A K3-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands

Donald Barr; Michael J. Doyle; Simon R. Drake; Paul R. Raithby; Ronald Snaith; Dominic S. Wright

doi:10.1021/ic00309a001

A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands

Donald Barr, Michael J. Doyle, Simon R. Drake, Paul R. Raithby, Ronald Snaith, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	1767-1768
Number of pages	2
Journal	Inorganic Chemistry
Volume	28
Issue number	10
DOIs	https://doi.org/10.1021/ic00309a001
Publication status	Published - 1 May 1989

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00309a001

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Barr, D., Doyle, M. J., Drake, S. R., Raithby, P. R., Snaith, R., & Wright, D. S. (1989). A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands. Inorganic Chemistry, 28(10), 1767-1768. https://doi.org/10.1021/ic00309a001

A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands. / Barr, Donald; Doyle, Michael J.; Drake, Simon R. et al.
In: Inorganic Chemistry, Vol. 28, No. 10, 01.05.1989, p. 1767-1768.

Research output: Contribution to journal › Article › peer-review

Barr, D, Doyle, MJ, Drake, SR, Raithby, PR, Snaith, R & Wright, DS 1989, 'A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands', Inorganic Chemistry, vol. 28, no. 10, pp. 1767-1768. https://doi.org/10.1021/ic00309a001

Barr D, Doyle MJ, Drake SR, Raithby PR, Snaith R, Wright DS. A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands. Inorganic Chemistry. 1989 May 1;28(10):1767-1768. doi: 10.1021/ic00309a001

Barr, Donald ; Doyle, Michael J. ; Drake, Simon R. et al. / A K₃-containing trigonal-bipyramidal cluster : Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands. In: Inorganic Chemistry. 1989 ; Vol. 28, No. 10. pp. 1767-1768.

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A K3-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands

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A K₃-containing trigonal-bipyramidal cluster: Synthesis of (KSCN)₃.5HMPA by reaction of solid NH₄SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K⁺ ions linked by three equatorial μ2-HMPA ligands and bicapped by two μ3-HMPA ligands