• 4 SOUTH 0.14

Accepting PhD Students

20122018
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Research Output 2012 2018

2018

Mechanistic Insights into a Chiral Phosphoric Acid-Catalyzed Asymmetric Pinacol Rearrangement

Falcone, B. N., Grayson, M. N. & Rodriguez, J. B., 7 Dec 2018, In : Journal of Organic Chemistry. 83, 23, p. 14683-14687 5 p.

Research output: Contribution to journalArticle

3 Citations

Recent Developments and Applications of the Chiral Bronsted Acid Catalyzed Allylboration of Carbonyl Compounds

Sedgwick, D. M., Grayson, M. N., Fustero, S. & Barrio, P., 17 May 2018, In : Synthesis (Germany). 50, 10, p. 1935-1957 23 p.

Research output: Contribution to journalArticle

Carbonyl compounds
Acids
Alcohols
1 Citations

Using Transition State Modeling to Predict Mutagenicity for Michael Acceptors

Allen, T. E. H., Grayson, M. N., Goodman, J. M., Gutsell, S. & Russell, P. J., 25 Jun 2018, In : Journal of Chemical Information and Modeling. 58, 6, p. 1266-1271 6 p.

Research output: Contribution to journalArticle

Open Access
Covalent bonds
activation
Assays
DNA
energy
2017
21 Citations
Open Access
Chronology
Phosphoric acid
Molecular Dynamics Simulation
Hydrogen Bonding
Molecular dynamics
20 Citations
Open Access
Cinchona
Stereoselectivity
Thiourea
Hydrogen bonds
Nucleophiles
2016
26 Citations

Chiral Brønsted Acid-Catalyzed Asymmetric Allyl(propargyl)boration Reaction of ortho-Alkynyl Benzaldehydes: Synthetic Applications and Factors Governing the Enantioselectivity

Rodríguez, E., Grayson, M. N., Asensio, A., Barrio, P., Houk, K. N. & Fustero, S., 1 Apr 2016, In : ACS Catalysis. 6, 4, p. 2506-2514 9 p.

Research output: Contribution to journalArticle

Benzaldehydes
Alkynes
Enantioselectivity
Scaffolds
Electronic properties
38 Citations
Cinchona Alkaloids
Hydrogen Bonding
Hydroxyl Radical
Cinchona
Hydrogen bonds
39 Citations

Cinchona Urea-Catalyzed Asymmetric Sulfa-Michael Reactions: The Brønsted Acid-Hydrogen Bonding Model

Grayson, M. N. & Houk, K. N., 27 Jul 2016, In : Journal of the American Chemical Society. 138, 29, p. 9041-9044 4 p.

Research output: Contribution to journalArticle

Open Access
Cinchona
Cinchona Alkaloids
Hydrogen Bonding
Urea
Hydrogen bonds
53 Citations

Theory and Modeling of Asymmetric Catalytic Reactions

Lam, Y. H., Grayson, M. N., Holland, M. C., Simon, A. & Houk, K. N., 19 Apr 2016, In : Accounts of Chemical Research. 49, 4, p. 750-762 13 p.

Research output: Contribution to journalArticle

Stereoselectivity
Diamines
Cinchona Alkaloids
Amines
Fluorination
2015
23 Citations

Asymmetric boronate addition to o -quinone methides: Ligand exchange, solvent effects, and Lewis acid catalysis

Grayson, M. N. & Goodman, J. M., 20 Feb 2015, In : Journal of Organic Chemistry. 80, 4, p. 2056-2061 6 p.

Research output: Contribution to journalArticle

Open Access
Lewis Acids
Catalysis
Ion exchange
Enantioselectivity
Ligands
8 Citations

Base-mediated cascade rearrangements of aryl-substituted diallyl ethers

Reid, J. P., McAdam, C. A., Johnston, A. J. S., Grayson, M. N., Goodman, J. M. & Cook, M. J., 6 Feb 2015, In : Journal of Organic Chemistry. 80, 3, p. 1472-1498 27 p.

Research output: Contribution to journalArticle

Ethers
Isomerization
Substrates
Experiments
21 Citations

Efficient Biosynthesis of Fungal Polyketides Containing the Dioxabicyclo-octane Ring System

Mao, X. M., Zhan, Z. J., Grayson, M. N., Tang, M. C., Xu, W., Li, Y. Q., Yin, W. B., Lin, H. C., Chooi, Y. H., Houk, K. N. & Tang, Y., 23 Sep 2015, In : Journal of the American Chemical Society. 137, 37, p. 11904-11907 4 p.

Research output: Contribution to journalArticle

Polyketides
Polyenes
Aurovertins
Biosynthesis
Pyrones
30 Citations

Mechanistic insights into a BINOL-derived phosphoric acid-catalyzed asymmetric Pictet-Spengler reaction

Overvoorde, L. M., Grayson, M. N., Luo, Y. & Goodman, J. M., 6 Mar 2015, In : Journal of Organic Chemistry. 80, 5, p. 2634-2640 7 p.

Research output: Contribution to journalArticle

Open Access
norharman
Enantioselectivity
Catalysts
Stereoselectivity
Atoms
26 Citations

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

Grayson, M. N., Krische, M. J. & Houk, K. N., 15 Jul 2015, In : Journal of the American Chemical Society. 137, 27, p. 8838-8850 13 p.

Research output: Contribution to journalArticle

phosphine
Ruthenium
Enantioselectivity
Butadiene
Hydrogen
2013
10 Citations

Lewis acid catalysis and ligand exchange in the asymmetric binaphthol-catalyzed propargylation of ketones

Grayson, M. N. & Goodman, J. M., 6 Sep 2013, In : Journal of Organic Chemistry. 78, 17, p. 8796-8801 6 p.

Research output: Contribution to journalArticle

Lewis Acids
Ketones
Catalysis
Ion exchange
Ligands
47 Citations
Naphthol
Phosphoric acid
Aldehydes
Phosphoric Acids
Oxygen
2012
97 Citations

Mechanistic insights into the BINOL-derived phosphoric acid-catalyzed asymmetric allylboration of aldehydes

Grayson, M. N., Pellegrinet, S. C. & Goodman, J. M., 8 Feb 2012, In : Journal of the American Chemical Society. 134, 5, p. 2716-2722 7 p.

Research output: Contribution to journalArticle

Phosphoric acid
Aldehydes
Phosphoric Acids
Oxygen
Catalysts