A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO 2 adsorption

John P S Mowat; Valerie R. Seymour; John M. Griffin; Stephen P. Thompson; Alexandra M Z Slawin; David Fairen-Jimenez; Tina Düren; Sharon E. Ashbrook; Paul A. Wright

doi:10.1039/c1dt11729g

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO ₂ adsorption

John P S Mowat
, Valerie R. Seymour
, John M. Griffin
, Stephen P. Thompson
, Alexandra M Z Slawin
, David Fairen-Jimenez
, Tina Düren
, Sharon E. Ashbrook
, Paul A. Wright

Department of Chemical Engineering

University of St Andrews
University of Edinburgh
Rutherford Appleton Laboratory
Diamond Light Source Ltd

Research output: Contribution to journal › Article › peer-review

101 Citations (SciVal)

Abstract

The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO ₂ adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO ₂.

Original language	English
Pages (from-to)	3937-3941
Number of pages	5
Journal	Dalton Transactions
Volume	41
Issue number	14
Early online date	15 Nov 2011
DOIs	https://doi.org/10.1039/c1dt11729g
Publication status	Published - 14 Apr 2012

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c1dt11729g

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abstract = "The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO 2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO 2.",

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AU - Mowat, John P S

AU - Seymour, Valerie R.

AU - Griffin, John M.

AU - Thompson, Stephen P.

AU - Slawin, Alexandra M Z

AU - Fairen-Jimenez, David

AU - Düren, Tina

AU - Ashbrook, Sharon E.

AU - Wright, Paul A.

PY - 2012/4/14

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N2 - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO 2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO 2.

AB - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO 2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO 2.

UR - https://www.scopus.com/pages/publications/84858721908

U2 - 10.1039/c1dt11729g

DO - 10.1039/c1dt11729g

M3 - Article

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO ₂ adsorption

Abstract

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