A mixed organozinc-diorganophosphide complex containing protic phosphine ligands bonded to zinc

Matthew G. Davidson; Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Christopher A. Russell; Alexander Steiner; Kerry L. Verhorevoort; Dominic S. Wright

doi:10.1039/C39950001989

A mixed organozinc-diorganophosphide complex containing protic phosphine ligands bonded to zinc

Matthew G. Davidson, Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Christopher A. Russell, Alexander Steiner, Kerry L. Verhorevoort, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Metallation of diphenylphosphine with ZnEt₂ (5:3 equiv.) in thf produces {[EtZn(μ-PPh₂)]₃·(HPPh ₂)₂·thf} 1, which is shown by X-ray crystallography to have a Zn₃P₃ core in which Ph₂PH ligands act as donors to two of the zinc centres.

Original language	English
Pages (from-to)	1989-1990
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1995
Issue number	19
DOIs	https://doi.org/10.1039/C39950001989
Publication status	Published - 31 Dec 1995

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39950001989

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@article{b09918044afd4e40981b321a4e4205a6,

title = "A mixed organozinc-diorganophosphide complex containing protic phosphine ligands bonded to zinc",

abstract = "Metallation of diphenylphosphine with ZnEt2 (5:3 equiv.) in thf produces \{[EtZn(μ-PPh2)]3·(HPPh 2)2·thf\} 1, which is shown by X-ray crystallography to have a Zn3P3 core in which Ph2PH ligands act as donors to two of the zinc centres.",

author = "Davidson, \{Matthew G.\} and Edwards, \{Andrew J.\} and Paver, \{Michael A.\} and Raithby, \{Paul R.\} and Russell, \{Christopher A.\} and Alexander Steiner and Verhorevoort, \{Kerry L.\} and Wright, \{Dominic S.\}",

year = "1995",

month = dec,

day = "31",

doi = "10.1039/C39950001989",

language = "English",

volume = "1995",

pages = "1989--1990",

journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Chemical Society",

number = "19",

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T1 - A mixed organozinc-diorganophosphide complex containing protic phosphine ligands bonded to zinc

AU - Davidson, Matthew G.

AU - Edwards, Andrew J.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Russell, Christopher A.

AU - Steiner, Alexander

AU - Verhorevoort, Kerry L.

AU - Wright, Dominic S.

PY - 1995/12/31

Y1 - 1995/12/31

N2 - Metallation of diphenylphosphine with ZnEt2 (5:3 equiv.) in thf produces {[EtZn(μ-PPh2)]3·(HPPh 2)2·thf} 1, which is shown by X-ray crystallography to have a Zn3P3 core in which Ph2PH ligands act as donors to two of the zinc centres.

AB - Metallation of diphenylphosphine with ZnEt2 (5:3 equiv.) in thf produces {[EtZn(μ-PPh2)]3·(HPPh 2)2·thf} 1, which is shown by X-ray crystallography to have a Zn3P3 core in which Ph2PH ligands act as donors to two of the zinc centres.

UR - https://www.scopus.com/pages/publications/37049081644

U2 - 10.1039/C39950001989

DO - 10.1039/C39950001989

M3 - Article

AN - SCOPUS:37049081644

SN - 0022-4936

VL - 1995

SP - 1989

EP - 1990

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 19

ER -

A mixed organozinc-diorganophosphide complex containing protic phosphine ligands bonded to zinc

Abstract

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