Projects per year
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Research interests
Our interests lie in the organometallic and coordination chemistry of late transition metals. We have a particular focus on bond activation reactions (e.g. C-H activation) in both stoichiometric and catalytic processes.
We employ a combination of Schlenk, vacuum line and glove box techniques for the manipulation of air and water sensitive compounds, replying heavily on multinuclear NMR spectroscopy, IR spectroscopy and X-ray crystallography for characterisation.
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Dual Unsaturated TM-M' Heterobimetallic Complexes for Cooperative Activation and Catalysis
Engineering and Physical Sciences Research Council
6/07/20 → 5/07/23
Project: Research council
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EU Marie Curie Individual Fellowship - Maia Espinal - Low Coordinate TM Magnets
13/02/17 → 27/08/19
Project: EU Commission
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Extreme g-tensor anisotropy and its insensitivity to structural distortions in a family of linear two-coordinate Ni(I) bis-N-heterocyclic carbene complexes
Blackaby, W. J. M., Harriman, K. L. M., Greer, S. M., Folli, A., Hill, S., Krewald, V., Mahon, M. F., Murphy, D. M., Murugesu, M., Richards, E., Suturina, E. & Whittlesey, M. K., 24 Jan 2022, In: Inorganic Chemistry. 61, 3, p. 1308-1315 8 p.Research output: Contribution to journal › Article › peer-review
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Zinc-Promoted ZnMe/ZnPh Exchange in Eight-Coordinate [Ru(PPh3)2(ZnMe)4H2]
Sotorrios, L., Miloserdov, F., Pecharman, A-F., Lowe, J., Macgregor, S., Mahon, M. & Whittlesey, M., 2 May 2022, In: Angewandte Chemie-International Edition. 61, 19, e202117495.Research output: Contribution to journal › Article › peer-review
Open Access -
[Ni(NHC)2] as a scaffold for structurally characterized trans [H-Ni-PR2] and trans [R2P-Ni-PR2] complexes
Sabater, S., Schmidt, D., Schmidt, H., Kuntze-Fechner, M., Zell, T., Isaac, C., Rajabi, N., Grieve, H., Blackaby, W., Lowe, J., Macgregor, S., Mahon, M., Radius, U. & Whittlesey, M., 15 Sep 2021, In: Chemistry - A European Journal. 27, p. 13221-13234Research output: Contribution to journal › Article › peer-review
Open AccessFile9 Downloads (Pure) -
Bonding and reactivity of a pair of neutral and cationic heterobimetallic RuZn complexes
Miloserdov, F., Pecharman, A-F., Sotorrios, L., Rajabi, N., Lowe, J., Macgregor, S., Mahon, M. & Whittlesey, M., 1 Nov 2021, In: Inorganic Chemistry. 60, 21, p. 16256-16265Research output: Contribution to journal › Article › peer-review
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Synthetic Access to Ring-Expanded N-Heterocyclic Carbene (RE-NHC) Copper Complexes and their Performance in Click Chemistry
Hall, J. W., Bouchet, D., Mahon, M. F., Whittlesey, M. K. & Cazin, C. S. J., 10 May 2021, In: Organometallics. 40, 9, p. 1252-1261 10 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile1 Downloads (Pure)