A mononuclear indium(I) carbene analogue

Michael S. Hill; Peter B. Hitchcock

doi:10.1039/b406017b

A mononuclear indium(I) carbene analogue

Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journal › Article › peer-review

120 Citations (SciVal)

Abstract

The 'one pot' reaction between K[N(SiMe₃)₂], InI and the β-diimine ligand precursor [H(NDippCMe)₂CH] (Dipp = C ₆H₃Prⁱ₂-2,6) gave [In{(NDippCMe)₂CH}] 1, the first example of a two-coordinate, neutral, In(1) singlet 'carbene analogue'.

Original language	English
Pages (from-to)	1818-1819
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/b406017b
Publication status	Published - 21 Aug 2004

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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@article{e40b1235739f4386b90b0bb2e093c718,

title = "A mononuclear indium(I) carbene analogue",

abstract = "The 'one pot' reaction between K[N(SiMe3)2], InI and the β-diimine ligand precursor [H(NDippCMe)2CH] (Dipp = C 6H3Pri2-2,6) gave [In\{(NDippCMe)2CH\}] 1, the first example of a two-coordinate, neutral, In(1) singlet 'carbene analogue'.",

author = "Hill, \{Michael S.\} and Hitchcock, \{Peter B.\}",

year = "2004",

month = aug,

day = "21",

doi = "10.1039/b406017b",

language = "English",

pages = "1818--1819",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "16",

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T1 - A mononuclear indium(I) carbene analogue

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

PY - 2004/8/21

Y1 - 2004/8/21

N2 - The 'one pot' reaction between K[N(SiMe3)2], InI and the β-diimine ligand precursor [H(NDippCMe)2CH] (Dipp = C 6H3Pri2-2,6) gave [In{(NDippCMe)2CH}] 1, the first example of a two-coordinate, neutral, In(1) singlet 'carbene analogue'.

AB - The 'one pot' reaction between K[N(SiMe3)2], InI and the β-diimine ligand precursor [H(NDippCMe)2CH] (Dipp = C 6H3Pri2-2,6) gave [In{(NDippCMe)2CH}] 1, the first example of a two-coordinate, neutral, In(1) singlet 'carbene analogue'.

UR - https://www.scopus.com/pages/publications/4644351271

U2 - 10.1039/b406017b

DO - 10.1039/b406017b

M3 - Article

AN - SCOPUS:4644351271

SN - 1359-7345

SP - 1818

EP - 1819

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

A mononuclear indium(I) carbene analogue

Abstract

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