Projects per year
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Research interests
Our interests lie in the organometallic and coordination chemistry of late transition metals. We have a particular focus on bond activation reactions (e.g. C-H activation) in both stoichiometric and catalytic processes.
We employ a combination of Schlenk, vacuum line and glove box techniques for the manipulation of air and water sensitive compounds, replying heavily on multinuclear NMR spectroscopy, IR spectroscopy and X-ray crystallography for characterisation.
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Dual Unsaturated TM-M' Heterobimetallic Complexes for Cooperative Activation and Catalysis
Engineering and Physical Sciences Research Council
6/07/20 → 5/07/23
Project: Research council
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EU Marie Curie Individual Fellowship - Maia Espinal - Low Coordinate TM Magnets
13/02/17 → 27/08/19
Project: EU Commission
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Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands
Isaac, C. J., Wilson, C. I., Burnage, A. L., Miloserdov, F., Mahon, M. F., Macgregor, S. A. & Whittlesey, M. K., 19 Dec 2022, In: Inorganic Chemistry. 61, 50, p. 20690-20698 9 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile1 Downloads (Pure) -
Extreme g-tensor anisotropy and its insensitivity to structural distortions in a family of linear two-coordinate Ni(I) bis-N-heterocyclic carbene complexes
Blackaby, W. J. M., Harriman, K. L. M., Greer, S. M., Folli, A., Hill, S., Krewald, V., Mahon, M. F., Murphy, D. M., Murugesu, M., Richards, E., Suturina, E. & Whittlesey, M. K., 24 Jan 2022, In: Inorganic Chemistry. 61, 3, p. 1308-1315 8 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile2 Downloads (Pure) -
Structure and Reactivity of [Ru-Al] and [Ru-Sn] Heterobimetallic PPh3-Based Complexes
Isaac, C., Miloserdov, F., Pecharman, A-F., Lowe, J., McMullin, C. & Whittlesey, M., 10 Oct 2022, In: Organometallics. 41, 19, p. 2716-2730 15 p.Research output: Contribution to journal › Article › peer-review
Open Access -
Zinc-Promoted ZnMe/ZnPh Exchange in Eight-Coordinate [Ru(PPh3)2(ZnMe)4H2]
Sotorrios, L., Miloserdov, F., Pecharman, A-F., Lowe, J., Macgregor, S., Mahon, M. & Whittlesey, M., 2 May 2022, In: Angewandte Chemie-International Edition. 61, 19, e202117495.Research output: Contribution to journal › Article › peer-review
Open Access -
[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
Sabater, S., Schmidt, D., Schmidt, H., Kuntze-Fechner, M., Zell, T., Isaac, C., Rajabi, N., Grieve, H., Blackaby, W., Lowe, J., Macgregor, S., Mahon, M., Radius, U. & Whittlesey, M., 15 Sep 2021, In: Chemistry - A European Journal. 27, p. 13221-13234Research output: Contribution to journal › Article › peer-review
Open AccessFile1 Citation (SciVal)11 Downloads (Pure)