Projects per year
Personal profile
Research interests
Our interests lie in the organometallic and coordination chemistry of late transition metals. We have a particular focus on bond activation reactions (e.g. C-H activation) in both stoichiometric and catalytic processes.
We employ a combination of Schlenk, vacuum line and glove box techniques for the manipulation of air and water sensitive compounds, replying heavily on multinuclear NMR spectroscopy, IR spectroscopy and X-ray crystallography for characterisation.
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Collaborations and top research areas from the last five years
Projects
- 13 Finished
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Dual Unsaturated TM-M' Heterobimetallic Complexes for Cooperative Activation and Catalysis
Whittlesey, M. (PI)
Engineering and Physical Sciences Research Council
6/07/20 → 5/07/23
Project: Research council
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Hub 'Science' 3: Catalysis for the Circular Economy and Sustainable Manufacturing - WP4: Earth-abundant metals in resource efficient catalysis
Webster, R. (PI), Davidson, M. (CoI), Hill, M. (CoI) & Whittlesey, M. (CoI)
Engineering and Physical Sciences Research Council
1/05/19 → 30/04/21
Project: Research council
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Ru-Zn Heterobimetallic Complexes (Marie Curie IF)
Whittlesey, M. (PI)
1/06/18 → 31/07/20
Project: EU Commission
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EU Marie Curie Individual Fellowship - Maia Espinal - Low Coordinate TM Magnets
Whittlesey, M. (PI)
13/02/17 → 27/08/19
Project: EU Commission
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Single Molecule Magnets (Dr Sara Sabater)
Whittlesey, M. (PI)
1/03/16 → 28/02/18
Project: Research council
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ZnH2 as a precursor to catalytically active Ru-ZnH heterometallic complexes
Pecharman, A.-F., Carpentier, A., Lowe, J. P., MacGregor, S., Mahon, M. F. & Whittlesey, M., 3 Mar 2025, In: Inorganic Chemistry. 64, 8, p. 4043-4051Research output: Contribution to journal › Article › peer-review
Open Access -
Isolobal Cationic Iridium Dihydride and Dizinc Complexes: A Dual Role for the ZnR Ligand Enhances H2 Activation
Walsh, A., Sotorrios, L., Cameron, R., Pecharman, A.-F., Procacci, B., Lowe, J., Macgregor, S., Mahon, M., Hunt, N. & Whittlesey, M., 2 Dec 2024, In: Inorganic Chemistry. 63, 48, p. 22944-22954Research output: Contribution to journal › Article › peer-review
Open Access1 Citation (SciVal) -
Isolation of Bis- and Mono-Cyclometallated Ru-IMes Complexes Upon Reaction of [Ru(PPh3)3HCl], IMes and ZnMe2
Pecharman, A.-F., Roberts, E., Miloserdov, F., Varela-Izquierdo, V., Mahon, M. & Whittlesey, M., 25 Apr 2023, In: European Journal of Inorganic Chemistry. e202300037.Research output: Contribution to journal › Article › peer-review
Open Access2 Citations (SciVal) -
Reactions of a P-N Stabilised Aluminium Dihydride with Ruthenium Hydride Complexes
Pecharman, A.-F., Falconer, R., Owen, E., Cowley, M., Lowe, J., McMullin, C., Mahon, M. & Whittlesey, M., 1 Oct 2023, In: Polyhedron. 243, 116531.Research output: Contribution to journal › Article › peer-review
Open Access -
Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands
Isaac, C. J., Wilson, C. I., Burnage, A. L., Miloserdov, F., Mahon, M. F., Macgregor, S. A. & Whittlesey, M. K., 19 Dec 2022, In: Inorganic Chemistry. 61, 50, p. 20690-20698 9 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile4 Citations (SciVal)86 Downloads (Pure)