μ2-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]

Y. Sow, L. Diop, K.C. Molloy, G. Kociok-Kohn

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The asymmetric unit of the binuclear title compound, [Sn2(C2O )(C6H)6(CHNS)2], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O interactions are also present.
Original languageEnglish
Article numberm1337
JournalActa Crystallographica Section E-Structure Reports Online
Volume68
Issue number11
DOIs
Publication statusPublished - Nov 2012

Fingerprint

Thiourea
Oxalates
Tin
Thioureas
thioureas
oxalates
tin
Atoms
Molecules
Hydrogen bonds
Negative ions
Ligands
Anions
atoms
molecules
hydrogen bonds
anions
ligands
interactions

Cite this

μ2-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]. / Sow, Y.; Diop, L.; Molloy, K.C.; Kociok-Kohn, G.

In: Acta Crystallographica Section E-Structure Reports Online, Vol. 68, No. 11, m1337, 11.2012.

Research output: Contribution to journalArticle

@article{cfbd29dd10984ababbfaadc4c8783e4d,
title = "μ2-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]",
abstract = "The asymmetric unit of the binuclear title compound, [Sn2(C2O )(C6H)6(CHNS)2], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O interactions are also present.",
author = "Y. Sow and L. Diop and K.C. Molloy and G. Kociok-Kohn",
year = "2012",
month = "11",
doi = "10.1107/S1600536812040706",
language = "English",
volume = "68",
journal = "Acta Crystallographica Section E-Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "11",

}

TY - JOUR

T1 - μ2-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]

AU - Sow, Y.

AU - Diop, L.

AU - Molloy, K.C.

AU - Kociok-Kohn, G.

PY - 2012/11

Y1 - 2012/11

N2 - The asymmetric unit of the binuclear title compound, [Sn2(C2O )(C6H)6(CHNS)2], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O interactions are also present.

AB - The asymmetric unit of the binuclear title compound, [Sn2(C2O )(C6H)6(CHNS)2], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O interactions are also present.

UR - http://www.scopus.com/inward/record.url?scp=84870928540&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1107/S1600536812040706

U2 - 10.1107/S1600536812040706

DO - 10.1107/S1600536812040706

M3 - Article

VL - 68

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

SN - 1600-5368

IS - 11

M1 - m1337

ER -