Abstract
This work describes an operationally simple catalytic synthesis of cyclic S-thiocarbonates with predictable regioselectivity in good yields. The reaction utilizes substrates derived from ubiquitous 1,2-diols in an atom economical intramolecular rearrangement, catalysed by an inexpensive and simple catalyst–ligand system. A crystal structure is presented that clearly confirms the regioselectivity of the reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 6441-6444 |
| Number of pages | 4 |
| Journal | European Journal of Organic Chemistry |
| Volume | 2017 |
| Issue number | 43 |
| Early online date | 3 Nov 2017 |
| DOIs | |
| Publication status | Published - 24 Nov 2017 |
Keywords
- Alkyl migrations
- Homogeneous catalysis
- Newman-Kwart
- Sulfur
- Synthetic methods
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
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