A New Method for the Synthesis of Heterometallic Complexes: Syntheses and Structures of [(PhCH2CH2NLi)3Sb(thf)]2 and [Sb3(cyN)4(NMe2)2]Li

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Moira‐Ann ‐A Rennie; Christopher A. Russell; Dominic S. Wright

doi:10.1002/anie.199412771

A New Method for the Synthesis of Heterometallic Complexes: Syntheses and Structures of [(PhCH₂CH₂NLi)₃Sb(thf)]₂ and [Sb₃(cyN)₄(NMe₂)₂]Li

Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Moira‐Ann ‐A Rennie, Christopher A. Russell, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Successive metalation of primary amines, first with nBuLi and then with Sb(NMe₂)₃, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH₂)₂N(H)Li]_n and ionic Li[Sb(cyNH)₄] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.)

Original language	English
Pages (from-to)	1277-1279
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	12
DOIs	https://doi.org/10.1002/anie.199412771
Publication status	Published - 6 Jun 1994

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199412771

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A New Method for the Synthesis of Heterometallic Complexes: Syntheses and Structures of [(PhCH₂CH₂NLi)₃Sb(thf)]₂ and [Sb₃(cyN)₄(NMe₂)₂]Li. / Edwards, Andrew J.; Paver, Michael A.; Raithby, Paul R. et al.
In: Angewandte Chemie International Edition in English, Vol. 33, No. 12, 06.06.1994, p. 1277-1279.

Research output: Contribution to journal › Article › peer-review

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abstract = "Successive metalation of primary amines, first with nBuLi and then with Sb(NMe2)3, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH2)2N(H)Li]n and ionic Li[Sb(cyNH)4] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.)",

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AU - Edwards, Andrew J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Rennie, Moira‐Ann ‐A

AU - Russell, Christopher A.

AU - Wright, Dominic S.

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AB - Successive metalation of primary amines, first with nBuLi and then with Sb(NMe2)3, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH2)2N(H)Li]n and ionic Li[Sb(cyNH)4] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.)

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A New Method for the Synthesis of Heterometallic Complexes: Syntheses and Structures of [(PhCH₂CH₂NLi)₃Sb(thf)]₂ and [Sb₃(cyN)₄(NMe₂)₂]Li

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