[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

M D Jones; F A A Paz; J E Davies; B F G Johnson

doi:10.1107/s1600536803003581

[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

M D Jones, F A A Paz, J E Davies, B F G Johnson

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

Original language	English
Pages (from-to)	M111-M113
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	59
DOIs	https://doi.org/10.1107/s1600536803003581
Publication status	Published - 2003

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@article{2c4ce641eca74b56beb502f54cc60387,

title = "[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate",

abstract = "The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.",

author = "Jones, {M D} and Paz, {F A A} and Davies, {J E} and Johnson, {B F G}",

note = "ID number: ISI:000181609600014",

year = "2003",

doi = "10.1107/s1600536803003581",

language = "English",

volume = "59",

pages = "M111--M113",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - [1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

AU - Jones, M D

AU - Paz, F A A

AU - Davies, J E

AU - Johnson, B F G

N1 - ID number: ISI:000181609600014

PY - 2003

Y1 - 2003

N2 - The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

AB - The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

U2 - 10.1107/s1600536803003581

DO - 10.1107/s1600536803003581

M3 - Article

VL - 59

SP - M111-M113

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

SN - 1600-5368

ER -

[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate

Abstract

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