Abstract
The synthesis of ω-alkenylallylboronate derivatives is described for the first time. In addition, their performance in the chiral Brønsted acid-catalyzed allylboration/RCM tandem sequence is studied. Cyclic alcohols, displaying the hydroxyl functionality at an exocyclic position and two consecutive stereocenters, are obtained as single diastereoisomers and in high degree of enantioselectivity, in most of the cases.
Original language | English |
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Pages (from-to) | 3492-3495 |
Number of pages | 4 |
Journal | European Journal of Organic Chemistry |
Volume | 2021 |
Issue number | 24 |
Early online date | 27 May 2021 |
DOIs | |
Publication status | Published - 25 Jun 2021 |
Funding
P. B. thanks the Spanish MINECO for a Ramón y Cajal contract (RyC‐2016‐20951).M.N.G. thanks the University of Bath for financial support.