A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)

J K Bjernemose; R P Davies; A P S Jurd; M G Martinelli; P R Raithby; A J P White

doi:10.1039/b412488j

A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)

J K Bjernemose, R P Davies, A P S Jurd, M G Martinelli, P R Raithby, A J P White

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

Original language	English
Pages (from-to)	3169-3170
Number of pages	2
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b412488j
Publication status	Published - 2004

Bibliographical note

ID number: ISI:000224462300004

Access to Document

10.1039/b412488j

Cite this

@article{b648b1af09f04a84920846c11ca8c9c9,

title = "A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)",

abstract = "A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.",

author = "Bjernemose, \{J K\} and Davies, \{R P\} and Jurd, \{A P S\} and Martinelli, \{M G\} and Raithby, \{P R\} and White, \{A J P\}",

note = "ID number: ISI:000224462300004",

year = "2004",

doi = "10.1039/b412488j",

language = "English",

pages = "3169--3170",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)

AU - Bjernemose, J K

AU - Davies, R P

AU - Jurd, A P S

AU - Martinelli, M G

AU - Raithby, P R

AU - White, A J P

N1 - ID number: ISI:000224462300004

PY - 2004

Y1 - 2004

N2 - A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

AB - A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

UR - https://www.scopus.com/pages/publications/9244265494

U2 - 10.1039/b412488j

DO - 10.1039/b412488j

M3 - Article

SN - 1477-9226

SP - 3169

EP - 3170

JO - Dalton Transactions

JF - Dalton Transactions

IS - 20

ER -

A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this