Projects per year
Personal profile
Research interests
A large variety of N-substituted 1,3,5-triazacyclohexanes (R3TAC) can be easily prepared from formaldehyde and primary amines. We are investigating the general coordination chemistry with transition metal ranging from the lanthanides to zinc. We are examining the complexes mainly by X-ray crystallography, UV/visible, IR, Raman, and NMR spectroscopy.
R3TAC occupies three coordination sites of the metal with unusually small N-metal-N angles of 60-65°. This leads to low steric demand of the ligand and allows the preparation of unusual complexes and increased catalytic activity in general.
Research Interests
- Catalysis of Polymerisation and Trimerisation of Olefin
- Bio-Analogous Copper Complexes for Oxygen Activation
- Transition Metal Clusters
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Projects
- 4 Finished
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International Research Initiator Scheme 2015-2016
Kohn, R. (PI) & Yang, Y. (CoI)
1/04/16 → 30/04/16
Project: Research-related funding
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HIGH RESOLUTION MASS SPECTROMETERS TO SUPPORT CHEMISTRY AT B ATH
James, T. (PI), Bull, S. (CoI), Davidson, M. (CoI), Frost, C. (CoI), Kohn, R. (CoI), Molloy, K. C. (CoI), Weller, A. (CoI), Whittlesey, M. (CoI), Williams, J. (CoI) & Willis, M. C. (CoI)
Engineering and Physical Sciences Research Council
9/10/06 → 8/10/09
Project: Research council
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500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY
Whittlesey, M. (PI), Danson, M. (CoI), Frost, C. (CoI), Kohn, R. (CoI), Lowe, J. (CoI), Weller, A. (CoI) & Williams, J. (CoI)
Engineering and Physical Sciences Research Council
12/06/06 → 11/06/09
Project: Research council
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TRIAZACYCLOHEXANES AS LIGANDS FOR TRIANGULAR TRIMETAL COMPLE XES
Kohn, R. (PI)
Engineering and Physical Sciences Research Council
1/07/04 → 30/06/08
Project: Research council
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New di-n-butyltin(iv)-bis-(1-alkoxy-isoquinoline-4-nitrile thiolate): crystallographic and computational studies
Singh, A., Singh, A., Srivastava, D., Kociok-Köhn, G., Köhn, R. D., Kumar, A. & Muddassir, M., 21 Jun 2022, In: CrystEngComm. 24, 23, p. 4274-4282 9 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile8 Citations (SciVal)21 Downloads (Pure) -
Triazacyclohexane Chromium Triflate Complexes as Precursors for the Catalytic Selective Olefin Trimerisation and its Investigation by Mass Spectrometry
Köhn, R., Coxon, A., Chunawat, S., Heron, C., Mihan, S., Lyall, C., Reeksting, S. & Kociok-Kohn, G., 15 Jul 2020, In: Polyhedron. 185, 114572.Research output: Contribution to journal › Article › peer-review
Open AccessFile4 Citations (SciVal)202 Downloads (Pure) -
Antibacterial Activities of New Saturated Heterocyclic Nitrogen Compounds
Lefrada, L., Köhn, R., Malki, S., Mazouz, W., Bouchemma, A. & Hadjem, M., 11 Sept 2017, In: Algerian Journal of Natural Products. 5, 2, p. 463-468Research output: Contribution to journal › Article › peer-review
Open Access -
Synthesis and antimicrobial activity of 1,3-bis-butyl-5-(4-iodophenyl)-1,3,5-triazacyclohexane
Lefrada, L., Kohn, R., Malki, S., Mazouz, W., Bouchemma, A. & Hadjem, M., 31 Mar 2017, In: Central European Journal of Chemistry. 8, 1, p. 82-84Research output: Contribution to journal › Article › peer-review
Open Access -
Efficient 1-hexene trimerization with triazacyclohexane chromium catalysts and detailed product analysis by 13C NMR
Coxon, A. G. N. & Kohn, R. D., 6 May 2016, In: ACS Catalysis. 6, 5, p. 3008-3016 9 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile17 Citations (SciVal)909 Downloads (Pure)