μ2-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]

Y. Sow, L. Diop, K.C. Molloy, G. Kociok-Kohn

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The asymmetric unit of the binuclear title compound, [Sn2(C2O )(C6H)6(CHNS)2], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O interactions are also present.
Original languageEnglish
Article numberm1337
JournalActa Crystallographica Section E-Structure Reports Online
Volume68
Issue number11
DOIs
Publication statusPublished - Nov 2012

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