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2019

A Stable Calcium Alumanyl

Hill, M., Schwamm, R., Coles, M., Mahon, M., McMullin, C., Rajabi, N. & Wilson, A., 12 Dec 2019, In : Angewandte Chemie-International Edition.

Research output: Contribution to journalArticle

Calcium formamidinate derivatives by hydride insertion of carbodiimides

Dyall, J., Hill, M. S., Mahon, M. F., Teh, L. & Wilson, A. S. S., 7 Apr 2019, In : Dalton Transactions. 48, 13, p. 4248-4254 7 p.

Research output: Contribution to journalArticle

Open Access
9 Citations (Scopus)

Calcium Hydride Insertion Reactions with Unsaturated C-C Bonds

Wilson, A. S. S., Hill, M. S. & Mahon, M. F., 28 Jan 2019, In : Organometallics. 38, 2, p. 351-360 10 p.

Research output: Contribution to journalArticle

Calcium stannyl formation by organostannane dehydrogenation

Morris, L. J., Hill, M. S., Manners, I., Mcmullin, C. L., Mahon, M. F. & Rajabi, N. A., 7 Nov 2019, In : Chemical Communications. 55, 86, p. 12964-12967 4 p.

Research output: Contribution to journalArticle

Open Access
Open Access

Ferrocene-Containing Polycarbosilazanes via the Alkaline-Earth-Catalyzed Dehydrocoupling of Silanes and Amines

Morris, L. J., Whittell, G. R., Eloi, J. C., Mahon, M. F., Marken, F., Manners, I. & Hill, M. S., 14 Oct 2019, In : Organometallics. 38, 19, p. 3629-3648 20 p.

Research output: Contribution to journalArticle

Open Access
2 Citations (Scopus)

Heterobimetallic Ruthenium-Zinc Complexes with Bulky N-Heterocyclic Carbenes: Syntheses, Structures and Reactivity

Espinal-Viguri, M., Varela-Izquerido, V., Miloserdov, F., Riddlestone, I., Mahon, M. & Whittlesey, M., 26 Mar 2019, In : Dalton Transactions . 48, 13, p. 4176-4189 14 p.

Research output: Contribution to journalArticle

Open Access
3 Citations (Scopus)
7 Downloads (Pure)

Magnesium hydride alkene insertion and catalytic hydrosilylation

Hill, M., Mahon, M., Garcia Rodriguez, L., Dinoi, C. & Maron, L., 28 Sep 2019, In : Chemical Science. 10, 35, p. 8108-8118 11 p.

Research output: Contribution to journalArticle

Open Access
File
1 Citation (Scopus)

Making the cut: Monopyrrolidine-based complexes for the ROP of lactide

Shere, H., McKeown, P., Mahon, M. F. & Jones, M. D., 1 May 2019, In : European Polymer Journal. 114, p. 319-325 7 p.

Research output: Contribution to journalArticle

2 Citations (Scopus)

Multimetallic Alkaline-Earth Hydride Cations

Garcia, L., Mahon, M. F. & Hill, M. S., 14 Oct 2019, In : Organometallics. 38, 19, p. 3778-3785 8 p.

Research output: Contribution to journalArticle

2 Citations (Scopus)

Reduction of 1,3,5,7-Cyclooctatetraene by a Molecular Calcium Hydride: An Even Electron Polarised Insertion/Deprotonation Mechanism

Hill, M., Wilson, A., Mahon, M., Maron, L. & Richards, E., 18 May 2019, In : Chemical Communications. 55, 40, p. 5732-5735 4 p.

Research output: Contribution to journalArticle

Open Access

Salalens and Salans derived from 3‐Aminopyrrolidine: Aluminium Complexation and Lactide Polymerisation

Britton, L., Ditz, D., Beament, J., McKeown, P., Quilter, H., Riley, K., Mahon, M. & Jones, M., 16 Jun 2019, In : European Journal of Inorganic Chemistry. 2019, 22, p. 2768-2773 6 p.

Research output: Contribution to journalArticle

2 Citations (Scopus)

Snapshots of magnesium-centred diborane heterolysis by an outer sphere SN2 process

Pecharman, A-F., Hill, M. S., McMullon, G., McMullin, C. & Mahon, M., 21 Jul 2019, In : Chemical Science. 10, 27, p. 6672-6682 11 p.

Research output: Contribution to journalArticle

Open Access

Transforming PPh3 into Bidentate Phosphine Ligands at Ru-Zn Heterobimetallic Complexes

O'Leary, N., Miloserdov, F., Mahon, M. & Whittlesey, M., 24 Sep 2019, In : Dalton Transactions . 48, 37, p. 14000-14009 10 p.

Research output: Contribution to journalArticle

Open Access
3 Citations (Scopus)

Tuning the thiolen: Al(III) and Fe(III) thiolen complexes for the isoselective ROP of rac-lactide

Stewart, J., McKeown, P., Driscoll, O., Mahon, M., Ward, B. & Jones, M., 13 Aug 2019, In : Macromolecules. 52, 15, p. 5977-5984 8 p.

Research output: Contribution to journalArticle

2018
5 Citations (Scopus)

[Ru3(6-NHC)(CO)10]: Synthesis, Characterization and Reactivity of Rare 46-Electron Tri-ruthenium Clusters

Ellul, C., Lowe, J., Mahon, M., Raithby, P. & Whittlesey, M., 7 Apr 2018, In : Dalton Transactions . 47, 13, p. 4518-4523 6 p.

Research output: Contribution to journalArticle

Open Access
Ruthenium
Carbon Monoxide
Electrons
Acylation
Salts
5 Citations (Scopus)
2 Downloads (Pure)

1,1-Diphosphines and divinylphosphines via base catalyzed hydrophosphination

Coles, N., Mahon, M. & Webster, R., 21 Sep 2018, In : Chemical Communications. 54, 74, p. 10443-10446 4 p.

Research output: Contribution to journalArticle

Open Access
Ligands
Phosphines
Alkynes
Catalysis
Potassium
15 Citations (Scopus)
7 Downloads (Pure)

Aluminum complexes of mono-pyrrolidine ligands for the con-trolled ring opening polymerization of lactide

Beament, J., Mahon, M., Buchard, A. & Jones, M., 11 Jun 2018, In : Organometallics. 37, 11, p. 1719-1724 6 p.

Research output: Contribution to journalArticle

Open Access
File
Ring opening polymerization
Aluminum
polymerization
Ligands
aluminum
2 Citations (Scopus)
18 Downloads (Pure)
Open Access
File
dihydrides
Ruthenium
Fluorides
ruthenium
halides
11 Citations (Scopus)

Coordination of arenes and phosphines by charge separated alkaline earth cations

Hill, M., Garcia, L., Anker, M., Mahon, M. & Maron, L., 28 Sep 2018, In : Dalton Transactions . 47, 36, p. 12684-12693 10 p.

Research output: Contribution to journalArticle

Open Access
12 Citations (Scopus)
60 Downloads (Pure)

Copper-NHC-Mediated Semi-Hydrogenation and Hydroboration of Alkynes: Enhanced Catalytic Activity Using Ring-Expanded Carbenes

Hall, J., Unson, D., Brunel, P., Collins, L., Cybulski, M., Mahon, M. & Whittlesey, M., 24 Sep 2018, In : Organometallics. 37, 18, p. 3102-3110 9 p.

Research output: Contribution to journalArticle

Open Access
File
9 Citations (Scopus)
20 Downloads (Pure)

Diborane Heterolysis: Breaking and Making B-B bonds at Magnesium

Hill, M., Pecharman, A-F. & Mahon, M., 7 Jun 2018, In : Dalton Transactions . 47, 21, p. 7300-7305 6 p.

Research output: Contribution to journalArticle

Open Access
21 Citations (Scopus)
9 Downloads (Pure)

Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls

Wilson, A., Dinoi, C., Hill, M., Mahon, M. & Maron, L., 9 Nov 2018, In : Angewandte Chemie-International Edition. 57, 47, p. 15500-15504 5 p.

Research output: Contribution to journalArticle

Open Access
10 Citations (Scopus)
5 Downloads (Pure)

Highly Active Mg(II) and Zn(II) complexes for the ring opening polymerisation of lactide

McKeown, P., Mccormick, S., Mahon, M. & Jones, M., 28 Nov 2018, In : Polymer Chemistry. 9, 44, p. 5339-5347 9 p.

Research output: Contribution to journalArticle

Open Access
File
7 Citations (Scopus)
6 Downloads (Pure)

Iron (III) Salalen Complexes for the Polymerisation of Lactide

Driscoll, O., Leung, C., McKeown, P., Mahon, M. & Jones, M., 19 Dec 2018, European Journal of Inorganic Chemistry, 2018, 47, p. 5129-5135 7 p.

Research output: Contribution to specialist publicationArticle

Open Access
File
5 Citations (Scopus)
30 Downloads (Pure)

Magnesium-Mediated Nucleophilic Borylation of Carbonyl Electrophiles

Hill, M., Mahon, M., Pecharman, A-F. & McMullin, C., 10 Dec 2018, In : Organometallics. 37, 23, p. 4457-4464 8 p.

Research output: Contribution to journalArticle

Open Access
File
5 Citations (Scopus)
22 Downloads (Pure)

Mono- and dinuclear Ni(I) products formed upon bromide abstraction from the Ni(I) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br]

Blackaby, W. J. M., Sabater, S., Poulten, R. C., Page, M. J., Folli, A., Krewald, V., Mahon, M. F., Murphy, D. M., Richards, E. & Whittlesey, M. K., 1 Jan 2018, In : Dalton Transactions . 47, 3, p. 769-782 14 p.

Research output: Contribution to journalArticle

Open Access
File
phosphine
Carbon Monoxide
Bromides
Toluene
Dimers
2 Citations (Scopus)
24 Downloads (Pure)

Post-Synthetic Mannich Chemistry on Metal-Organic Frameworks: System-Specific Reactivity and Functionality-Triggered Dissolution

Amer Hamzah, H., Gee, W., Raithby, P., Teat, S. J., Mahon, M. & Burrows, A., 1 Aug 2018, In : Chemistry - A European Journal. 24, 43, p. 11094-11102 9 p.

Research output: Contribution to journalArticle

Open Access
Dissolution
Metals
Nitrogen
Atoms
Carbon Monoxide
2 Citations (Scopus)

Small Molecule Antagonists of NAADP-Induced Ca2+ Release in T-Lymphocytes Suggest Potential Therapeutic Agents for Autoimmune Disease

Zhang, B., Watt, J. M., Cordiglieri, C., Dammermann, W., Mahon, M., Flugel, A., Guse, A. H. & Potter, B., 13 Nov 2018, In : Scientific Reports. 8, 17 p., 16775.

Research output: Contribution to journalArticle

Open Access

Synthesis and solid-state conformations of 6S,8aR/S-6-alkyl-3,3-dimethyltetrahydrooxazolo[3,4-a]pyrazine-5,8-diones (pseudoproline DKPs).

Beauchard, A., Dufton, H. F., Odumah, K., Jaggers, R. H., Mahon, M. F., Wood, P. J. & Threadgill, M., 2018, In : Indian Journal of Heterocyclic Chemistry.

Research output: Contribution to journalArticle

Diketopiperazines
Pyrazines
S 6
Conformations
Dipeptides
4 Citations (Scopus)
13 Downloads (Pure)

Synthesis of Unsymmetrical Diboranes by Diborane Metathesis

Pecharman, A-F., Hill, M. & Mahon, M., 6 Aug 2018, In : Angewandte Chemie-International Edition. 57, 33, p. 10688-10691 4 p.

Research output: Contribution to journalArticle

Open Access
File
4 Citations (Scopus)
35 Downloads (Pure)

The effect of metal distribution on the luminescence properties of mixed-lanthanide metal–organic frameworks

Cadman, L., Mahon, M. & Burrows, A., 21 Feb 2018, In : Dalton Transactions . 47, 7, p. 2360-2367 8 p.

Research output: Contribution to journalArticle

Open Access
Lanthanoid Series Elements
Luminescence
Metals
Europium
Terbium
3 Citations (Scopus)
22 Downloads (Pure)

Well-Defined Heterobimetallic Reactivity at Unsupported Ruthenium-Indium Bonds

Riddlestone, I., Rajabi, N., Macgregor, S., Mahon, M. & Whittlesey, M., 1 Feb 2018, In : Chemistry - A European Journal. 24, 7, p. 1732-1738 7 p.

Research output: Contribution to journalArticle

Open Access
File
2017
13 Citations (Scopus)

Alane-Centered Ring Expansion of N-Heterocyclic Carbenes

Anker, M. D., Colebatch, A. L., Iverson, K., Wilson, D. J. D., Dutton, J., Garcia Rodriguez, L., Hill, M., Liptrot, D. & Mahon, M., 27 Mar 2017, In : Organometallics. 36, 6, p. 1173-1178 6 p.

Research output: Contribution to journalArticle

carbenes
methylidyne
Aluminum
imidazoles
expansion
22 Citations (Scopus)
117 Downloads (Pure)

Alkaline Earth-Centered CO Homologation, Reduction, and Amine Carbonylation

Anker, M. D., Kefalidis, C. E., Yang, Y-Y., Fang, J., Hill, M. S., Mahon, M. F. & Maron, L., 26 Jul 2017, In : Journal of the American Chemical Society. 139, 29, p. 10036-10054 19 p.

Research output: Contribution to journalArticle

Open Access
File
Carbonylation
Carbon Monoxide
Magnesium
Amines
Earth (planet)
10 Citations (Scopus)

Alkaline-Earth Derivatives of the Reactive [HB(C6F5)3]- Anion

Anker, M. D., Arrowsmith, M., Arrowsmith, R. L., Hill, M. S. & Mahon, M. F., 15 May 2017, In : Inorganic Chemistry. 56, 10, p. 5976-5983 8 p.

Research output: Contribution to journalArticle

hydroboration
Magnesium
Anions
magnesium
Strontium
6 Citations (Scopus)
8 Citations (Scopus)
118 Downloads (Pure)

Computation Provides Chemical Insight into the Diverse Hydride NMR Chemical Shifts of [Ru(NHC)4(L)H]0/+ Species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ Congeners

Haller, L. J. L., Mas-Marza, E., Cybulski, M. K., Sanguramath, R. A., Macgregor, S. A., Mahon, M. F., Raynaud, C., Russell, C. A. & Whittlesey, M. K., 7 Mar 2017, In : Dalton Transactions . 46, p. 2861-2873

Research output: Contribution to journalArticle

Open Access
File
Chemical shift
Carbon Monoxide
Hydrides
Nuclear magnetic resonance
phosphine
7 Citations (Scopus)
87 Downloads (Pure)

Deposition of SnS Thin Films from Sn(II) Thioamidate Precursors

Catherall, A. L., Harris, S., Hill, M. S., Johnson, A. L. & Mahon, M. F., 4 Oct 2017, In : Crystal Growth and Design. 17, 10, p. 5544-5551

Research output: Contribution to journalArticle

Open Access
File
Tin
tin
Thin films
thin films
Thioamides
35 Citations (Scopus)

Easy access to nucleophilic boron through diborane to magnesium boryl metathesis

Pécharman, A. F., Colebatch, A. L., Hill, M. S., McMullin, C. L., Mahon, M. F. & Weetman, C., 7 Apr 2017, In : Nature Communications. 8, p. 1-7 7 p., 15022.

Research output: Contribution to journalArticle

Open Access
diborane
Boron
metathesis
Magnesium
magnesium
12 Citations (Scopus)

Hydrodeoxygenation of isocyanates: Snapshots of a magnesium-mediated CO bond cleavage

Yang, Y-Y., Anker, M. D., Fang, J., Mahon, M. F., Maron, L., Weetman, C. & Hill, M. S., 1 Mar 2017, In : Chemical Science. 8, 5, p. 3529-3537 9 p.

Research output: Contribution to journalArticle

Open Access
Isocyanates
Carbon Monoxide
Magnesium
Chemical activation
Borates
6 Citations (Scopus)
110 Downloads (Pure)

Iron catalysis for the synthesis of ligands: exploring the products of hydrophosphination as ligands in cross-coupling

Espinal-Viguri, M., Mahon, M. F., Tyler, S. N. G. & Webster, R. L., 5 Jan 2017, In : Tetrahedron. 73, 1, p. 64-69

Research output: Contribution to journalArticle

Open Access
File
12 Citations (Scopus)
Open Access
Ring opening polymerization
Ligands
Geometry
Nuclear magnetic resonance spectroscopy
Metals
11 Citations (Scopus)
5 Downloads (Pure)
Open Access
Magnesium
Anions
single bond
nonane
diborane
10 Citations (Scopus)
29 Downloads (Pure)

Markovnikov versus anti-Markovnikov hydrophosphination: Divergent reactivity using an iron(II) β-diketiminate pre-catalyst

King, A., Gallagher, K., Mahon, M. F. & Webster, R. L., 6 Jul 2017, In : Chemistry - A European Journal. 23, 38, p. 9039-9043

Research output: Contribution to journalArticle

Open Access
File
Iron
Phosphines
Regioselectivity
Catalysts
Methylene Chloride
52 Citations (Scopus)
93 Downloads (Pure)

Organocalcium-mediated nucleophilic alkylation of benzene

Wilson, A., Hill, M., Mahon, M., Dinoi, C. & Maron, L., 1 Dec 2017, In : Science. 358, 6367, p. 1168-1171 4 p.

Research output: Contribution to journalArticle

Open Access
File
Alkylation
Benzene
Nucleophiles
Calcium
Hydrides
27 Citations (Scopus)
32 Downloads (Pure)

Phosphine- and Amine-Borane Dehydrocoupling Using a Three Coordinate Iron(II) β-Diketiminate Pre-Catalyst

Coles, N., Mahon, M. & Webster, R., 12 Jun 2017, In : Organometallics. 36, 11, p. 2262-2268

Research output: Contribution to journalArticle

Open Access
File
10 Citations (Scopus)

Ratiometric electrochemical detection of hydrogen peroxide and glucose

Goggins, S., Apsey, E. A., Mahon, M. F. & Frost, C. G., 21 Feb 2017, In : Organic and Biomolecular Chemistry. 15, 11, p. 2459-2466 8 p.

Research output: Contribution to journalArticle

Open Access
Boronic Acids
Enzyme Assays
hydrogen peroxide
glucose
Hydrogen Peroxide
61 Citations (Scopus)
110 Downloads (Pure)

Remote C6-Selective Ruthenium-Catalyzed C-H Alkylation of Indole Derivatives via σ-Activation

Leitch, J. A., McMullin, C. L., Mahon, M. F., Bhonoah, Y. & Frost, C. G., 7 Apr 2017, In : ACS Catalysis. 7, 4, p. 2616-2623 8 p.

Research output: Contribution to journalArticle

Open Access
File
Ruthenium
Alkylation
Catalysis
Chemical activation
Derivatives