ω‐Alkenylallylboronates: Design, Synthesis and Application to the Asymmetric Allylation / RCM Tandem Sequence

Francisco Garnes-Portolés, Rubén Miguélez, Matthew N Grayson, Pablo Barrio

Research output: Contribution to journalArticlepeer-review

1 Citation (SciVal)

Abstract

The synthesis of ω-alkenylallylboronate derivatives is described for the first time. In addition, their performance in the chiral Brønsted acid-catalyzed allylboration/RCM tandem sequence is studied. Cyclic alcohols, displaying the hydroxyl functionality at an exocyclic position and two consecutive stereocenters, are obtained as single diastereoisomers and in high degree of enantioselectivity, in most of the cases.
Original languageEnglish
Pages (from-to)3492-3495
Number of pages4
JournalEuropean Journal of Organic Chemistry
Volume2021
Issue number24
Early online date27 May 2021
DOIs
Publication statusPublished - 25 Jun 2021

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