Projects per year
Personal profile
Research interests
Although research in the Hill group is rooted in molecular organometallic chemistry, our interests are somewhat broader and span from the discovery of environmentally benign and atom-efficient catalysts to the development of precursors for nanoparticle synthesis or chemical vapour deposition.
Current research projects include
- Catalysis with alkaline earth complexes (polymer and molecular chemistry)
- ‘Subvalent’ and multiply bonded main group species
- Catenated and ‘sigma delocalised’ group 13- and group 14-based electronic materials
- Organolanthanide (stereospecific) catalysis (polymer and molecular chemistry)
- Precursors for chemical vapour deposition and nanomaterials
Research Interests
- Group 2 Complexes in Molecular Catalysis
- Subvalent Main Group Species
- Catenated and ‘Sigma-delocalised’ Group 13 and Group 14 Polymeric materials
- Organolanthanide Chemistry for Enantioselective Catalysis
- Precursors for Chemical Vapour Deposition (CVD)
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
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Collaborations and top research areas from the last five years
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Alkaline Element Z-type Ligands for Tunable Base Metal Catalysis
Hill, M. (PI) & Liu, H.-Y. (Researcher)
1/09/23 → 19/11/26
Project: UK charity
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Molecular s-block Assemblies for Redox-active Bond Activation and Catalysis: Repurposing the s-block as 3d-elements
Hill, M. (PI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/04/23 → 30/09/26
Project: Research council
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Hub 'Science' 3: Catalysis for the Circular Economy and Sustainable Manufacturing - WP4: Earth-abundant metals in resource efficient catalysis
Webster, R. (PI), Davidson, M. (CoI), Hill, M. (CoI) & Whittlesey, M. (CoI)
Engineering and Physical Sciences Research Council
1/05/19 → 30/04/21
Project: Research council
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Ryan Schwamm- 1851 Fellowship - Activation of Nitrogen using Alkaline Earth Metals
Schwamm, R. (PI) & Hill, M. (CoI)
Royal Commission for the Exhibition of 1851
5/11/18 → 4/11/21
Project: UK charity
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Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council
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Allosteric Differentiation of Al(I) Reactivity
Hill, M., Liu, H.-Y., Kenar, J., Shere, H., Schwamm, R., Mahon, M. & McMullin, C., 11 Apr 2025, (Acceptance date) In: Chemistry - A European Journal.Research output: Contribution to journal › Article › peer-review
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Hydridostannylene Derivatives of Magnesium and Calcium
Kennedy, D. B., Pearce, K. G., Neale, S. E., Morris, L. J., Mahon, M. F., Lowe, J. P., McMullin, C. L., Jones, C. & Hill, M. S., 17 Feb 2025, In: Chemistry - A European Journal. 31, 10, e202404416.Research output: Contribution to journal › Article › peer-review
Open Access -
Nucleophilic Triphenylgermanides of Magnesium and Calcium
Kennedy, D. B., Pearce, K. G., Morris, L. J., Mahon, M. F., Jones, C. & Hill, M. S., 12 Feb 2025, In: Chemistry - A European Journal. 31, 9, e202404160.Research output: Contribution to journal › Article › peer-review
Open Access -
Terminal Alkyne Activation by an Al(I)-Centered Anion: Impact on the Mechanism of Alkali Metal Identity
Liu, H.-Y., Shere, H., Neale, S., Hill, M. S., Mahon, M. F. & McMullin, C. L., 31 Jan 2025, In: Organometallics. 44, 1, p. 236-243Research output: Contribution to journal › Article › peer-review
Open Access1 Citation (SciVal) -
Tetrazenyl-, Imido-, and Azidoaluminate Derivatives of a Sterically Demanding Bis-silazide Ligand
Liu, H.-Y., Schwamm, R. J., Kenar, J., Mahon, M. F. & Hill, M. S., 31 Jan 2025, In: Inorganics. 13, 1, 25.Research output: Contribution to journal › Article › peer-review
Open Access
Datasets
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CCDC 2032029: Experimental Crystal Structure Determination
Richardson, G. (Creator), Douair, I. (Creator), Cameron, S. (Creator), Bracegirdle, J. (Creator), Keyzers, R. (Creator), Hill, M. (Creator), Maron, L. (Creator) & Anker, M. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc266hb8
Dataset
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CCDC 2034334: Experimental Crystal Structure Determination
Richardson, G. (Creator), Douair, I. (Creator), Cameron, S. (Creator), Bracegirdle, J. (Creator), Keyzers, R. (Creator), Hill, M. (Creator), Maron, L. (Creator) & Anker, M. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc268wp2
Dataset
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CCDC 2032031: Experimental Crystal Structure Determination
Richardson, G. (Creator), Douair, I. (Creator), Cameron, S. (Creator), Bracegirdle, J. (Creator), Keyzers, R. (Creator), Hill, M. (Creator), Maron, L. (Creator) & Anker, M. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc266hdb
Dataset
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CCDC 2032031: Experimental Crystal Structure Determination
Richardson, G. (Creator), Douair, I. (Creator), Cameron, S. (Creator), Bracegirdle, J. (Creator), Keyzers, R. (Creator), Hill, M. (Creator), Maron, L. (Creator) & Anker, M. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc266hdb
Dataset
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CCDC 2032030: Experimental Crystal Structure Determination
Richardson, G. (Creator), Douair, I. (Creator), Cameron, S. (Creator), Bracegirdle, J. (Creator), Keyzers, R. (Creator), Hill, M. (Creator), Maron, L. (Creator) & Anker, M. (Creator), Cambridge Crystallographic Data Centre, 2021
DOI: 10.5517/ccdc.csd.cc266hc9
Dataset