This chapter organizes the established pattern, that is, the compounds are listed in an order according to the number of double bonds in the heterocycles. “1, 3-thiazane” is described in this chapter. The synthesis and reactions of thiazinium salts are discussed. The compounds 2H-1, 3-thiazines, 4H-1, 3-thiazines (1, R=H), and 6H-1, 3-Thiazines, are discussed for synthesis, reactions and physical methods. The chapter illustrates that 6H-1, 3-thiazines react with a variety of nucleophiles. The section on thiazinones, thiones and imines are discussed and illustrationed. The compounds containing banzothiazines; 1, 3-benzothiazinediones; thiones and imines; 4H-3; 1-benzothiazines; and benzothiazones are presented. The perhydrobenzothiazines and related compounds—namely, perhydrothiazines, perhydro-3, 1-benzothiazin-2-ones are explained for the conformational effects because they show similar behavior.
|Title of host publication||Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds|
|Subtitle of host publication||A Modern Comprehensive Treatise|
|Number of pages||42|
|Publication status||Published - 1991|
Sainsbury, M. (1991). 1,3-Thiazines and benzothiazines and their reduced forms. In Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds: A Modern Comprehensive Treatise (2 ed., Vol. 4, pp. 533-574) https://doi.org/10.1016/B978-044453347-0.50214-7