A new type of luminescent alkynyl Au4Cu2 cluster

H de la Riva; M Nieuwhuyzen; C M Fierro; P R Raithby; L Male; M C Lagunas

doi:10.1021/ic051503e

A new type of luminescent alkynyl Au4Cu2 cluster

H de la Riva, M Nieuwhuyzen, C M Fierro, P R Raithby, L Male, M C Lagunas

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

74 Citations (SciVal)

Abstract

Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.

Original language	English
Pages (from-to)	1418-1420
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	4
DOIs	https://doi.org/10.1021/ic051503e
Publication status	Published - 2006

Bibliographical note

ID number: ISI:000235480700005

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10.1021/ic051503e

Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY
Raithby, P. (PI)
Engineering and Physical Sciences Research Council
1/12/06 → 30/11/11
Project: Research council

Cite this

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title = "A new type of luminescent alkynyl Au4Cu2 cluster",

abstract = "Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.",

author = "{de la Riva}, H and M Nieuwhuyzen and Fierro, {C M} and Raithby, {P R} and L Male and Lagunas, {M C}",

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pages = "1418--1420",

journal = "Inorganic Chemistry",

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T1 - A new type of luminescent alkynyl Au4Cu2 cluster

AU - de la Riva, H

AU - Nieuwhuyzen, M

AU - Fierro, C M

AU - Raithby, P R

AU - Male, L

AU - Lagunas, M C

N1 - ID number: ISI:000235480700005

PY - 2006

Y1 - 2006

N2 - Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.

AB - Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.

U2 - 10.1021/ic051503e

DO - 10.1021/ic051503e

M3 - Article

SN - 0020-1669

VL - 45

SP - 1418

EP - 1420

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

A new type of luminescent alkynyl Au4Cu2 cluster

Abstract

Bibliographical note

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Projects

Senior Fellowship - TIME RESOLVED CRYSTALLOGRAPHY

Cite this