NEW FACILITIES FOR STUDYING SINGLE CRYSTALS UNDER A RANGE OF NON-AMBIENT CONDITIONS USING SR RADIATION

Project: Research council

Project Details

Description

The project is to develop instrumentation and methodologies for studying sub-100 micron crystals, using single crystal X-ray diffraction techniques and synchrotron radiation, under non-ambient conditions in order to understand structure/property correlations in a wide range of key materials ranging form sensors to pharmaceuticals. Environmental cells will be developed to apply low temperatures (below 30K), or moderate pressures at the crystal, or to expose the crystal to sound or microwaves to the crystal during data collection. Gas flow cells will also be developed so that chemical reactions between single crystals and gases can be monitored crystallographically; important applications here involve the development of gas storage devices and of establishing the nature of heterogeneous chemical reactions. Initial work will be carried out at the SRS, and then as the prototype cells are developed the instrumentation and methodologies will be transferred to the single crystal beamline, I19, on diamond, during 2008 when it becomes operational. In this way a unique facility for UK structural scientists and others will be provided, where it will be possible to study structures under change in real time. These developments will provide the users access to new techniques that are not currently possible at any other central facilities in the world.
StatusFinished
Effective start/end date9/10/068/01/10

Funding

  • Science & Technology Facilities Council (STFC)

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  • Research Output

    Photoactivated linkage isomerism in single crystals of nickel, palladium and platinum di-nitro complexes: A photocrystallographic investigation

    Warren, M. R., Brayshaw, S. K., Hatcher, L. E., Johnson, A. L., Schiffers, S., Warren, A. J., Woodall, C. H., Raithby, P. R., Teat, S. J. & Warren, J. E., 14 Nov 2012, In : Dalton Transactions. 41, 42, p. 13173-13179 7 p.

    Research output: Contribution to journalArticle

    Open Access
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  • 20 Citations (Scopus)
    119 Downloads (Pure)

    Photochemical-mediated solid-state [2+2]-cycloaddition reactions of an unsymmetrical dibenzylidene acetone (monothiophos-dba)

    Jarvis, A. G., Sparkes, H. A., Tallentire, S. E., Hatcher, L. E., Warren, M. R., Raithby, P. R., Allan, D. R., Whitwood, A. C., Cockett, M. C. R., Duckett, S. B., Clark, J. L. & Fairlamb, I. J. S., 7 Sep 2012, In : CrystEngComm. 14, 17, p. 5564-5571 8 p.

    Research output: Contribution to journalArticle

  • 15 Citations (Scopus)

    A prototype environmental gas cell for in situ small-molecule X-ray diffraction

    Warren, J. E., Pritchard, R. G., Abram, D., Davies, H. M., Savarese, T. L., Cash, R. J., Raithby, P. R., Morris, R., Jones, R. H. & Teat, S. J., 2009, In : Journal of Applied Crystallography. 42, p. 457-460 4 p.

    Research output: Contribution to journalArticle

  • 7 Citations (Scopus)