A new type of luminescent alkynyl Au4Cu2 cluster

H de la Riva, M Nieuwhuyzen, C M Fierro, P R Raithby, L Male, M C Lagunas

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Abstract

Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.
Original languageEnglish
Pages (from-to)1418-1420
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number4
DOIs
Publication statusPublished - 2006

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    de la Riva, H., Nieuwhuyzen, M., Fierro, C. M., Raithby, P. R., Male, L., & Lagunas, M. C. (2006). A new type of luminescent alkynyl Au4Cu2 cluster. Inorganic Chemistry, 45(4), 1418-1420. https://doi.org/10.1021/ic051503e