3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

Matthew D. Jones, Filipe A.Almeida Paz, John E. Davies, Brian F.G. Johnson

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Original languageEnglish
Pages (from-to)m105-m107
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number3
Early online date21 Feb 2003
DOIs
Publication statusPublished - 1 Mar 2003

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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