• WESSEX HOUSE 1.27

Accepting PhD Students

20062023
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Research Output 2006 2019

2019

Evidence for tetranuclear bis-μ-oxo cubane species in molecular iridium-based water oxidation catalysts from XAS analysis

Bartlett, S. A., Sackville, E. V., Gibson, E. K., Celorrio, V., Wells, P. P., Nachtegaal, M., Sheehan, S. W. & Hintermair, U., 19 Jun 2019, In : Chemical communications (Cambridge, England). 55, 54, p. 7832-7835 4 p.

Research output: Contribution to journalArticle

Open Access
1 Citation (Scopus)
15 Downloads (Pure)

Graphite-protected CsPbBr3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in water

Poli, I., Hintermair, U., Regue, M., Kumar, S., Sackville, E. V., Baker, J., Watson, T. M., Eslava, S. & Cameron, P. J., 8 May 2019, In : Nature Communications. 10, 1, 10 p., 2097.

Research output: Contribution to journalArticle

Open Access
File

Inexpensive Metal Free Encapsulation Layers Enable Halide Perovskite Based Photoanodes for Water Splitting

Poli, I., Hintermair, U., Regue Grino, M., Kumar, S., Sackville, E., Baker, J., Watson, T. M., Eslava, S. & Cameron, P., 12 May 2019.

Research output: Contribution to conferencePoster

In-Situ Monitoring of Nanoparticle Formation during Iridium-Catalysed Oxygen Evolution by Real-Time Small Angle X-Ray Scattering

Singer Hobbs, M., Sackville, E. V., Smith, A. J., Edler, K. J. & Hintermair, U., 19 Aug 2019, In : ChemCatChem. 11, p. 1-10 11 p.

Research output: Contribution to journalArticle

Open Access
31 Downloads (Pure)
Open Access
File
9 Downloads (Pure)

Synthesis of organometallic pentalenide complexes

Boyt, S. M., Jenek, N. A. & Hintermair, U., 28 Apr 2019, In : Dalton Transactions . 48, 16, p. 5107-5124 18 p.

Research output: Contribution to journalArticle

Open Access
File
2018
2 Citations (Scopus)
14 Downloads (Pure)

Electrochemical and Kinetic Insights into Molecular Water Oxidation Catalysts Derived from Cp*Ir(pyridine-alkoxide) Complexes

Sackville, E. V., Marken, F. & Hintermair, U., 10 Sep 2018, In : ChemCatChem. 10, 19, p. 4280-4291 12 p.

Research output: Contribution to journalArticle

Open Access
File
alkoxides
Pyridine
pyridines
catalysts
Oxidation
5 Citations (Scopus)

Online monitoring of a photocatalytic reaction by real-time high resolution FlowNMR spectroscopy

Hall, A. M. R., Broomfield-Tagg, R., Camilleri, M., Carbery, D. R., Codina, A., Whittaker, D. T. E., Coombes, S., Lowe, J. P. & Hintermair, U., 4 Jan 2018, In : Chemical communications (Cambridge, England). 54, 1, p. 30-33 4 p.

Research output: Contribution to journalArticle

Open Access
Imines
Photooxidation
Photochemical reactions
Eosine Yellowish-(YS)
Photocatalysts
2017
9 Citations (Scopus)
51 Downloads (Pure)

Controlled Formation of Hierarchical Metal-Organic Frameworks Using CO2-Expanded Solvent Systems

Doan, H. V., Fang, Y., Yao, B., Dong, Z., White, T. J., Sartbaeva, A., Hintermair, U. & Ting, V. P., 5 Sep 2017, In : ACS Sustainable Chemistry and Engineering. 5, 9, p. 7887-7893 7 p.

Research output: Contribution to journalArticle

Open Access
File
Carbon Monoxide
Metals
metal
Crystallization
crystallization
4 Citations (Scopus)
30 Downloads (Pure)

Ligand Tuning in Pyridine-Alkoxide Ligated Cp*Ir III Oxidation Catalysts

Sackville, E. V., Kociok-Köhn, G. & Hintermair, U., 25 Sep 2017, In : Organometallics. 36, 18, p. 3578-3588 11 p.

Research output: Contribution to journalArticle

Open Access
File
alkoxides
pyridines
Tuning
tuning
Ligands
2016
14 Citations (Scopus)
28 Downloads (Pure)
Open Access
File
Iridium
Hematite
hematite
iridium
catalysts
13 Citations (Scopus)
21 Downloads (Pure)

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Naeem, A., Ting, V. P., Hintermair, U., Tian, M., Telford, R., Halim, S., Nowell, H., Hołyńska, M., Teat, S. J., Scowen, I. J. & Nayak, S., 25 Jun 2016, In : Chemical Communications. 52, 50, p. 7826-7829 4 p.

Research output: Contribution to journalArticle

Open Access
File
Hydrogen storage
Zirconium
Metals
Acids
Hydrogen
72 Downloads (Pure)

Practical aspects of real-time reaction monitoring using multi-nuclear high resolution FlowNMR spectroscopy

Hall, A. M. R., Chouler, J. C., Codina, A., Gierth, P. T., Lowe, J. P. & Hintermair, U., 21 Dec 2016, In : Catalysis Science and Technology. 6, 24, p. 8406-8417

Research output: Contribution to journalArticle

Open Access
File
Spectroscopy
Monitoring
Spectrometers
Nuclear magnetic resonance
Availability
2015
65 Citations (Scopus)
45 Downloads (Pure)

A molecular catalyst for water oxidation that binds to metal oxide surfaces

Sheehan, S. W., Thomsen, J. M., Hintermair, U., Crabtree, R. H., Brudvig, G. W. & Schmuttenmaer, C. A., 11 Mar 2015, In : Nature Communications. 6, p. 1-9 9 p., 6469.

Research output: Contribution to journalArticle

Open Access
Oxides
metal oxides
Metals
catalysts
Oxidation
9 Citations (Scopus)
23 Downloads (Pure)
Open Access
File
Catalysis
Supercritical fluids
supercritical fluids
Catalyst
catalysis
2014
47 Citations (Scopus)
31 Downloads (Pure)

Catalyst activation by loss of cyclopentadienyl ligands in hydrogen transfer catalysis with Cp*IrIII complexes

Campos, J., Hintermair, U., Brewster, T. P., Takase, M. K. & Crabtree, R. H., 7 Mar 2014, In : ACS Catalysis. 4, 3, p. 973-985 13 p.

Research output: Contribution to journalArticle

Open Access
File
Catalysis
Hydrogen
Chemical activation
Ligands
Iridium

Continuous-flow hydrogenation of CO2 using molecular catalysts

Wesselbaum, S., Vom Stein, T., Hintermair, U., Klankermayer, J. & Leitner, W., Sep 2014, In : Chemie Ingenieur Technik. 86, 9, p. 1428

Research output: Contribution to journalArticle

Carbon Monoxide
Ionic liquids
Hydrogenation
Ionic Liquids
Catalysts
74 Citations (Scopus)
27 Downloads (Pure)

Electrochemical activation of cp∗ iridium complexes for electrode-driven water-oxidation catalysis

Thomsen, J. M., Sheehan, S. W., Hashmi, S. M., Campos, J., Hintermair, U., Crabtree, R. H. & Brudvig, G. W., 1 Oct 2014, In : Journal of the American Chemical Society. 136, 39, p. 13826-13834 9 p.

Research output: Contribution to journalArticle

Open Access
File
Iridium
Catalysis
Electrodes
Chemical activation
Oxidation
55 Citations (Scopus)
29 Downloads (Pure)

Hydrogen-transfer catalysis with Cp*IrIII complexes: The influence of the ancillary ligands

Hintermair, U., Campos, J., Brewster, T. P., Pratt, L. M., Schley, N. D. & Crabtree, R. H., 3 Jan 2014, In : ACS Catalysis. 4, 1, p. 99-108 10 p.

Research output: Contribution to journalArticle

Open Access
File
Catalysis
Hydrogen
Bearings (structural)
Ligands
Iridium

Iridium Complexes for Electrocatalysis

Hintermair, U., Sheehan, S. W., Thomsen, J. M., Brudvig, G. W. & Crabtree, R. H., 27 Jun 2014, IPC No. US patent, Patent No. 14/317,906, Priority date 27 Jun 2014

Research output: Patent

Iridium
Electrocatalysis
Oxidation
Corrosion protection
Patents and inventions
37 Citations (Scopus)
29 Downloads (Pure)

Modes of activation of organometallic iridium complexes for catalytic water and C–H oxidation

Ingram, A. J., Wolk, A. B., Flender, C., Zhang, J., Johnson, C. J., Hintermair, U., Crabtree, R. H., Johnson, M. A. & Zare, R. N., 6 Jan 2014, In : Inorganic Chemistry. 53, 1, p. 423-433 12 p.

Research output: Contribution to journalArticle

Open Access
File
Iridium
Organometallics
iridium
Chemical activation
activation
2013
46 Citations (Scopus)
Ionic Liquids
Carbon Monoxide
Catalysis
Hydrogenation
Rhodium
44 Citations (Scopus)

Cp* iridium precatalysts for selective C–H oxidation with sodium periodate as the terminal oxidant

Zhou, M., Hintermair, U., Hashiguchi, B. G., Parent, A. R., Hashmi, S. M., Elimelech, M., Periana, R. A., Brudvig, G. W. & Crabtree, R. H., 25 Feb 2013, In : Organometallics. 32, 4, p. 957-965 9 p.

Research output: Contribution to journalArticle

Iridium
iridium
Oxidants
sodium
Oxidation
135 Citations (Scopus)
68 Downloads (Pure)

Precursor transformation during molecular oxidation catalysis with organometallic iridium complexes

Hintermair, U., Sheehan, S. W., Parent, A. R., Ess, D. H., Richens, D. T., Vaccaro, P. H., Brudvig, G. W. & Crabtree, R. H., 24 Jul 2013, In : Journal of the American Chemical Society. 135, 29, p. 10837-10851 15 p.

Research output: Contribution to journalArticle

Open Access
File
Iridium
Organometallics
Catalysis
Ligands
Oxidation
32 Citations (Scopus)
61 Downloads (Pure)

Probing the viability of oxo-coupling pathways in iridium-catalyzed oxygen evolution

Graeupner, J., Hintermair, U., Huang, D. L., Thomsen, J. M., Takase, M., Campos, J., Hashmi, S. M., Elimelech, M., Brudvig, G. W. & Crabtree, R. H., 14 Oct 2013, In : Organometallics. 32, 19, p. 5384–5390

Research output: Contribution to journalArticle

Open Access
File
Iridium
iridium
viability
Dimers
dimers
2012

CO2 Hydrogenation Method for Producing Formic Acid

Leitner, W., Hintermair, U. & Wesselbaum, S., 19 Jul 2012, IPC No. C07C51/083; C07C53/02, Patent No. WO2012095345

Research output: Patent

formic acid
Hydrogenation
Patents and inventions
105 Citations (Scopus)
formic acid
Ionic Liquids
Hydrogenation
Ruthenium
Carbon Dioxide
112 Citations (Scopus)

Particle formation during oxidation catalysis with Cp* iridium complexes

Hintermair, U., Hashmi, S. M., Elimelech, M. & Crabtree, R. H., 13 Jun 2012, In : Journal of the American Chemical Society. 134, 23, p. 9785-9795 11 p.

Research output: Contribution to journalArticle

Iridium
Catalysis
Light scattering
Oxidation
Nanoparticles
5 Citations (Scopus)

Transition-metal complexes in supported liquid phase and supercritical fluids: A beneficial combination for selective continuous-flow catalysis with integrated product separation

Hintermair, U., Chinnusamy, T. & Leitner, W., 17 Apr 2012, New Strategies in Synthesis and Catalysis. Pignataro, B. (ed.). Weinheim: Wiley-VCH, p. 273-297

Research output: Chapter in Book/Report/Conference proceedingChapter

2011
19 Citations (Scopus)

A versatile lab to pilot scale continuous reaction system for supercritical fluid processing

Hintermair, U., Roosen, C., Kaever, M., Kronenberg, H., Thelen, R., Aey, S., Leitner, W. & Greiner, L., 18 Nov 2011, In : Organic Process Research & Development. 15, 6, p. 1275-1280 6 p.

Research output: Contribution to journalArticle

Supercritical fluids
supercritical fluids
Catalysis
catalysis
Phase behavior
66 Citations (Scopus)

Continuous flow organometallic catalysis: New wind in old sails

Hintermair, U., Franciò, G. & Leitner, W., 7 Apr 2011, In : Chemical Communications. 47, 13, p. 3691-3701 11 p.

Research output: Contribution to journalArticle

Organometallics
Catalysis
Supercritical fluids
Recovery
Catalysts
44 Citations (Scopus)

Distinct reactivity of mono- and bis-NHC silver complexes: Carbene donors versus carbene–halide exchange reagents

Hintermair, U., Englert, U. & Leitner, W., 25 Jul 2011, In : Organometallics. 30, 14, p. 3726-3731

Research output: Contribution to journalArticle

carbenes
Silver
halides
reagents
Ion exchange
2010
11 Citations (Scopus)

Biphasic and flow systems involving water or supercritical fluids

Desset, S. L., Hintermair, U., Gong, Z., Santini, C. C. & Cole-Hamilton, D. J., 1 Aug 2010, In : Topics in Catalysis. 53, 13-14, p. 963-968 6 p.

Research output: Contribution to journalArticle

Supercritical fluids
Hydroformylation
Catalysts
Water
Toluene
70 Citations (Scopus)

Continuous enantioselective hydrogenation with a molecular catalyst in supported ionic liquid phase under supercritical CO2 flow

Hintermair, U., Höfener, T., Pullmann, T., Franciò, G. & Leitner, W., 8 Feb 2010, In : ChemCatChem. 2, 2, p. 150-154 5 p.

Research output: Contribution to journalArticle

Ionic Liquids
Rhodium
Carbon Monoxide
rhodium
Ionic liquids
47 Citations (Scopus)

Continuous flow hydroformylation using supported ionic liquid phase catalysts with carbon dioxide as a carrier

Hintermair, U., Gong, Z., Serbanovic, A., Muldoon, M. J., Santini, C. C. & Cole-Hamilton, D. J., 28 Sep 2010, In : Dalton Transactions. 39, 36, p. 8501-8510 10 p.

Research output: Contribution to journalArticle

Hydroformylation
Ionic Liquids
Carbon Dioxide
Catalysts
Reaction rates

Expanded liquid phases in catalysis: Gas-expanded liquids and liquid-supercritical fluid biphasic systems

Hintermair, U., Leitner, W. & Jessop, P., 15 Jul 2010, Handbook of Green Chemistry: Supercritical Solvents. Wiley-VCH, Vol. 4. p. 103-188

Research output: Chapter in Book/Report/Conference proceedingChapter

2008
34 Citations (Scopus)

Direct in situ synthesis of cationic N-heterocyclic carbene iridium and rhodium complexes from neat ionic liquid: Application in catalytic dehydrogenation of cyclooctadiene

Hintermair, U., Gutel, T., Slawin, A. M. Z., Cole-Hamilton, D. J., Santini, C. C. & Chauvin, Y., 1 Jul 2008, In : Journal of Organometallic Chemistry. 693, 14, p. 2407-2414 8 p.

Research output: Contribution to journalArticle

Ionic Liquids
Iridium
Rhodium
phosphine
carbenes
2007
83 Citations (Scopus)

Supported ionic liquid phase catalysis with supercritical flow

Hintermair, U., Zhao, G., Santini, C. C., Muldoon, M. J. & Cole-Hamilton, D. J., 2007, In : Chemical Communications. 2007, 14, p. 1462-1464

Research output: Contribution to journalArticle

Ionic Liquids
Ionic liquids
Catalysis
Hydroformylation
Rhodium
2006
1 Citation (Scopus)

Novel reaction engineering concepts for catalyst immobilisation in hydroformylation

Cole-Hamilton, D. J., Desset, S. L., Hintermair, U., Santini, C. C. & Muldoon, M. J., 1 Dec 2006, In : DGMK Tagungsbericht. 4, p. 41-52 12 p.

Research output: Contribution to journalArticle