A metallated primary arsine; synthesis and structure of [PhAsHLi·2tHf]∞

Michael A. Beswick; Yvonne G. Lawson; Paul R. Raithby; Jody A. Wood; Dominic S. Wright

doi:10.1039/a902590a

A metallated primary arsine; synthesis and structure of [PhAsHLi·2tHf]_∞

Michael A. Beswick, Yvonne G. Lawson, Paul R. Raithby, Jody A. Wood, Dominic S. Wright

University of Bath

Research output: Contribution to journal › Article › peer-review

8 Citations (SciVal)

Abstract

The lithium primary arsenide [PhAsHLi·2thf]_∞, obtained by reaction of ⁿBuLi with PhAsH₂ in toluene-thf, crystallises in the form of helical polymers; the structure of the right-hand enantiomorph has been obtained.

Original language	English
Pages (from-to)	1921-1922
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/a902590a
Publication status	Published - 21 Jun 1999

ASJC Scopus subject areas

General Chemistry

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10.1039/a902590a

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title = "A metallated primary arsine; synthesis and structure of [PhAsHLi·2tHf]∞",

abstract = "The lithium primary arsenide [PhAsHLi·2thf]∞, obtained by reaction of nBuLi with PhAsH2 in toluene-thf, crystallises in the form of helical polymers; the structure of the right-hand enantiomorph has been obtained.",

author = "Beswick, {Michael A.} and Lawson, {Yvonne G.} and Raithby, {Paul R.} and Wood, {Jody A.} and Wright, {Dominic S.}",

year = "1999",

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doi = "10.1039/a902590a",

language = "English",

pages = "1921--1922",

journal = "Journal of the Chemical Society - Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - A metallated primary arsine; synthesis and structure of [PhAsHLi·2tHf]∞

AU - Beswick, Michael A.

AU - Lawson, Yvonne G.

AU - Raithby, Paul R.

AU - Wood, Jody A.

AU - Wright, Dominic S.

PY - 1999/6/21

Y1 - 1999/6/21

N2 - The lithium primary arsenide [PhAsHLi·2thf]∞, obtained by reaction of nBuLi with PhAsH2 in toluene-thf, crystallises in the form of helical polymers; the structure of the right-hand enantiomorph has been obtained.

AB - The lithium primary arsenide [PhAsHLi·2thf]∞, obtained by reaction of nBuLi with PhAsH2 in toluene-thf, crystallises in the form of helical polymers; the structure of the right-hand enantiomorph has been obtained.

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U2 - 10.1039/a902590a

DO - 10.1039/a902590a

M3 - Article

AN - SCOPUS:33748478794

SN - 0300-9246

SP - 1921

EP - 1922

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 12

ER -

A metallated primary arsine; synthesis and structure of [PhAsHLi·2tHf]_∞

Abstract

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