Projects per year
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Research interests
Our interests lie in the organometallic and coordination chemistry of late transition metals. We have a particular focus on bond activation reactions (e.g. C-H activation) in both stoichiometric and catalytic processes.
We employ a combination of Schlenk, vacuum line and glove box techniques for the manipulation of air and water sensitive compounds, replying heavily on multinuclear NMR spectroscopy, IR spectroscopy and X-ray crystallography for characterisation.
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Dual Unsaturated TM-M' Heterobimetallic Complexes for Cooperative Activation and Catalysis
Engineering and Physical Sciences Research Council
6/07/20 → 5/07/23
Project: Research council
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EU Marie Curie Individual Fellowship - Maia Espinal - Low Coordinate TM Magnets
13/02/17 → 27/08/19
Project: EU Commission
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[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
Sabater, S., Schmidt, D., Schmidt, H., Kuntze-Fechner, M., Zell, T., Isaac, C., Rajabi, N., Grieve, H., Blackaby, W., Lowe, J., Macgregor, S., Mahon, M., Radius, U. & Whittlesey, M., 25 Jun 2021, (Acceptance date) In: Chemistry - A European Journal.Research output: Contribution to journal › Article › peer-review
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Synthetic Access to Ring-Expanded N-Heterocyclic Carbene (RE-NHC) Copper Complexes and their Performance in Click Chemistry
Hall, J. W., Bouchet, D., Mahon, M. F., Whittlesey, M. K. & Cazin, C. S. J., 10 May 2021, In: Organometallics. 40, 9, p. 1252-1261 10 p.Research output: Contribution to journal › Article › peer-review
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(carbene)CuF Complexes Featuring Bulky Arduengo-Type, Ring-Expanded, and Cyclic (Alkyl)(amino)carbenes: Applications in Catalytic Aldehyde Allylation
Hall, J., Seeberger, F., Mahon, M. & Whittlesey, M., 13 Jan 2020, In: Organometallics. 39, 1, p. 227-233 7 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile5 Citations (Scopus)34 Downloads (Pure) -
Breaking bonds over many timescales: In celebration of Robin Perutz's 70th birthday
Duckett, S. B., Nicasio, M. C. & Whittlesey, M. K., 14 Jan 2020, In: Dalton Transactions. 49, 2, p. 254-255 2 p.Research output: Contribution to journal › Editorial › peer-review
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Erratum: Heterobimetallic ruthenium-zinc complexes with bulky N-heterocyclic carbenes: Syntheses, structures and reactivity (Dalton Trans. (2019) 48 (4176-4189) (DOI:10.1039/C8DT05023F))
Espinal-Viguri, M., Varela-Izquierdo, V., Miloserdov, F. M., Riddlestone, I. M., Mahon, M. F. & Whittlesey, M. K., 28 May 2020, In: Dalton Transactions. 49, 20, 1 p.Research output: Contribution to journal › Comment/debate › peer-review
Open Access