Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

Research output

Research output per year 2007 2008 2009 2010 2014

• 28 Article
• 3 Review article
• 1 Comment/debate

Research output per year

Research output per year

Search results

• 2014

  Dearomatized BIAN alkaline-earth alkyl catalysts for the intramolecular hydroamination of hindered aminoalkenes

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 13 Jan 2014, In: Organometallics. 33, 1, p. 206-216 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Alkaline Earth Metal 100%
  • Hydroamination 100%
  • Catalyst 100%
  • C-C Coupling Reaction 33%
  • Alkylation 33%

  40   Link opens in a new tab Citations (SciVal)

  449 Downloads (Pure)

• 2012

  Alkaline earth catalysis of alkynyl alcohol hydroalkoxylation/cyclization

  Brinkmann, C., Barrett, A. G. M., Reid, S., Hill, M. S. & Procopiou, P. A., 22 Oct 2012, In: Organometallics. 31, 20, p. 7287-7297 11 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis 100%
  • Alkaline Earth Metal 100%
  • Carboxamide 25%
  • Enol Ether 25%
  • Kinetic Study 25%

  45   Link opens in a new tab Citations (SciVal)

• Heavier alkaline earth catalysts for the intermolecular hydroamination of vinylarenes, dienes, and alkynes

  Brinkmann, C., Barrett, A. G. M., Hill, M. S. & Procopiou, P. A., 1 Feb 2012, In: Journal of the American Chemical Society. 134, 4, p. 2193-2207 15 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Hydroamination 100%
  • Vinylarene 100%
  • Alkyne 100%
  • Catalyst 100%

  180   Link opens in a new tab Citations (SciVal)

• 2011

  Cation charge density and precatalyst selection in group 2-catalyzed aminoalkene hydroamination

  Arrowsmith, M., Crimmin, M. R., Barrett, A. G. M., Hill, M. S., Kociok-Kohn, G. & Procopiou, P. A., 28 Mar 2011, In: Organometallics. 30, 6, p. 1493-1506 14 p.

  Research output: Contribution to journal › Article › peer-review

  • Hydroamination 100%
  • Charge Density 100%
  • pre-catalyst 100%
  • Cation 100%
  • Strontium 57%

  112   Link opens in a new tab Citations (SciVal)

• Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 28 Mar 2011, In: Organometallics. 30, 6, p. 1291-1294 4 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis 100%
  • Alkaline Earth Metal 100%
  • Hydroamination 50%
  • Catalyst Activity 50%

  62   Link opens in a new tab Citations (SciVal)

• 2010

  Calcium-centred phosphine oxide reactivity: P–C metathesis, reduction and P–P coupling

  Hill, M. S., Mahon, M. F. & Robinson, T. P., 2010, In: Chemical Communications. 46, 14, p. 2498-2500 3 p.

  Research output: Contribution to journal › Article › peer-review

  61   Link opens in a new tab Citations (SciVal)

• Carbodiimide insertion reactions of homoleptic heavier alkaline earth amides and phosphides

  Barrett, A. G. M., Crimmin, M. R., Hill, M., Hitchcock, P. B., Lomas, S. L., Mahon, M. F. & Procopiou, P. A., 21 Aug 2010, In: Dalton Transactions. 39, 31, p. 7393-7400 8 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Carboxamide 100%
  • Insertion Reaction 100%
  • Carbodiimide 100%
  • Strontium 16%

  42   Link opens in a new tab Citations (SciVal)

• Dearomatization and C-H deprotonation with heavier group 2 alkyls: does size matter?

  Arrowsmith, M., Hill, M. S. & Kociok-Kohn, G., 11 Oct 2010, In: Organometallics. 29, 19, p. 4203-4206 4 p.

  Research output: Contribution to journal › Article › peer-review

  • Deprotonation 100%
  • Pyridine 50%
  • Imine 50%
  • Alkaline Earth Metal 25%
  • Methyl Group 25%

  44   Link opens in a new tab Citations (SciVal)

• Group 2 promoted hydrogen release from NMe₂h·BH₃: intermediates and catalysis

  Liptrot, D. J., Hill, M. S., Mahon, M. F. & MacDougall, D. J., 26 Jul 2010, In: Chemistry - A European Journal. 16, 28, p. 8508-8515 8 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis 100%
  • Magnesium 100%
  • Hydrogen 100%
  • Alkaline Earth Metal 16%
  • Carboxamide 16%

  138   Link opens in a new tab Citations (SciVal)

• Group 3-centred dehydrocoupling of Me₂NH.BH₃

  Hill, M. S., Kociok-Kohn, G. & Robinson, T. P., 28 Oct 2010, In: Chemical Communications. 46, 40, p. 7587-7589 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Amine 100%
  • Carboxamide 100%
  • Borane 100%
  • Catalytic Reaction 100%
  • formation 100%

  69   Link opens in a new tab Citations (SciVal)

• Magnesium hydride-promoted dearomatisation of pyridine

  Hill, M., MacDougall, D. J. & Mahon, M. F., 2010, In: Dalton Transactions. 39, 46, p. 11129-11131 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Pyridine 100%
  • Magnesium 100%
  • Magnesium Derivative 50%
  • Heterocyclic Compound 33%
  • Chemical Kinetics Characteristics 33%

  73   Link opens in a new tab Citations (SciVal)

• Nanostructured hybrid polymer-inorganic solar cell active layers formed by controllable in situ growth of semiconducting sulfide networks

  Leventis, H. C., King, S. P., Sudlow, A., Hill, M., Molloy, K. C. & Haque, S. A., 14 Apr 2010, In: Nano Letters. 10, 4, p. 1253-1258 6 p.

  Research output: Contribution to journal › Article

  • Nanocomposite Film 100%
  • Polymer Films 100%
  • Solar Cell 100%
  • Inorganic Polymer 100%
  • Sulfide 100%

  222   Link opens in a new tab Citations (SciVal)

• Synthesis of β-diketiminato calcium silylamides and their reactions with triethylaluminium

  Crimmin, M. R., Hill, M., Hitchcock, P. B. & Mahon, M. F., Aug 2010, In: New Journal of Chemistry. 34, 8, p. 1572-1578 7 p.

  Research output: Contribution to journal › Article › peer-review

  • Carboxamide 100%
  • NMR Spectroscopy 100%
  • Ambient Reaction Temperature 100%
  • Ethyl Group 100%

  37   Link opens in a new tab Citations (SciVal)

• 2009

  A hydride-rich magnesium cluster

  Arrowsmith, M., Hill, M. S., MacDougall, D. J. & Mahon, M. F., 18 May 2009, In: Angewandte Chemie International Edition. 48, 22, p. 4013-4016 4 p.

  Research output: Contribution to journal › Article › peer-review

  121   Link opens in a new tab Citations (SciVal)

• Alkali and alkaline-earth metals

  Hill, M. S., 31 Jul 2009, In: Annual Reports on the Progress of Chemistry - Section A. 105, p. 55-74 20 p.

  Research output: Contribution to journal › Review article › peer-review

  • Coordination Compound 100%
  • Alkaline Earth Metal 100%

  4   Link opens in a new tab Citations (SciVal)

• Bis(imidazolin-2-ylidene-1-yl)borate Complexes of the Heavier Alkaline Earths: Synthesis and Studies of Catalytic Hydroamination

  Arrowsmith, M., Hill, M. & Kociok-Kohn, G., 2009, In: Organometallics. 28, 6, p. 1730-1738 9 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Hydroamination 100%
  • Borate 100%
  • Donor 66%
  • N-Heterocyclic Carbene 66%

  106   Link opens in a new tab Citations (SciVal)

• Catalytic 2,3,4-hexatriene formation by terminal alkyne coupling at calcium

  Barrett, A. G. M., Crimmin, M. R., Hill, M. S., Hitchcock, P. B., Lomas, S. L., Procopiou, P. A. & Suntharalingam, K., 2009, In: Chemical Communications. 17, p. 2299-2301 3 p.

  Research output: Contribution to journal › Article › peer-review

  36   Link opens in a new tab Citations (SciVal)

• Heavier group 2 metals and intermolecular hydroamination: a computational and synthetic assessment

  Barrett, A. G. M., Brinkmann, C., Crimmin, M. R., Hill, M. S., Hunt, P. & Procopiou, P. A., 16 Sept 2009, In: Journal of the American Chemical Society. 131, 36, p. 12906-12907 2 p.

  Research output: Contribution to journal › Article › peer-review

  • Hydroamination 100%
  • Catalysis 33%
  • Alkaline Earth Metal 33%
  • Carboxamide 33%
  • Alkene 33%

  126   Link opens in a new tab Citations (SciVal)

• Intramolecular hydroamination of aminoalkenes by calcium and magnesium complexes: a synthetic and mechanistic study

  Crimmin, M. R., Arrowsmith, M., Barrett, A. G. M., Casely, I. J., Hill, M. S. & Procopiou, P. A., 22 Jul 2009, In: Journal of the American Chemical Society. 131, 28, p. 9670-9685 16 p.

  Research output: Contribution to journal › Article › peer-review

  • Magnesium 100%
  • Hydroamination 100%
  • Mechanistic Study 100%
  • pre-catalyst 100%
  • Alkene 66%

  265   Link opens in a new tab Citations (SciVal)

• Tris(imidazolin-2-ylidene-1-yl)borate complexes of the heavier alkaline earths: Synthesis and structural studies

  Arrowsmith, M., Heath, A., Hill, M. S., Hitchcock, P. B. & Kociok-Köhn, G., 10 Aug 2009, In: Organometallics. 28, 15, p. 4550-4559 10 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Tris 100%
  • Borate 100%
  • Strontium 66%
  • Halide 66%

  62   Link opens in a new tab Citations (SciVal)

• β-Diketiminate C-H activation with heavier group 2 alkyls

  Crimmin, M. R., Barrett, A. G. M., Hill, M. S., MacDougall, D. J., Mahon, M. F. & Procopiou, P. A., 16 Nov 2009, In: Dalton Transactions. 44, p. 9715-9717 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Methyl Group 100%

  28   Link opens in a new tab Citations (SciVal)

• β-Diketiminato Calcium and Magnesium Amides; Model Complexes for Hydroamination Catalysis

  Barrett, A. G. M., Casely, I. J., Crimmin, M. R., Hill, M., Lachs, J. R., Mahon, M. F. & Procopiou, P. A., 2009, In: Inorganic Chemistry. 48, 10, p. 4445-4453 9 p.

  Research output: Contribution to journal › Article › peer-review

  • Catalysis 100%
  • Carboxamide 100%
  • Magnesium 100%
  • Hydroamination 100%
  • NMR Spectroscopy 28%

  70   Link opens in a new tab Citations (SciVal)

• 2008

  Alkali and alkaline earth metals

  Hill, M. S., 2008, In: Annual Reports on the Progress of Chemistry - Section A. 104, p. 64-80 17 p.

  Research output: Contribution to journal › Review article › peer-review

  • Alkaline Earth Metal 100%
  • Coordination Chemistry 25%
  • Solid-State Chemistry 25%
  • Organometallic Chemistry 25%
  • Theoretical Chemistry 25%

  1   Link opens in a new tab Citation (SciVal)

• beta-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon-Carbon Bond Formation

  Barrett, A. G. M., Crimmin, M. R., Hill, M. S., Hitchcock, P. B., Lomas, S. L., Mahon, M. F., Procopiou, P. A. & Suntharalingam, K., 2008, In: Organometallics. 27, 23, p. 6300-6306 7 p.

  Research output: Contribution to journal › Article › peer-review

  • Acetylide 100%
  • Dimerization 100%
  • formation 100%
  • Carboxamide 40%
  • Hydrocarbon 40%

  61   Link opens in a new tab Citations (SciVal)

• Bis(trimethylsilyl)methyl Derivatives of Calcium, Strontium and Barium: Potentially Useful Dialkyls of the Heavy Alkaline Earth Elements

  Crimmin, M. R., Barrett, A. G. M., Hill, M., Macdougall, D. J., Mahon, M. F. & Procopiou, P. A., 2008, In: Chemistry - A European Journal. 14, 36, p. 11292-11295 4 p.

  Research output: Contribution to journal › Article › peer-review

  96   Link opens in a new tab Citations (SciVal)

• Heavier group 2 element-catalysed hydroamination of isocyanates

  Barrett, A. G. M., Boorman, T. C., Crimmin, M. R., Hill, M. S., Kociok-Köhn, G. & Procopiou, P. A., 2008, In: Chemical Communications. 41, p. 5206-5208 3 p.

  Research output: Contribution to journal › Article › peer-review

  • Carboxamide 100%
  • Isocyanic Acid Derivative 100%
  • Alkaline Earth Metal 50%

  56   Link opens in a new tab Citations (SciVal)

• Heavier group-2-element catalyzed hydroamination of carbodiimides

  Lachs, J. R., Barrett, A. G. M., Crimmin, M. R., Kociok-Köhn, G., Hill, M. S., Mahon, M. F. & Procopiou, P. A., 1 Sept 2008, In: European Journal of Inorganic Chemistry. 26, p. 4173-4179 7 p.

  Research output: Contribution to journal › Article › peer-review

  • Alkaline Earth Metal 100%
  • Carboxamide 100%
  • Hydroamination 100%
  • Carbodiimide 100%
  • Ambient Reaction Temperature 50%

  80   Link opens in a new tab Citations (SciVal)

• Heavier group 2 element catalyzed hydrophosphination of carbodiimides

  Crimmin, M. R., Barrett, A. G. M., Hill, M. S., Hitchcock, P. B. & Procopiou, P. A., 2008, In: Organometallics. 27, 4, p. 497-499 3 p.

  Research output: Contribution to journal › Article › peer-review

  144   Link opens in a new tab Citations (SciVal)

• Insertion reactions of β-diketiminate-stabilised calcium amides with 1,3-dialkylcarbodiimides

  Barrett, A. G. M., Crimmin, M. R., Hill, M. S., Hitchcock, P. B. & Procopiou, P. A., 20 Aug 2008, In: Dalton Transactions. 33, p. 4474-4481 8 p.

  Research output: Contribution to journal › Article › peer-review

  • Carboxamide 100%
  • Insertion Reaction 100%
  • Isopropyl Group 50%
  • Nitrogen 50%
  • Ambient Reaction Temperature 50%

  24   Link opens in a new tab Citations (SciVal)

• Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine

  Barrett, A. G. M., Crimmin, M. R., Hill, M. S., Kociok-Köhn, G., Lachs, J. R. & Procopiou, P. A., 4 Feb 2008, In: Journal of the Chemical Society. Dalton Transactions. 10, p. 1292-1294 3 p.

  Research output: Contribution to journal › Comment/debate › peer-review

  • Carboxamide 100%
  • Benzylamine 100%

  18   Link opens in a new tab Citations (SciVal)

• Triazenide complexes of the heavier alkaline earths: synthesis, characterization, and suitability for hydroamination catalysis

  Barrett, A. G. M., Crimmin, M. R., Hill, M. S., Hitchcock, P. B., Kociok-Köhn, G. & Procopiou, P. A., 2008, In: Inorganic Chemistry. 47, 16, p. 7366-7376 11 p.

  Research output: Contribution to journal › Article › peer-review

  140   Link opens in a new tab Citations (SciVal)

• 2007

  Alkali and alkaline-earth metals

  Hill, M. S., 1 Jan 2007, In: Annual Reports on the Progress of Chemistry - Section A. 103, p. 39-53 15 p.

  Research output: Contribution to journal › Review article › peer-review

  • Alkaline Earth Metal 100%
  • Chemistry 50%

  2   Link opens in a new tab Citations (SciVal)