β-Diketiminate C-H activation with heavier group 2 alkyls

Mark R. Crimmin; Anthony G.M. Barrett; Michael S. Hill; Dugald J. MacDougall; Mary F. Mahon; Panayiotis A. Procopiou

doi:10.1039/b917466b

β-Diketiminate C-H activation with heavier group 2 alkyls

Mark R. Crimmin, Anthony G.M. Barrett, Michael S. Hill, Dugald J. MacDougall, Mary F. Mahon, Panayiotis A. Procopiou

Research output: Contribution to journal › Article › peer-review

27 Citations (SciVal)

Abstract

Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe₃)₂}₂(THF)_n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

Original language	English
Pages (from-to)	9715-9717
Number of pages	3
Journal	Dalton Transactions
Issue number	44
DOIs	https://doi.org/10.1039/b917466b
Publication status	Published - 16 Nov 2009

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b917466b

Cite this

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title = "β-Diketiminate C-H activation with heavier group 2 alkyls",

abstract = "Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe3)2}2(THF)n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.",

author = "Crimmin, {Mark R.} and Barrett, {Anthony G.M.} and Hill, {Michael S.} and MacDougall, {Dugald J.} and Mahon, {Mary F.} and Procopiou, {Panayiotis A.}",

year = "2009",

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doi = "10.1039/b917466b",

language = "English",

pages = "9715--9717",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "44",

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T1 - β-Diketiminate C-H activation with heavier group 2 alkyls

AU - Crimmin, Mark R.

AU - Barrett, Anthony G.M.

AU - Hill, Michael S.

AU - MacDougall, Dugald J.

AU - Mahon, Mary F.

AU - Procopiou, Panayiotis A.

PY - 2009/11/16

Y1 - 2009/11/16

N2 - Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe3)2}2(THF)n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

AB - Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe3)2}2(THF)n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

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U2 - 10.1039/b917466b

DO - 10.1039/b917466b

M3 - Article

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SN - 1477-9226

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EP - 9717

JO - Dalton Transactions

JF - Dalton Transactions

IS - 44

ER -

β-Diketiminate C-H activation with heavier group 2 alkyls

Abstract

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

Sigma Delocalisation via Group 13 Homocatenation

Cite this

β-Diketiminate C-H activation with heavier group 2 alkyls

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Projects

Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

Sigma Delocalisation via Group 13 Homocatenation

Cite this