A magnesium-mediated cascade assembly for the atom-economical synthesis of bis(imidazolidine-2,4-dione)s

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Abstract

Bicycle race: Structurally complex bis(imidazolidine-2,4-dione) molecules may be synthesized with complete atom-efficiency from simple building blocks by a kinetically controlled magnesium-mediated cascade of intermolecular isocyanate insertion and intramolecular alkyne hydroamination reaction steps.
LanguageEnglish
Pages5364-5367
Number of pages4
JournalAngewandte Chemie-International Edition
Volume52
Issue number20
Early online date15 Apr 2013
DOIs
StatusPublished - 10 May 2013

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Isocyanates
Alkynes
Magnesium
imidazolidine-2,4-dione

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title = "A magnesium-mediated cascade assembly for the atom-economical synthesis of bis(imidazolidine-2,4-dione)s",
abstract = "Bicycle race: Structurally complex bis(imidazolidine-2,4-dione) molecules may be synthesized with complete atom-efficiency from simple building blocks by a kinetically controlled magnesium-mediated cascade of intermolecular isocyanate insertion and intramolecular alkyne hydroamination reaction steps.",
author = "M.S. Hill and D.J. Liptrot and M.F. Mahon",
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