • Chemosensor
  • DFT
  • Photoluminescence
  • Real sample analysis
  • Rhodamine

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

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