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• Three-coordinate beryllium β-diketiminates: Synthesis and reduction chemistry

  Arrowsmith, M., Hill, M. S., Kociok-Kohn, G., MacDougall, D. J., Mahon, M. F. & Mallov, I., 17 Dec 2012, In: Inorganic Chemistry. 51, 24, p. 13408-13418 11 p.

  Research output: Contribution to journal › Article › peer-review

  • synthesis (chemistry)
  • metathesis
  • Beryllium
  • amides
  • amines
  35 Citations (Scopus)

• The significance of secondary interactions during alkaline earth-promoted dehydrogenation of dialkylamine-boranes

  Bellham, P., Anker, M. D., Hill, M. S., Kociok-Kohn, G. & Mahon, M. F., 21 Sep 2016, In: Dalton Transactions. 45, 35, p. 13969-13978 10 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Dehydrogenation
  • Anions
  • Magnesium
  • Earth (planet)
  • Derivatives
  15 Citations (Scopus)

  166 Downloads (Pure)

• Thermal decomposition of solution processable metal xanthates on mesoporous titanium dioxide films: A new route to quantum-dot sensitised heterojunctions

  Lutz, T., MacLachlan, A., Sudlow, A., Nelson, J., Hill, M. S., Molloy, K. C. & Haque, S. A., 14 Dec 2012, In: Physical Chemistry Chemical Physics. 14, 47, p. 16192-16196 5 p.

  Research output: Contribution to journal › Article › peer-review

  • Semiconductor quantum dots
  • titanium dioxide
  • Heterojunctions
  • thermal decomposition
  • titanium oxides
  21 Citations (Scopus)

• The first crystallographically-characterised Cu(II) xanthate

  Johnson, A. L., Hill, M. S., Kociok-Kohn, G., Molloy, K. C. & Sudlow, A. L., Nov 2014, In: Inorganic Chemistry Communications. 49, p. 8-11 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • phenyllithium
  • N,N,N',N'-tetramethylethylenediamine
  • Copper
  • chelation
  • Film growth
  11 Citations (Scopus)

  161 Downloads (Pure)

• Synthesis and materials chemistry of bismuth Tris-(di-i-propylcarbamate): deposition of photoactive Bi₂O₃ thin films

  Cosham, S. D., Hill, M. S., Horley, G. A., Johnson, A. L., Jordan, L., Molloy, K. C. & Stanton, D. C., 6 Jan 2014, In: Inorganic Chemistry. 53, 1, p. 503-511 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • synthesis (chemistry)
  • Bismuth
  • bismuth
  • Thin films
  • chemistry
  14 Citations (Scopus)

  131 Downloads (Pure)

• Synthesis, Structure and CVD Studies of the Group 13 Complexes [Me₂M{tfacnac}] [M = Al, Ga, In; Htfacnac = F₃CC(OH)CHC(CH₃)NCH₂CH₂OCH₃]

  Cosham, S. D., Hamilton, J. A., Hill, M. S., Johnson, A. L. & Molloy, K. C., Apr 2016, In: European Journal of Inorganic Chemistry. 2016, 11, p. 1712-1719

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Chemical vapor deposition
  • Metals
  • Oxides
  • Metallorganic chemical vapor deposition
  • Indium
  1 Citation (Scopus)

  105 Downloads (Pure)

• Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 28 Mar 2011, In: Organometallics. 30, 6, p. 1291-1294 4 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis
  • catalytic activity
  • Catalyst activity
  • catalysis
  • methylidyne
  45 Citations (Scopus)

• Stoichiometric reactivity of dialkylamine boranes with alkaline earth silylamides

  Hill, M. S., Hodgson, M., Liptrot, D. J. & Mahon, M. F., 2011, In: Dalton Transactions. 40, 30, p. 7783-7790 8 p.

  Research output: Contribution to journal › Article › peer-review

  • BH 3
  • Earth (planet)
  • Amines
  • Derivatives
  • Molecules
  56 Citations (Scopus)

• Stoichiometric and catalytic reactivity of tert-butylamine-borane with calcium silylamides

  Bellham, P., Hill, M. S. & Kociok-Köhn, G., 27 Oct 2014, In: Organometallics. 33, 20, p. 5716-5721 6 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • tert-butylamine
  • boranes
  • Amines
  • reactivity
  • calcium
  13 Citations (Scopus)

  118 Downloads (Pure)

• Solution-processed mesoscopic Bi₂S₃: polymer photoactive layers

  MacLachlan, A. J., O'Mahony, F. T. F., Sudlow, A. L., Hill, M. S., Molloy, K. C., Nelson, J. & Haque, S. A., 14 Apr 2014, In: ChemPhysChem. 15, 6, p. 1019-1023 5 p.

  Research output: Contribution to journal › Article › peer-review

  • Polymers
  • polarization (charge separation)
  • polymers
  • Photoexcitation
  • Absorption spectroscopy
  22 Citations (Scopus)

• Single-source AACVD of composite cobalt-silicon oxide thin films

  Hill, M. S., Johnson, A. L., Manning, T. D., Molloy, K. C. & Wickham, B. J., 1 Oct 2014, In: Inorganica Chimica Acta. 422, p. 47-56 10 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • tert-butoxy
  • Silicon oxides
  • cobalt oxides
  • Oxide films
  • Cobalt
  5 Citations (Scopus)

  167 Downloads (Pure)

• Selective reduction of CO₂ to a methanol equivalent by B(C₆F₅)₃-activated alkaline earth catalysis

  Anker, M. D., Arrowsmith, M., Bellham, P., Hill, M. S., Kociok-Köhn, G., Liptrot, D. J., Mahon, M. F. & Weetman, C., 1 Jul 2014, In: Chemical Science. 5, 7, p. 2826-2830 5 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Catalysis
  • Methanol
  • Carbon Monoxide
  • Earth (planet)
  • Borates
  83 Citations (Scopus)

  170 Downloads (Pure)

• Routes to the low temperature deposition of transparent conducting oxides

  Wildsmith, T., Hill, M., Molloy, K., Johnson, A. & Kingsley, A. J., 20 Jul 2012.

  Research output: Contribution to conference › Poster

• Routes to the low temperature deposition of tin oxide

  Wildsmith, T., Molloy, K., Hill, M. & Johnson, A., 27 Oct 2012.

  Research output: Contribution to conference › Poster

• Routes to low temperature precursors for transparent conducting oxides

  Wildsmith, T., Hill, M., Molloy, K., Johnson, A. & Kingsley, A. J., 3 Apr 2012.

  Research output: Contribution to conference › Other

• Ring expansion of a ring expanded carbene

  Garcia Rodriguez, L., Al Fahraiji, K., Wilson, D. J. D., Dutton, J., Hill, M. & Mahon, M., 28 Sep 2017, In: Dalton Transactions . 46, 36, p. 12015-12018 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • carbene
  • Carbon
  • Silicon
  • Heating
  • Temperature
  4 Citations (Scopus)

• Precursors for p-Type Nickel Oxide: Atmospheric-Pressure Metal-Organic Chemical-Vapour Deposition (MOCVD) of Nickel Oxide Thin Films with High Work Functions

  Johnson, A., Richards, S., Manning, T. D., Hill, M. & Molloy, K., 3 Apr 2017, In: European Journal of Inorganic Chemistry. 2017, 13, p. 1868-1876 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • phenyllithium
  • nickel monoxide
  • indium tin oxide
  • Organic Chemicals
  • Oxide films
  2 Citations (Scopus)

  66 Downloads (Pure)

• Organocalcium-mediated nucleophilic alkylation of benzene

  Wilson, A., Hill, M., Mahon, M., Dinoi, C. & Maron, L., 1 Dec 2017, In: Science. 358, 6367, p. 1168-1171 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Alkylation
  • Benzene
  • Nucleophiles
  • Hydrides
  • Calcium
  83 Citations (Scopus)

  129 Downloads (Pure)

• N-Heterocyclic carbenes and charge separation in heterometallic s-block silylamides

  Hill, M. S., Kociok-Kohn, G. & MacDougall, D. J., 2011, In: Inorganic Chemistry. 50, 11, p. 5234-5241 8 p.

  Research output: Contribution to journal › Article › peer-review

  • carbene
  • carbenes
  • polarization (charge separation)
  • Alkali Metals
  • ligands
  51 Citations (Scopus)

• New organo- and amidozinc derivatives of primary amines

  Cosham, S. D., Hill, M. S., Johnson, A. L. & Molloy, K. C., 1 Jan 2014, In: Dalton Transactions. 43, 2, p. 859-864

  Research output: Contribution to journal › Article › peer-review

  File
  3 Citations (Scopus)

  153 Downloads (Pure)

• Mononuclear three-coordinate magnesium complexes of a highly sterically encumbered β-diketiminate ligand

  Arrowsmith, M., Maitland, B., Kociok-Köhn, G., Stasch, A., Jones, C. & Hill, M. S., 6 Oct 2014, In: Inorganic Chemistry. 53, 19, p. 10543-10552 10 p.

  Research output: Contribution to journal › Article › peer-review

  File

  • Imines
  • imines
  • Magnesium
  • ligands
  • magnesium
  47 Citations (Scopus)

  183 Downloads (Pure)

• Magnesium hydrides and the dearomatisation of pyridine and quinoline derivatives

  Hill, M., Kociok-Kohn, G., MacDougall, D. J., Mahon, M. F. & Weetman, C., 14 Dec 2011, In: Dalton Transactions. 40, 46, p. 12500-12509 10 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • quinoline
  • pyridine
  • 4-methylpyridine
  • Magnesium
  • Derivatives
  45 Citations (Scopus)

  163 Downloads (Pure)

• Magnesium-catalyzed hydroboration of pyridines

  Arrowsmith, M., Hill, M. S., Hadlington, T., Kociok-Kohn, G. & Weetman, C., 14 Nov 2011, In: Organometallics. 30, 21, p. 5556-5559 4 p.

  Research output: Contribution to journal › Article › peer-review

  • hydroboration
  • Pyridines
  • pyridine
  • pyridines
  • Magnesium
  144 Citations (Scopus)

• Magnesium catalysis of imine hydroboration

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 18 Feb 2013, In: Chemistry - A European Journal. 19, 8, p. 2776-2783 8 p.

  Research output: Contribution to journal › Article › peer-review

  • Imines
  • Catalysis
  • Magnesium
  • pinacol
  • ketimine
  91 Citations (Scopus)

• Magnesium catalysis for the hydroboration of carbodiimides

  Weetman, C., Hill, M. S. & Mahon, M. F., 17 May 2016, In: Chemistry - A European Journal. 22, 21, p. 7158-7162 5 p.

  Research output: Contribution to journal › Article › peer-review

  • Carbodiimides
  • pinacol
  • Catalysis
  • formamidine
  • Magnesium
  44 Citations (Scopus)

• Magnesium-catalysed nitrile hydroboration

  Weetman, C., Anker, M., Arrowsmith, M., Hill, M., Kociok-Kohn, G., Liptrot, D. & Mahon, M., 1 Jan 2016, In: Chemical Science. 7, 1, p. 628-641 14 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Nitriles
  • Magnesium
  • Catalysis
  • Electrons
  • Isotopes
  96 Citations (Scopus)

  89 Downloads (Pure)

• Magnesium-catalysed hydroboration of pyridines: kinetic analysis and poly-pyridine dearomatisation

  Weetman, C., Hill, M. S. & Mahon, M. F., 8 Jan 2016, In: Polyhedron. 103, Part 8, p. 115-120

  Research output: Contribution to journal › Article › peer-review

  File

  • hydroboration
  • Pyridines
  • Pyridine
  • quinoline
  • pyridine
  29 Citations (Scopus)

  166 Downloads (Pure)

• Magnesium-catalysed hydroboration of aldehydes and ketones

  Arrowsmith, M., Hadlington, T. J., Hill, M. & Kociok-Kohn, G., 2012, In: Chemical Communications. 48, 38, p. 4567-4569 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Aldehydes
  • Ketones
  • Magnesium
  • Catalysts
  • 4,4,5,5-tetramethyl(1,3,2)dioxaborolane
  165 Citations (Scopus)

• Magnesium Boryl Reactivity with 9-BBN and Ph3B: Rational B-B' Bond Formation and Diborane Isomerization

  Pecharman, A-F., Hill, M., McMullin, C. & Mahon, M., 13 Dec 2017, In: Angewandte Chemie-International Edition. 56, 51, p. 16363-16366 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Nucleophiles
  • Isomerization
  • Negative ions
  • Magnesium
  • Derivatives
  17 Citations (Scopus)

  5 Downloads (Pure)

• Low temperature precursors for the metal organic chemical vapour deposition of transparent conducting oxides

  Wildsmith, T., Hill, M., Johnson, A., Molloy, K. & Kingsley, A. J., 15 Jul 2011.

  Research output: Contribution to conference › Poster

• Low temperature precursors for the metal organic chemical vapour deposition of transparent conducting oxides

  Wildsmith, T., Hill, M., Johnson, A., Molloy, K. & Kingsley, A. J., 31 Jul 2011.

  Research output: Contribution to conference › Poster

• Influence of crystallinity and energetics on charge separation in polymer–inorganic nanocomposite films for solar cells

  Bansal, N., Reynolds, L. X., MacLachlan, A., Lutz, T., Ashraf, R. S., Zhang, W., Nielsen, C. B., McCulloch, I., Rebois, D. G., Kirchartz, T., Hill, M. S., Molloy, K. C., Nelson, J. & Haque, S. A., 25 Mar 2013, In: Scientific Reports. 3, 1531.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • polarization (charge separation)
  • crystallinity
  • heterojunctions
  • nanocomposites
  • solar cells
  69 Citations (Scopus)

  166 Downloads (Pure)

• Hydrodeoxygenation of isocyanates: Snapshots of a magnesium-mediated CO bond cleavage

  Yang, Y-Y., Anker, M. D., Fang, J., Mahon, M. F., Maron, L., Weetman, C. & Hill, M. S., 1 Mar 2017, In: Chemical Science. 8, 5, p. 3529-3537 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • Isocyanates
  • Carbon Monoxide
  • Magnesium
  • Chemical activation
  • Borates
  24 Citations (Scopus)

• Homoleptic zirconium amidates: single source precursors for the aerosol-assisted chemical vapour deposition of ZrO₂

  Catherall, A. L., Hill, M. S., Johnson, A. L., Kociok-Kohn, G. & Mahon, M. F., 7 Dec 2016, In: Journal of Materials Chemistry C. 4, 45, p. 10731-10739 9 p.

  Research output: Contribution to journal › Article › peer-review

  • Zirconium
  • Aerosols
  • Chemical vapor deposition
  • Pyrolysis
  • Derivatives
  6 Citations (Scopus)

• Homogeneous catalysis with organometallic complexes of group 2

  Crimmin, M. R. & Hill, M. S., 2013, Alkaline-Earth Metal Compounds: Oddities and Applications. Harder, S. (ed.). Berlin: Springer, p. 191-242 52 p. (Topics in Organometallic Chemistry; vol. 45).

  Research output: Chapter in Book/Report/Conference proceeding › Chapter

  • Isocyanates
  • Organometallics
  • Catalysis
  • Amines
  • Hydrosilylation
  85 Citations (Scopus)

• Hetero-dehydrocoupling of silanes and amines by heavier alkaline earth catalysis

  Hill, M. S., Liptrot, D. J., MacDougall, D. J., Mahon, M. F. & Robinson, T. P., Nov 2013, In: Chemical Science. 4, 11, p. 4212-4222 11 p.

  Research output: Contribution to journal › Article › peer-review

  • Silanes
  • Catalysis
  • Amines
  • Catalysts
  • Earth (planet)
  62 Citations (Scopus)

• Heterobimetallic s-block hydrides by σ-bond metathesis

  Liptrot, D. J., Hill, M. S. & Mahon, M. F., 4 Aug 2014, In: Chemistry - A European Journal. 20, 32, p. 9871-9874

  Research output: Contribution to journal › Article › peer-review

  • Alkali Metals
  • Alkali metals
  • Hydrides
  • Metals
  21 Citations (Scopus)

• Heavier alkaline earth catalyzed ene-yne cyclizations: Atom-efficient access to tetrahydroisoquinoline frameworks

  Reid, S., Barrett, A. G. M., Hill, M. S. & Procopiou, P. A., 21 Nov 2014, In: Organic Letters. 16, 22, p. 6016-6019 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Cyclization
  • alkynes
  • Alkynes
  • 1,2,3,4-tetrahydroisoquinoline
  • Alkenes
  7 Citations (Scopus)

  151 Downloads (Pure)

• Heavier alkaline earth catalysts for the intermolecular hydroamination of vinylarenes, dienes, and alkynes

  Brinkmann, C., Barrett, A. G. M., Hill, M. S. & Procopiou, P. A., 1 Feb 2012, In: Journal of the American Chemical Society. 134, 4, p. 2193-2207 15 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkynes
  • Amines
  • Alkenes
  • Olefins
  • Catalysts
  131 Citations (Scopus)

• Facile kinetic induction of a dihydropyridide to pyrrolide ring contraction

  Carbery, D. R., Hill, M. S., Mahon, M. F. & Weetman, C., 14 Apr 2016, In: Dalton Transactions . 45, 14, p. 5925-5928

  Research output: Contribution to journal › Article › peer-review

  File

  • Carbodiimides
  • Magnesium
  • Substitution reactions
  • Derivatives
  1 Citation (Scopus)

  76 Downloads (Pure)

• Exclusive formation of SnO by low temperature single-source AACVD

  Wildsmith, T., Hill, M. S., Johnson, A. L., Kingsley, A. J. & Molloy, K. C., 9 Oct 2013, In: Chemical communications (Cambridge, England). 49, 78, p. 8773-8775 3 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Aerosols
  • Chemical vapor deposition
  • Oxidation
  • Derivatives
  • Temperature
  18 Citations (Scopus)

  190 Downloads (Pure)

• Easy access to nucleophilic boron through diborane to magnesium boryl metathesis

  Pécharman, A. F., Colebatch, A. L., Hill, M. S., McMullin, C. L., Mahon, M. F. & Weetman, C., 7 Apr 2017, In: Nature Communications. 8, p. 1-7 7 p., 15022.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  • diborane
  • metathesis
  • Boron
  • Magnesium
  • magnesium
  47 Citations (Scopus)

• Direct growth of metal sulfide nanoparticle networks in solid-state polymer films for hybrid inorganic-organic solar cells

  Dowland, S., Lutz, T., Ward, A., King, S. P., Sudlow, A., Hill, M., Molloy, K. C. & Haque, S. A., 24 Jun 2011, In: Advanced Materials. 23, 24, p. 2739-2744 6 p.

  Research output: Contribution to journal › Article › peer-review

  • Organic solar cells
  • Sulfides
  • Polymer films
  • Nanoparticles
  • Metals
  113 Citations (Scopus)

• Deposition of SnS Thin Films from Sn(II) Thioamidate Precursors

  Catherall, A. L., Harris, S., Hill, M. S., Johnson, A. L. & Mahon, M. F., 4 Oct 2017, In: Crystal Growth and Design. 17, 10, p. 5544-5551

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Tin
  • Thin films
  • tin
  • Thioamides
  • thin films
  11 Citations (Scopus)

  140 Downloads (Pure)

• Dearomatized BIAN alkaline-earth alkyl catalysts for the intramolecular hydroamination of hindered aminoalkenes

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 13 Jan 2014, In: Organometallics. 33, 1, p. 206-216 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • catalysts
  • Catalysts
  • Earth (planet)
  • methylidyne
  • ligands
  21 Citations (Scopus)

  246 Downloads (Pure)

• Cation charge density and precatalyst selection in group 2-catalyzed aminoalkene hydroamination

  Arrowsmith, M., Crimmin, M. R., Barrett, A. G. M., Hill, M. S., Kociok-Kohn, G. & Procopiou, P. A., 28 Mar 2011, In: Organometallics. 30, 6, p. 1493-1506 14 p.

  Research output: Contribution to journal › Article › peer-review

  • Charge density
  • Cyclization
  • Cations
  • calcium
  • Strontium
  97 Citations (Scopus)

• Catalytic hydroacetylenation of carbodiimides with homoleptic alkaline earth hexamethyldisilazides

  Arrowsmith, M., Crimmin, M. R., Hill, M. S., Lomas, S. L., Heng, M. S., Hitchcock, P. B. & Kociok-Köhn, G., 14 Oct 2014, In: Dalton Transactions. 43, 38, p. 14249-14256 8 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Carbodiimides
  • Strontium
  • Earth (planet)
  • Acetylene
  • Catalyst activity
  26 Citations (Scopus)

  130 Downloads (Pure)

• Catalytic and stoichiometric cumulene formation within dimeric group 2 acetylides

  Arrowsmith, M., Crimmin, M. R., Hill, M. S., Lomas, S. L., Macdougall, D. J. & Mahon, M. F., 9 Sep 2013, In: Organometallics. 32, 17, p. 4961-4972 12 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkynes
  • Polyenes
  • Magnesium
  • magnesium
  • acetylene
  19 Citations (Scopus)

• Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

  Bellham, P., Hill, M. S., Kociok-Kohn, G. & Liptrot, D. J., 7 Mar 2013, In: Chemical Communications. 49, 19, p. 1960-1962 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis
  • Amines
  • Earth (planet)
  • Amides
  • Metals
  25 Citations (Scopus)

• Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene

  Arrowsmith, M., Hill, M. S., Kociok-Kohn, G., MacDougall, D. J. & Mahon, M. F., 27 Feb 2012, In: Angewandte Chemie-International Edition. 51, 9, p. 2098-2100 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Beryllium
  • Chemical activation
  102 Citations (Scopus)