A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Belén Galán; Marta E.G. Mosquera; Julie S. Palmer; Paul R. Raithby; Dominic S. Wright

doi:10.1039/a901478k

A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Belén Galán, Marta E.G. Mosquera, Julie S. Palmer, Paul R. Raithby, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

Controlled hydrolysis of the cubane [SnN′Bu]₄ with H₂O in thf-MeCN provides a direct route to the oxo complex [Sn₄(N′Bu)₃O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn₄-(N′Bu)₃(Nnaph)] as the sole product.

Original language	English
Pages (from-to)	1043-1044
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/a901478k
Publication status	Published - 7 Apr 1999

ASJC Scopus subject areas

General Chemistry

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10.1039/a901478k

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title = "A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane",

abstract = "Controlled hydrolysis of the cubane [SnN′Bu]4 with H2O in thf-MeCN provides a direct route to the oxo complex [Sn4(N′Bu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4-(N′Bu)3(Nnaph)] as the sole product.",

author = "Bel{\'e}n Gal{\'a}n and Mosquera, \{Marta E.G.\} and Palmer, \{Julie S.\} and Raithby, \{Paul R.\} and Wright, \{Dominic S.\}",

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T1 - A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

AU - Galán, Belén

AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Raithby, Paul R.

AU - Wright, Dominic S.

PY - 1999/4/7

Y1 - 1999/4/7

N2 - Controlled hydrolysis of the cubane [SnN′Bu]4 with H2O in thf-MeCN provides a direct route to the oxo complex [Sn4(N′Bu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4-(N′Bu)3(Nnaph)] as the sole product.

AB - Controlled hydrolysis of the cubane [SnN′Bu]4 with H2O in thf-MeCN provides a direct route to the oxo complex [Sn4(N′Bu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4-(N′Bu)3(Nnaph)] as the sole product.

UR - https://www.scopus.com/pages/publications/33748490468

U2 - 10.1039/a901478k

DO - 10.1039/a901478k

M3 - Article

AN - SCOPUS:33748490468

SN - 0300-9246

SP - 1043

EP - 1044

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 7

ER -

A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Abstract

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