A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Belén Galán; Marta E.G. Mosquera; Julie S. Palmer; Paul R. Raithby; Dominic S. Wright

doi:10.1039/a901478k

A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Belén Galán, Marta E.G. Mosquera, Julie S. Palmer, Paul R. Raithby, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

Controlled hydrolysis of the cubane [SnN′Bu]₄ with H₂O in thf-MeCN provides a direct route to the oxo complex [Sn₄(N′Bu)₃O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn₄-(N′Bu)₃(Nnaph)] as the sole product.

Original language	English
Pages (from-to)	1043-1044
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/a901478k
Publication status	Published - 7 Apr 1999

ASJC Scopus subject areas

General Chemistry

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abstract = "Controlled hydrolysis of the cubane [SnN′Bu]4 with H2O in thf-MeCN provides a direct route to the oxo complex [Sn4(N′Bu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4-(N′Bu)3(Nnaph)] as the sole product.",

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AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Raithby, Paul R.

AU - Wright, Dominic S.

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AB - Controlled hydrolysis of the cubane [SnN′Bu]4 with H2O in thf-MeCN provides a direct route to the oxo complex [Sn4(N′Bu)3O], reaction of which with naphNHLi (naph = 1-naphthyl) gives the heteroleptic cubane [Sn4-(N′Bu)3(Nnaph)] as the sole product.

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A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane

Abstract

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