[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

M D Jones, F A A Paz, J E Davies, B F G Johnson

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Abstract

The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.
LanguageEnglish
PagesM111-M113
JournalActa Crystallographica Section E-Structure Reports Online
Volume59
DOIs
StatusPublished - 2003

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Rhodium
Methylene Chloride
Dichloromethane
tetrahydrofuran
Chelation
rhodium
Ligands
Geometry
Metals
ligands
geometry
metals
1,1'-bis(diphenylphosphino)ferrocene
1,5-cyclooctadiene
trifluoromethanesulfonic acid
ferrocene

Cite this

@article{2c4ce641eca74b56beb502f54cc60387,
title = "[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate",
abstract = "The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.",
author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G}",
note = "ID number: ISI:000181609600014",
year = "2003",
doi = "10.1107/s1600536803003581",
language = "English",
volume = "59",
pages = "M111--M113",
journal = "Acta Crystallographica Section E-Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - [1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

AU - Jones,M D

AU - Paz,F A A

AU - Davies,J E

AU - Johnson,B F G

N1 - ID number: ISI:000181609600014

PY - 2003

Y1 - 2003

N2 - The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

AB - The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

U2 - 10.1107/s1600536803003581

DO - 10.1107/s1600536803003581

M3 - Article

VL - 59

SP - M111-M113

JO - Acta Crystallographica Section E-Structure Reports Online

T2 - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

SN - 1600-5368

ER -