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Research Output

2010

Alternatives to organoboron reagents in rhodium-catalyzed conjugate additions

Hargrave, J. D., Allen, J. C. & Frost, C. G., 1 Mar 2010, In : Chemistry - An Asian Journal. 5, 3, p. 386-396 11 p.

Research output: Contribution to journalArticle

48 Citations (Scopus)

A modular approach to catalytic synthesis using a dual-functional linker for Click and Suzuki coupling reactions

White, J. R., Price, G. J., Schiffers, S., Raithby, P. R., Plucinski, P. K. & Frost, C. G., 28 Jul 2010, In : Tetrahedron Letters. 51, 30, p. 3913-3917 5 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

Catalytic enantioselective Dieckmann-type annulation: Synthesis of pyrrolidines with quaternary stereogenic centers

Hargrave, J. D., Allen, J. C., Kociok-Kohn, G., Bish, G. & Frost, C. G., 1 Mar 2010, In : Angewandte Chemie-International Edition. 49, 10, p. 1825-1829 5 p.

Research output: Contribution to journalArticle

13 Citations (Scopus)

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Burrows, A. D., Frost, C. G., Mahon, M. F., Raithby, P. R., Renouf, C. L., Richardson, C. & Stevenson, A., 28 Jul 2010, In : Chemical Communications. 46, 28, p. 5067-5069 3 p.

Research output: Contribution to journalArticle

46 Citations (Scopus)

Exploring rhodium-catalysed conjugate addition of chiral alkenylboronates using chiral olefin ligands

Frost, C. G., Edwards, H. J., Penrose, S. D. & Gleave, R., Oct 2010, In : Synthesis. 2010, 19, p. 3243-3247 5 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

First catalytic enantioselective Dieckmann-type annulation

Hargrave, J. D., Frost, C. G. & Allen, J. C., Jun 2010, In : Synthesis. 2010, 11, p. A50-A52

Research output: Contribution to journalArticle

Heterogeneous catalytic synthesis using microreactor technology

Frost, C. G. & Mutton, L., Oct 2010, In : Green Chemistry. 12, 10, p. 1687-1703 17 p.

Research output: Contribution to journalArticle

216 Citations (Scopus)

Post-synthetic modification: Playing tag with metal-organic frameworks

Burrows, A., Frost, C., Mahon, M. & Richardson, C., 2010.

Research output: Contribution to conferencePoster

Rhodium-catalysed conjugate addition of arylboronic acids to enantiopure dehydroamino acid derivatives

Hargrave, J. D., Bish, G., Kociok-Kohn, G. & Frost, C. G., 21 Nov 2010, In : Organic and Biomolecular Chemistry. 8, 22, p. 5120-5125 6 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)
19 Citations (Scopus)

Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand

Burrows, A. D., Frost, C. G., Mahon, M. F., Raithby, P. R., Richardson, C. & Stevenson, A., 28 Jul 2010, In : Chemical Communications. 46, 28, p. 5064-5066 3 p.

Research output: Contribution to journalArticle

Open Access
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19 Citations (Scopus)
120 Downloads (Pure)

Synthetic applications of rhodium catalysed conjugate addition

Edwards, H. J., Hargrave, J. D., Penrose, S. D. & Frost, C. G., Jun 2010, In : Chemical Society Reviews. 39, 6, p. 2093-2105 13 p.

Research output: Contribution to journalArticle

231 Citations (Scopus)
2009

A Practical Synthesis of α-Substituted tert-Butyl Acrylates from Meldrum's Acid and Aldehydes

Frost, C. G., Penrose, S. D. & Gleave, R., 2009, In : Synthesis. 4, p. 627-635 9 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

Easy-separable magnetic nanoparticle-supported Pd catalysts: Kinetics, stability and catalyst re-use

Laska, U., Frost, C. G., Price, G. J. & Plucinski, P. K., 10 Dec 2009, In : Journal of Catalysis. 268, 2, p. 318-328 11 p.

Research output: Contribution to journalArticle

92 Citations (Scopus)
18 Citations (Scopus)

Rhodium-catalyzed 1,4-additions to enantiopure acceptors: asymmetric synthesis of functionalized pyrrolizidinones

Zoute, L., Kociok-Kohn, G. & Frost, C. G., 18 Jun 2009, In : Organic Letters. 11, 12, p. 2491-2494 4 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

Sulfur-tagged metal–organic frameworks and their post-synthetic oxidation

Burrows, A. D., Frost, C. G., Mahon, M. F. & Richardson, C., 28 Jul 2009, In : Chemical Communications. 28, p. 4218-4220 3 p.

Research output: Contribution to journalArticle

81 Citations (Scopus)

The rhodium-catalysed 1,2-addition of arylboronic acids to aldehydes and ketones with sulfonated S-Phos

White, J. R., Price, G. J., Plucinski, P. K. & Frost, C. G., 30 Dec 2009, In : Tetrahedron Letters. 50, 52, p. 7365-7368 4 p.

Research output: Contribution to journalArticle

25 Citations (Scopus)
2008

BINOL-3,3′-triflone N,N-dimethyl phosphoramidites: Through-space 19F31P spin-spin coupling with a remarkable dependency on temperature and solvent internal pressure

Kruck, M., Munoz, M. P., Bishop, H. L., Butts, C. P., Lloyd-Jones, G. C., Frost, C. G., Chapman, C. J. & Kociok-Kohn, G., 8 Sep 2008, In : Chemistry - A European Journal. 14, 26, p. 7808-7812 5 p.

Research output: Contribution to journalArticle

25 Citations (Scopus)

Enantioselective rhodium-catalysed 1,4-additions of 2-heteroarylzinc donors using Me-DUPHOS

Le Nôtre, J., Allen, J. C. & Frost, C. G., 28 Aug 2008, In : Chemical Communications. 2008, 32, p. 3795-3797 3 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

Peptide modification through site-selective residue interconversion: application of the rhodium-catalysed 1,4-addition of aryl siloxanes and boronates

Chapman, C. J., Hargrave, J. D., Bish, G. & Frost, C. G., 2008, In : Tetrahedron. 64, 40, p. 9528-9539 12 p.

Research output: Contribution to journalArticle

24 Citations (Scopus)

Post-synthetic modification of tagged metal-organic frameworks

Burrows, A., Frost, C., Mahon, M. & Richardson, C., 2008.

Research output: Contribution to conferencePoster

212 Citations (Scopus)

Post-synthetic modification of tagged metal-organic frameworks

Burrows, A. D., Frost, C. G., Mahon, M. F. & Richardson, C., 20 Oct 2008, In : Angewandte Chemie-International Edition. 47, 44, p. 8482-8486 5 p.

Research output: Contribution to journalArticle

212 Citations (Scopus)

Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide

Nôtre, J. L. & Frost, C. G., 20 Oct 2008, In : Tetrahedron Letters. 49, 43, p. 6217-6219 3 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)
22 Citations (Scopus)
33 Citations (Scopus)

Subtle structural variation in copper metal-organic frameworks: Syntheses, structures, magnetic properties and catalytic behaviour

Burrows, A. D., Frost, C. G., Mahon, M. F., Winsper, M., Richardson, C., Attfield, J. P. & Rodgers, J. A., 2008, In : Dalton Transactions. 2008, 47, p. 6788-6795 8 p.

Research output: Contribution to journalArticle

37 Citations (Scopus)
2007

A new method for constructing quaternary carbon centres: Tandem rhodium-catalysed 1,4-addition/intramolecular cyclisation

Le Nôtre, J., Van Mele, D. & Frost, C. G., 1 Feb 2007, In : Advanced Synthesis & Catalysis. 349, 3, p. 432-440 9 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

Easily recyclable homogeneous catalysts based on magnetic fluids

Laska, U., Frost, C. G., Plucinski, P. K. & Price, G. J., 2007, In : Récents Progrès en Génie des Procédés. 94, p. 1-8 8 p.

Research output: Contribution to journalArticle

Kinetic and selectivity studies of gas-liquid reaction under Taylor flow in a circular capillary

Tsoligkas, A. N., Simmons, M. J. H., Wood, J. & Frost, C. G., 15 Oct 2007, In : Catalysis Today. 128, 1-2, p. 36-46 11 p.

Research output: Contribution to journalArticle

29 Citations (Scopus)

Rhodium-catalyzed conjugate addition-enantioselective protonation: The synthesis of alpha,alpha'-dibenzyl esters

Frost, C. G., Penrose, S. D., Lambshead, K., Raithby, P. R., Warren, J. E. & GleaveO, R., 2007, In : Organic Letters. 9, 11, p. 2119-2122 4 p.

Research output: Contribution to journalArticle

48 Citations (Scopus)

Site-selective modification of peptides using rhodium and palladium catalysis: Complementary electrophilic and nucleophilic arylation

Chapman, C. J., Frost, C. G., Matsuno, A. & Willis, M. C., 2007, In : Chemical Communications. 2007, 38, p. 3903-3905 3 p.

Research output: Contribution to journalArticle

31 Citations (Scopus)

Structural Variation in Polymeric 5-Nitroisophthalate Copper Complexes: Application of MOFs to Catalysis

Burrows, A., Richardson, C., Winsper, M., Mahon, M. & Frost, C., 2007.

Research output: Contribution to conferencePoster

Tandem and domino catalytic strategies for enantioselective synthesis

Chapman, C. J. & Frost, C. G., 4 Jan 2007, In : Synthesis. 2007, 1, p. 1-21 21 p.

Research output: Contribution to journalArticle

400 Citations (Scopus)

Tandem molybdenum catalyzed hydrosilylations: An expedient synthesis of β-aryl aldehydes

Frost, C. G. & Hartley, B. C., 11 Oct 2007, In : Organic Letters. 9, 21, p. 4259-4261 3 p.

Research output: Contribution to journalArticle

12 Citations (Scopus)
2006

Chelating phosphane-boranes as hemilabile ligands - Synthesis of [Mn(CO)32-H3B·dppin)][BArF4 ] and [Mn(CO)41-H3B· dppm)][BArF4]

Merle, N., Frost, C. G., Kociok-Kohn, G., Willis, M. C. & Weller, A. S., 16 Oct 2006, In : European Journal of Inorganic Chemistry. 2006, 20, p. 4068-4073 6 p.

Research output: Contribution to journalArticle

11 Citations (Scopus)

Indium triflate catalysed Ene and Friedel Crafts additions to α-imino esters: A one-pot synthesis of α-amino acid derivatives

Krakowski, M., Frost, C. G., Hartley, J. P. & Chauhan, K. K., 1 Mar 2006, In : Letters in Organic Chemistry. 3, 3, p. 228-230 3 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

Douglas, T. M., Le Notre, J., Brayshaw, S. K., Frost, C. G. & Weller, A. S., 2006, In : Chemical Communications. 2006, 32, p. 3408-3410 3 p.

Research output: Contribution to journalArticle

41 Citations (Scopus)

Rhodium-catalysed addition of organotrialkoxysilanes to α-substituted acrylic esters

Hargrave, J. D., Herbert, J., Bish, G. & Frost, C. G., 2006, In : Organic and Biomolecular Chemistry. 4, 17, p. 3235-3241 7 p.

Research output: Contribution to journalArticle

28 Citations (Scopus)

Structure and reactivity of new phosphine ligands containing the hemi-labile sulfone moiety

Chapman, C. J., Frost, C. G. & Mahon, M. F., 2006, In : Dalton Transactions. 2006, 18, p. 2251-2262 12 p.

Research output: Contribution to journalArticle

9 Citations (Scopus)

Switching stereoselectivity in rhodium-catalysed 1,4-additions: The asymmetric synthesis of 2-substituted pyrrolizidinones

Hargrave, J. D., Frost, C. G. & Bish, G., 2006, In : Chemical Communications. 2006, 42, p. 4389-4391 3 p.

Research output: Contribution to journalArticle

16 Citations (Scopus)

The α-arylation of α-bromo- and α-chloroenones using palladium-catalysed cross-coupling

Banks, J. C., Van Mele, D. & Frost, C. G., 24 Apr 2006, In : Tetrahedron Letters. 47, 17, p. 2863-2866 4 p.

Research output: Contribution to journalArticle

15 Citations (Scopus)
2005

Ruthenium (II) complexes of the chelating phosphine borane H2ClB · dppm

Merle, N., Frost, C. G., Kociok-Kohn, G., Willis, M. C. & Weller, A. S., 1 Jun 2005, In : Journal of Organometallic Chemistry. 690, 11, p. 2829-2834 6 p.

Research output: Contribution to journalArticle

19 Citations (Scopus)
2004

An electrochemical gene detection assay utilising T7 exonuclease activity on complementary probe-target oligonucleotide sequences

Hillier, S. C., Flower, S. E., Frost, C. G., Jenkins, A. T. A., Keay, R., Braven, H. & Clarkson, J., 1 Dec 2004, In : Electrochemistry Communications. 6, 12, p. 1227-1232 6 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

An electrochemical study of enzymatic oligonucleotide digestion

Hillier, S. C., Frost, C. G., Jenkins, A. T. A., Braven, H. T., Keay, R. W., Flower, S. E. & Clarkson, J. M., 1 Jun 2004, In : Bioelectrochemistry. 63, 1-2, p. 307-310 4 p.

Research output: Contribution to journalArticle

29 Citations (Scopus)

Rhodium-catalysed 1,4-additions in water: Synthesis of succinic esters and β2-amino acid derivatives

Wadsworth, K. J., Wood, F. K., Chapman, C. J. & Frost, C. G., 6 Sep 2004, In : Synlett. 2004, 11, p. 2022-2024 3 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters

Moss, R. J., Wadsworth, K. J., Chapman, C. J. & Frost, C. G., 7 Sep 2004, In : Chemical Communications. 10, 17, p. 1984-1985 2 p.

Research output: Contribution to journalArticle

50 Citations (Scopus)

Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P·BH3

Merle, N., Kociok-Kohn, G., Mahon, M. F., Frost, C. G., Ruggerio, G. D., Weller, A. S. & Willis, M. C., 2004, In : Dalton Transactions. 2004, 22, p. 3883-3892 10 p.

Research output: Contribution to journalArticle

58 Citations (Scopus)

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

Cotgreave, J. H., Colclough, D., Kociok-Kohn, G., Ruggiero, G., Frost, C. G. & Weller, A. S., 21 May 2004, In : Dalton Transactions. 2004, 10, p. 1519-1520 2 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)
2003

Diphosphine mono-sulfides: readily available chiral monophosphines

Chapman, C. J., Frost, C. G., Gill-Carey, M. P., Kociok-Kohn, G., Mahon, M. F., Weller, A. S. & Willis, M. C., 21 Mar 2003, In : Tetrahedron: Asymmetry. 14, 6, p. 705-710 6 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)