(η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

Matthew D. Jones; Filipe A.Almeida Paz; John E. Davies; Brian F.G. Johnson

doi:10.1107/S1600536803003507

(η³-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

Matthew D. Jones, Filipe A.Almeida Paz, John E. Davies, Brian F.G. Johnson

University of Cambridge

Research output: Contribution to journal › Article › peer-review

5 Citations (SciVal)

Abstract

The title compound, [Pd(C₃H₅)(C₉H ₁₈N₂)]CF₃SO₃, crystallizes in the non-centrosymmetric space group P2₁2₁2₁ and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C₉H₁₈N₂) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η³- allyl)(pmp)]⁺ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Original language	English
Pages (from-to)	m105-m107
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	3
Early online date	21 Feb 2003
DOIs	https://doi.org/10.1107/S1600536803003507
Publication status	Published - 1 Mar 2003

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate",

abstract = "The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.",

author = "Jones, \{Matthew D.\} and Paz, \{Filipe A.Almeida\} and Davies, \{John E.\} and Johnson, \{Brian F.G.\}",

year = "2003",

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doi = "10.1107/S1600536803003507",

language = "English",

volume = "59",

pages = "m105--m107",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

number = "3",

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TY - JOUR

T1 - (η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

AU - Jones, Matthew D.

AU - Paz, Filipe A.Almeida

AU - Davies, John E.

AU - Johnson, Brian F.G.

PY - 2003/3/1

Y1 - 2003/3/1

N2 - The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

AB - The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

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U2 - 10.1107/S1600536803003507

DO - 10.1107/S1600536803003507

M3 - Article

AN - SCOPUS:3242805124

SN - 1600-5368

VL - 59

SP - m105-m107

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

(η³-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

Abstract

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