[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

M D Jones, F A A Paz, J E Davies, B F G Johnson

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.
Original languageEnglish
Pages (from-to)M111-M113
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

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