3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

Matthew D. Jones, Filipe A.Almeida Paz, John E. Davies, Brian F.G. Johnson

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Original languageEnglish
Pages (from-to)m105-m107
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number3
Early online date21 Feb 2003
DOIs
Publication statusPublished - 1 Mar 2003

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Palladium
Chelation
sulfonates
Anions
Cations
palladium
Hydrogen
Negative ions
Positive ions
Metals
Ligands
anions
cations
ligands
Geometry
hydrogen
geometry
metals
pyrrolidine
trifluoromethanesulfonic acid

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate. / Jones, Matthew D.; Paz, Filipe A.Almeida; Davies, John E.; Johnson, Brian F.G.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 59, No. 3, 01.03.2003, p. m105-m107.

Research output: Contribution to journalArticle

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abstract = "The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.",
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T1 - (η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)-pyrrolidine] palladium(II) trifluoromethane-sulfonate

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AU - Paz, Filipe A.Almeida

AU - Davies, John E.

AU - Johnson, Brian F.G.

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N2 - The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

AB - The title compound, [Pd(C3H5)(C9H 18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3- allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

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