[(η5‐Cp)2Sn(μ‐η5‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion

Matthew G. Davidson; Dietmar Stalke; Dominic S. Wright

doi:10.1002/anie.199212261

[(η⁵‐Cp)₂Sn(μ‐η⁵‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion

Matthew G. Davidson, Dietmar Stalke, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

An organotin(II) anion with three η⁵‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp₂Sn], and PMDETA (mol ratio 1:1:1). This [Cp₃Sn]⁻ ion is linked to the Na⁺ ion by a μ‐η⁵‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me₂NCH₂CH₂)₂NMe. (Figure Presented.)

Original language	English
Pages (from-to)	1226-1227
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	9
DOIs	https://doi.org/10.1002/anie.199212261
Publication status	Published - Sept 1992

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Catalysis
General Chemistry

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@article{8e9616e729e04a46ae186812e7469df2,

title = "[(η5‐Cp)2Sn(μ‐η5‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion",

abstract = "An organotin(II) anion with three η5‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]− ion is linked to the Na+ ion by a μ‐η5‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me2NCH2CH2)2NMe. (Figure Presented.)",

author = "Davidson, \{Matthew G.\} and Dietmar Stalke and Wright, \{Dominic S.\}",

year = "1992",

month = sep,

doi = "10.1002/anie.199212261",

language = "English",

volume = "31",

pages = "1226--1227",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Inc.",

number = "9",

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TY - JOUR

T1 - [(η5‐Cp)2Sn(μ‐η5‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion

AU - Davidson, Matthew G.

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1992/9

Y1 - 1992/9

N2 - An organotin(II) anion with three η5‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]− ion is linked to the Na+ ion by a μ‐η5‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me2NCH2CH2)2NMe. (Figure Presented.)

AB - An organotin(II) anion with three η5‐Cp ligands and a Sn atom in a trigonal‐planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]− ion is linked to the Na+ ion by a μ‐η5‐Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) … Na interactions. PMDETA = (Me2NCH2CH2)2NMe. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748228261

U2 - 10.1002/anie.199212261

DO - 10.1002/anie.199212261

M3 - Article

AN - SCOPUS:33748228261

SN - 0570-0833

VL - 31

SP - 1226

EP - 1227

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 9

ER -

[(η⁵‐Cp)₂Sn(μ‐η⁵‐Cp)Na · PMDETA], a Compound with a Trigonal‐Planar “Paddle Wheel” Triorganostannate Ion

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