A Novel Electrochemical Sensor Based on Printex L6 Carbon Black Carrying CuO/Cu2O Nanoparticles for Propylparaben Determination

Lorena A. Goulart; Thaís T. Guaraldo; Marcos R.V. Lanza

doi:10.1002/elan.201800549

A Novel Electrochemical Sensor Based on Printex L6 Carbon Black Carrying CuO/Cu₂O Nanoparticles for Propylparaben Determination

Lorena A. Goulart, Thaís T. Guaraldo, Marcos R.V. Lanza

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

24 Citations (SciVal)

Abstract

The paper reports the development of a new sensor based on Printex L6 (CPL6) carbon black modified with copper oxides (CuO/Cu₂O) nanoparticles and its application towards the determination of Propylparaben (PP). In fact, it is the first report of its kind in the literature. The sensor was produced through the dispersion of CPL6 in dimethylformamide on glassy carbon electrode surface followed by CuO/Cu₂O electrodeposition. The conditions of electrodeposition investigated included time and solution concentration of Cu (II). Morphological, structural and electrochemical characterizations of the sensor were performed. Under optimal conditions, wide linear range (1.0 to 35.0 μmol L⁻¹) was obtained in the detection of PP. The detection limit obtained was 0.46 μmol L⁻¹ (S/N=3). The CuO/Cu₂O-CPL6/GCE sensor was found to be as sensitive as the high performance liquid chromatography in the determination of PP in both cosmetic and river water samples, in addition to being reproducible and stable.

Original language	English
Pages (from-to)	2967-2976
Number of pages	10
Journal	Electroanalysis
Volume	30
Issue number	12
Early online date	22 Oct 2018
DOIs	https://doi.org/10.1002/elan.201800549
Publication status	Published - 31 Dec 2018

Bibliographical note

Funding Information:
The authors gratefully acknowledge the financial support received from CNPq (grants 301492/2013-1 and 465571/ 2014-0 (INCT-DATREM)) and São Paulo Research Foundation (FAPESP) (grants #2016/01937-4, #2014/ 11861-0, #2014/50945-4, #2016/08760-2 and #2017/10118-0). This study was financed in part by the Coordenac¸ão de Aperfeic¸oamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001. Thanks to Dr. Daniel F. Segura for art work support.

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

The authors gratefully acknowledge the financial support received from CNPq (grants 301492/2013-1 and 465571/ 2014-0 (INCT-DATREM)) and São Paulo Research Foundation (FAPESP) (grants #2016/01937-4, #2014/ 11861-0, #2014/50945-4, #2016/08760-2 and #2017/10118-0). This study was financed in part by the Coordenac¸ão de Aperfeic¸oamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001. Thanks to Dr. Daniel F. Segura for art work support.

Keywords

Carbon black
Copper oxide nanoparticles
Printex L6 carbon
Propylparaben
Sensor

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

Access to Document

10.1002/elan.201800549

Cite this

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title = "A Novel Electrochemical Sensor Based on Printex L6 Carbon Black Carrying CuO/Cu2O Nanoparticles for Propylparaben Determination",

abstract = "The paper reports the development of a new sensor based on Printex L6 (CPL6) carbon black modified with copper oxides (CuO/Cu2O) nanoparticles and its application towards the determination of Propylparaben (PP). In fact, it is the first report of its kind in the literature. The sensor was produced through the dispersion of CPL6 in dimethylformamide on glassy carbon electrode surface followed by CuO/Cu2O electrodeposition. The conditions of electrodeposition investigated included time and solution concentration of Cu (II). Morphological, structural and electrochemical characterizations of the sensor were performed. Under optimal conditions, wide linear range (1.0 to 35.0 μmol L−1) was obtained in the detection of PP. The detection limit obtained was 0.46 μmol L−1 (S/N=3). The CuO/Cu2O-CPL6/GCE sensor was found to be as sensitive as the high performance liquid chromatography in the determination of PP in both cosmetic and river water samples, in addition to being reproducible and stable.",

keywords = "Carbon black, Copper oxide nanoparticles, Printex L6 carbon, Propylparaben, Sensor",

author = "Goulart, {Lorena A.} and Guaraldo, {Tha{\'i}s T.} and Lanza, {Marcos R.V.}",

note = "Funding Information: The authors gratefully acknowledge the financial support received from CNPq (grants 301492/2013-1 and 465571/ 2014-0 (INCT-DATREM)) and S{\~a}o Paulo Research Foundation (FAPESP) (grants #2016/01937-4, #2014/ 11861-0, #2014/50945-4, #2016/08760-2 and #2017/10118-0). This study was financed in part by the Coordenac¸{\~a}o de Aperfeic¸oamento de Pessoal de N{\'i}vel Superior – Brasil (CAPES) – Finance Code 001. Thanks to Dr. Daniel F. Segura for art work support. Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Lanza, Marcos R.V.

N1 - Funding Information: The authors gratefully acknowledge the financial support received from CNPq (grants 301492/2013-1 and 465571/ 2014-0 (INCT-DATREM)) and São Paulo Research Foundation (FAPESP) (grants #2016/01937-4, #2014/ 11861-0, #2014/50945-4, #2016/08760-2 and #2017/10118-0). This study was financed in part by the Coordenac¸ão de Aperfeic¸oamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001. Thanks to Dr. Daniel F. Segura for art work support. Publisher Copyright: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/12/31

Y1 - 2018/12/31

N2 - The paper reports the development of a new sensor based on Printex L6 (CPL6) carbon black modified with copper oxides (CuO/Cu2O) nanoparticles and its application towards the determination of Propylparaben (PP). In fact, it is the first report of its kind in the literature. The sensor was produced through the dispersion of CPL6 in dimethylformamide on glassy carbon electrode surface followed by CuO/Cu2O electrodeposition. The conditions of electrodeposition investigated included time and solution concentration of Cu (II). Morphological, structural and electrochemical characterizations of the sensor were performed. Under optimal conditions, wide linear range (1.0 to 35.0 μmol L−1) was obtained in the detection of PP. The detection limit obtained was 0.46 μmol L−1 (S/N=3). The CuO/Cu2O-CPL6/GCE sensor was found to be as sensitive as the high performance liquid chromatography in the determination of PP in both cosmetic and river water samples, in addition to being reproducible and stable.

AB - The paper reports the development of a new sensor based on Printex L6 (CPL6) carbon black modified with copper oxides (CuO/Cu2O) nanoparticles and its application towards the determination of Propylparaben (PP). In fact, it is the first report of its kind in the literature. The sensor was produced through the dispersion of CPL6 in dimethylformamide on glassy carbon electrode surface followed by CuO/Cu2O electrodeposition. The conditions of electrodeposition investigated included time and solution concentration of Cu (II). Morphological, structural and electrochemical characterizations of the sensor were performed. Under optimal conditions, wide linear range (1.0 to 35.0 μmol L−1) was obtained in the detection of PP. The detection limit obtained was 0.46 μmol L−1 (S/N=3). The CuO/Cu2O-CPL6/GCE sensor was found to be as sensitive as the high performance liquid chromatography in the determination of PP in both cosmetic and river water samples, in addition to being reproducible and stable.

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KW - Copper oxide nanoparticles

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