TY - JOUR
T1 - α-Fluorination of β-ketosulfones by Selectfluor™ F–TEDA–BF4
AU - Loghmani-Khouzani, Hossein
AU - Poorheravi, Mohammad R
AU - Sadeghi, Majid M M
AU - Caggiano, Lorenzo
AU - Jackson, Richard F W
PY - 2008
Y1 - 2008
N2 - Attempted fluorination of β-ketosulfides using Selectfluor™ resulted only in the isolation of the corresponding diaryl disulfides, presumed to arise by decomposition of an unstable fluorinated intermediate. However, fluorination of β-ketosulfones using Selectfluor™ under anhydrous conditions does allow the isolation of both mono-and difluorinated products in moderate to good yields.
AB - Attempted fluorination of β-ketosulfides using Selectfluor™ resulted only in the isolation of the corresponding diaryl disulfides, presumed to arise by decomposition of an unstable fluorinated intermediate. However, fluorination of β-ketosulfones using Selectfluor™ under anhydrous conditions does allow the isolation of both mono-and difluorinated products in moderate to good yields.
UR - http://www.scopus.com/inward/record.url?scp=45449083424&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1016/j.tet.2008.05.034
U2 - 10.1016/j.tet.2008.05.034
DO - 10.1016/j.tet.2008.05.034
M3 - Article
VL - 64
SP - 7419
EP - 7425
JO - Tetrahedron
JF - Tetrahedron
IS - 30-31
ER -