TY - JOUR
T1 - A New Method for the Synthesis of Heterometallic Complexes
T2 - Syntheses and Structures of [(PhCH2CH2NLi)3Sb(thf)]2 and [Sb3(cyN)4(NMe2)2]Li
AU - Edwards, Andrew J.
AU - Paver, Michael A.
AU - Raithby, Paul R.
AU - Rennie, Moira‐Ann ‐A
AU - Russell, Christopher A.
AU - Wright, Dominic S.
PY - 1994/6/6
Y1 - 1994/6/6
N2 - Successive metalation of primary amines, first with nBuLi and then with Sb(NMe2)3, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH2)2N(H)Li]n and ionic Li[Sb(cyNH)4] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.)
AB - Successive metalation of primary amines, first with nBuLi and then with Sb(NMe2)3, has enabled the preparation of the heterometallic complexes 1 and 2. Neutra [Ph(CH2)2N(H)Li]n and ionic Li[Sb(cyNH)4] occur as the intermediates in the formation of 1 and 2, respectively. (Formula Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33750247652&partnerID=8YFLogxK
U2 - 10.1002/anie.199412771
DO - 10.1002/anie.199412771
M3 - Article
AN - SCOPUS:33750247652
SN - 0570-0833
VL - 33
SP - 1277
EP - 1279
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -