A fully self-assembled non-symmetric triad for photoinduced charge separation

Elisabetta Iengo; G. Dan Pantos; Jeremy K. M. Sanders; Michele Orlandi; Claudio Chiorboli; Sandro Fracasso; Franco Scandola

doi:10.1039/c0sc00520g

A fully self-assembled non-symmetric triad for photoinduced charge separation

Elisabetta Iengo, G. Dan Pantos, Jeremy K. M. Sanders, Michele Orlandi, Claudio Chiorboli, Sandro Fracasso, Franco Scandola

Research output: Contribution to journal › Article › peer-review

50 Citations (SciVal)

Abstract

A very efficient and successful metal-mediated strategy towards the formation of a non-symmetric triad is described: appropriate Lewis acid and/or base functions on the molecular components (a naphthalenediimide, an aluminium(III) porphyrin, and a ruthenium(II) porphyrin) lead to the desired product uniquely. The photophysics of the triad was investigated in detail using time-resolved spectroscopy in the pico- and nanosecond time domains. The strategy is of great potential interest as, while confining the synthetic effort to the single components, it can give access to a wide range of photoactive systems.

Original language	English
Pages (from-to)	676-685
Number of pages	10
Journal	Chemical Science
Volume	2
Issue number	4
DOIs	https://doi.org/10.1039/c0sc00520g
Publication status	Published - 2011

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abstract = "A very efficient and successful metal-mediated strategy towards the formation of a non-symmetric triad is described: appropriate Lewis acid and/or base functions on the molecular components (a naphthalenediimide, an aluminium(III) porphyrin, and a ruthenium(II) porphyrin) lead to the desired product uniquely. The photophysics of the triad was investigated in detail using time-resolved spectroscopy in the pico- and nanosecond time domains. The strategy is of great potential interest as, while confining the synthetic effort to the single components, it can give access to a wide range of photoactive systems.",

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T1 - A fully self-assembled non-symmetric triad for photoinduced charge separation

AU - Iengo, Elisabetta

AU - Pantos, G. Dan

AU - Sanders, Jeremy K. M.

AU - Orlandi, Michele

AU - Chiorboli, Claudio

AU - Fracasso, Sandro

AU - Scandola, Franco

PY - 2011

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AB - A very efficient and successful metal-mediated strategy towards the formation of a non-symmetric triad is described: appropriate Lewis acid and/or base functions on the molecular components (a naphthalenediimide, an aluminium(III) porphyrin, and a ruthenium(II) porphyrin) lead to the desired product uniquely. The photophysics of the triad was investigated in detail using time-resolved spectroscopy in the pico- and nanosecond time domains. The strategy is of great potential interest as, while confining the synthetic effort to the single components, it can give access to a wide range of photoactive systems.

UR - https://www.scopus.com/pages/publications/79955552526

U2 - 10.1039/c0sc00520g

DO - 10.1039/c0sc00520g

M3 - Article

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VL - 2

SP - 676

EP - 685

JO - Chemical Science

JF - Chemical Science

IS - 4

ER -

A fully self-assembled non-symmetric triad for photoinduced charge separation

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