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Research Output

1991

Palladium Catalysed Coupling Reactions

Frost, C. G., 1991, Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds: A Modern Comprehensive Treatise. 2 ed. Vol. 5. p. 315-350 36 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

1992

Selectivity in palladium catalysed allylic substitution

Frost, C. G., Howarth, J. & Williams, J. M. J., 1 Sep 1992, In : Tetrahedron: Asymmetry. 3, 9, p. 1089-1122 34 p.

Research output: Contribution to journalArticle

1993

Asymmetric addition of diethylzinc to aromatic aldehydes using enantiomerically pure hydroxymethyl oxazoline ligands

Allen, J. V., Frost, C. G. & Williams, J. M. J., 1993, In : Tetrahedron: Asymmetry. 4, 4, p. 649-650 2 p.

Research output: Contribution to journalArticle

Asymmetric palladium catalyzed allylic substitution using phosphorus containing oxazoline ligands

Dawson, G. J., Frost, C. G., Williams, J. M. J. & Coote, S. J., 7 May 1993, In : Tetrahedron Letters. 34, 19, p. 3149-3150 2 p.

Research output: Contribution to journalArticle

Enantioselective palladium catalysed allylic substitution with sulfur-containing oxazoline ligands

Frost, C. G. & Williams, J. M. J., Aug 1993, In : Tetrahedron: Asymmetry. 4, 8, p. 1785-1788 4 p.

Research output: Contribution to journalArticle

Enantioselective palladium catalysed allylic substitution with thienyl oxazoline ligands

Frost, C. G. & Williams, J. M. J., 19 Mar 1993, In : Tetrahedron Letters. 34, 12, p. 2015-2018 4 p.

Research output: Contribution to journalArticle

Sulfides tethered to oxazolines: Ligands for enantioselective catalysis

Dawson, G. J., Frost, C. G., Martin, C. J., Williams, J. M. J. & Coote, S. J., 26 Nov 1993, In : Tetrahedron Letters. 34, 48, p. 7793-7796 4 p.

Research output: Contribution to journalArticle

The preparation of functionalised aryl phosphines from aryl fluorides by nucleophilic aromatic substitution with potassium diphenylphosphide

Coote, S. J., Dawson, G. J., Frost, C. G. & Williams, J. M. J., 1 Jul 1993, In : Synlett. 1993, 7, p. 509-510 2 p.

Research output: Contribution to journalArticle

1994

Enantiomerically pure acetals as ligands for asymmetric catalysis

Frost, C. G. & Williams, J. M. J., 1 Jul 1994, In : Synlett. 1994, 7, p. 551-552 2 p.

Research output: Contribution to journalArticle

Palladium-catalysed asymmetric allylic substitution: A ligand design incorporating steric and electronic effects

Allen, J. V., Coote, S. J., Dawson, G. J., Frost, C. G., Martin, C. J. & Williams, J. M. J., 1994, In : Journal of the Chemical Society: Perkin Transactions 1. 1994, 15, p. 2065-2072 8 p.

Research output: Contribution to journalArticle

Preparation of novel sulfur and phosphorus containing oxazolines as ligands for asymmetric catalysis

Allen, J. V., Dawson, G. J., Frost, C. G., Williams, J. M. J. & Coote, S. J., 17 Jan 1994, In : Tetrahedron. 50, 3, p. 799-808 10 p.

Research output: Contribution to journalArticle

1995

Catalytic applications of transition metals in organic synthesis

Frost, C. G. & Williams, J. M. J., 1995, In : Contemporary Organic Synthesis. 2, 2, p. 65-83 19 p.

Research output: Contribution to journalArticle

1996

Concise synthesis of taxol A-ring components: Remote diastereoselective additions of alkenyl lithiums to aldehydes

Frost, C., Linnane, P., Magnus, P. & Spyvee, M., 16 Dec 1996, In : Tetrahedron Letters. 37, 51, p. 9139-9142 4 p.

Research output: Contribution to journalArticle

19 Citations (Scopus)

Taxane diterpenes 1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors

Bauta, W. E., Booth, J., Bos, M. E., DeLuca, M., Diorazio, L., Donohoe, T. J., Frost, C., Magnus, N., Magnus, P., Mendoza, J., Pye, P., Tarrant, J. G., Thom, S. & Ujjainwalla, F., 4 Nov 1996, In : Tetrahedron. 52, 45, p. 14081-14102 22 p.

Research output: Contribution to journalArticle

33 Citations (Scopus)
1997

Iterative amination strategy in the synthesis of peptidomimetics

Frost, C. G. & Mendonça, P., 1997, In : Chemistry Letters. 26, 11, p. 1159-1160 2 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)
1998

Recent developments in aromatic heteroatom coupling reactions

Frost, C. G. & Mendonça, P., 21 Aug 1998, In : Journal of the Chemical Society - Perkin Transcriptions 1. 1998, 16, p. 2615-2623 9 p.

Research output: Contribution to journalArticle

100 Citations (Scopus)
1999

Catalytic asymmetric hydrosilylation of ketones using mixed-ligand ruthenium complexes

Moreau, C., Frost, C. G. & Murrer, B., 23 Jul 1999, In : Tetrahedron Letters. 40, 30, p. 5617-5620 4 p.

Research output: Contribution to journalArticle

30 Citations (Scopus)

Indium triflate: An efficient catalyst for acylation reactions

Chauhan, K. K., Frost, C. G., Love, I. & Waite, D., 1999, In : Synlett. 1999, 11, p. 1743-1744 2 p.

Research output: Contribution to journalArticle

218 Citations (Scopus)

Indium triflate an efficient catalyst for hetero Diels-Alder reactions

Ali, T., Chauhan, K. K. & Frost, C. G., 23 Jul 1999, In : Tetrahedron Letters. 40, 30, p. 5621-5624 4 p.

Research output: Contribution to journalArticle

88 Citations (Scopus)

Palladium catalysed mono-N-arylation of enantiopure diamines

Frost, C. G. & Mendonça, P., 21 May 1999, In : Tetrahedron: Asymmetry. 10, 10, p. 1831-1834 4 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

Taxane diterpenes 5: Synthesis of the A- and C-rings: An unusual rearrangement of an N-hydroxyimino lactone

Magnus, P., Westwood, N., Spyvee, M., Frost, C., Linnane, P., Tavares, F. & Lynch, V., 21 May 1999, In : Tetrahedron. 55, 21, p. 6435-6452 18 p.

Research output: Contribution to journalArticle

27 Citations (Scopus)
2000

Advances in indium-catalysed organic synthesis

Chauhan, K. K. & Frost, C. G., 21 Sep 2000, In : Journal of the Chemical Society, Perkin Transactions 1. 2000, 18, p. 3015-3019 5 p.

Research output: Contribution to journalArticle

250 Citations (Scopus)
55 Citations (Scopus)
2001

[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction

Hague, C., Patmore, N. J., Frost, C. G., Mahon, M. F. & Weller, A. S., 2001, In : Chemical Communications. 2001, 21, p. 2286-2287 2 p.

Research output: Contribution to journalArticle

34 Citations (Scopus)

Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(eta(2)-BH3)Ph2PCH2PPh2}][PF6] (COD=1,5-cyclooctadiene)

Ingleson, M., Patmore, N. J., Ruggiero, G. D., Frost, C. G., Mahon, M. F., Willis, M. C. & Weller, A. S., 15 Oct 2001, In : Organometallics. 20, 21, p. 4434-4436 3 p.

Research output: Contribution to journalArticle

47 Citations (Scopus)

Efficient aromatic and heteroatom acylations using catalytic indium complexes with lithium perchlorate

Chapman, C. J., Frost, C. G., Hartley, J. P. & Whittle, A. J., 29 Jan 2001, In : Tetrahedron Letters. 42, 5, p. 773-775 3 p.

Research output: Contribution to journalArticle

74 Citations (Scopus)

Indium-catalysed aryl and alkyl sulfonylation of aromatics

Frost, C. G., Hartley, J. P. & Whittle, A. J., 2001, In : Synlett. 2001, 6, p. 830-832 3 p.

Research output: Contribution to journalArticle

57 Citations (Scopus)

Organic aspects of organometallic chemistry

Frost, C. G. & Willis, M. C., 2001, In : Organometallic Chemistry. 29, p. 170-206 37 p.

Research output: Contribution to journalArticle

1 Citation (Scopus)

Rhodium catalysed addition of boronic acids to anhydrides: A new method for the synthesis of ketones

Frost, C. G. & Wadsworth, K. J., 21 Nov 2001, In : Chemical Communications. 2001, 22, p. 2316-2317 2 p.

Research output: Contribution to journalArticle

65 Citations (Scopus)

Rhodium-catalysed aryl transfer to aldehydes: Counterion effects with nitrogen containing ligands

Moreau, C., Hague, C., Weller, A. S. & Frost, C. G., 24 Sep 2001, In : Tetrahedron Letters. 42, 39, p. 6957-6960 4 p.

Research output: Contribution to journalArticle

95 Citations (Scopus)
2002

Catalytic arylation of sulfamoyl chlorides: A practical synthesis of sulfonamides

Frost, C. G., Hartley, J. P. & Griffin, D., 1 Jan 2002, In : Synlett. 2002, 11, p. 1928-1930 3 p.

Research output: Contribution to journalArticle

46 Citations (Scopus)

Counterion effects in indium-catalysed aromatic electrophilic substitution reactions

Frost, C. G., Hartley, J. P. & Griffin, D., 1 Jul 2002, In : Tetrahedron Letters. 43, 27, p. 4789-4791 3 p.

Research output: Contribution to journalArticle

61 Citations (Scopus)

Silver phosphanes partnered with carborane monoanions: Synthesis, structures and use as highly active lewis acid catalysts in a hetero-Diels-Alder reaction

Patmore, N. J., Hague, C., Cotgreave, J. H., Mahon, M. F., Frost, C. G. & Weller, A. S., 2002, In : Chemistry - A European Journal. 8, 9, p. 2088-2098 11 p.

Research output: Contribution to journalArticle

120 Citations (Scopus)
2003

Diphosphine mono-sulfides: readily available chiral monophosphines

Chapman, C. J., Frost, C. G., Gill-Carey, M. P., Kociok-Kohn, G., Mahon, M. F., Weller, A. S. & Willis, M. C., 21 Mar 2003, In : Tetrahedron: Asymmetry. 14, 6, p. 705-710 6 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

Enantioselective rhodium-catalysed addition of boronic acids using C-symmetric aryl diphosphite ligands

Chapman, C. J., Wadsworth, K. J. & Frost, C. G., 29 Aug 2003, In : Journal of Organometallic Chemistry. 680, 1-2, p. 206-211 6 p.

Research output: Contribution to journalArticle

44 Citations (Scopus)

Synthesis of functionalised phenylalanines using rhodium catalysis in water

Chapman, C. J. & Frost, C. G., 1 Mar 2003, In : Advanced Synthesis & Catalysis. 345, 3, p. 353-355 3 p.

Research output: Contribution to journalArticle

32 Citations (Scopus)
2004

An electrochemical gene detection assay utilising T7 exonuclease activity on complementary probe-target oligonucleotide sequences

Hillier, S. C., Flower, S. E., Frost, C. G., Jenkins, A. T. A., Keay, R., Braven, H. & Clarkson, J., 1 Dec 2004, In : Electrochemistry Communications. 6, 12, p. 1227-1232 6 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

An electrochemical study of enzymatic oligonucleotide digestion

Hillier, S. C., Frost, C. G., Jenkins, A. T. A., Braven, H. T., Keay, R. W., Flower, S. E. & Clarkson, J. M., 1 Jun 2004, In : Bioelectrochemistry. 63, 1-2, p. 307-310 4 p.

Research output: Contribution to journalArticle

29 Citations (Scopus)

Rhodium-catalysed 1,4-additions in water: Synthesis of succinic esters and β2-amino acid derivatives

Wadsworth, K. J., Wood, F. K., Chapman, C. J. & Frost, C. G., 6 Sep 2004, In : Synlett. 2004, 11, p. 2022-2024 3 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters

Moss, R. J., Wadsworth, K. J., Chapman, C. J. & Frost, C. G., 7 Sep 2004, In : Chemical Communications. 10, 17, p. 1984-1985 2 p.

Research output: Contribution to journalArticle

50 Citations (Scopus)

Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P·BH3

Merle, N., Kociok-Kohn, G., Mahon, M. F., Frost, C. G., Ruggerio, G. D., Weller, A. S. & Willis, M. C., 2004, In : Dalton Transactions. 2004, 22, p. 3883-3892 10 p.

Research output: Contribution to journalArticle

58 Citations (Scopus)

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

Cotgreave, J. H., Colclough, D., Kociok-Kohn, G., Ruggiero, G., Frost, C. G. & Weller, A. S., 21 May 2004, In : Dalton Transactions. 2004, 10, p. 1519-1520 2 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)
2005

Ruthenium (II) complexes of the chelating phosphine borane H2ClB · dppm

Merle, N., Frost, C. G., Kociok-Kohn, G., Willis, M. C. & Weller, A. S., 1 Jun 2005, In : Journal of Organometallic Chemistry. 690, 11, p. 2829-2834 6 p.

Research output: Contribution to journalArticle

19 Citations (Scopus)
2006

Chelating phosphane-boranes as hemilabile ligands - Synthesis of [Mn(CO)32-H3B·dppin)][BArF4 ] and [Mn(CO)41-H3B· dppm)][BArF4]

Merle, N., Frost, C. G., Kociok-Kohn, G., Willis, M. C. & Weller, A. S., 16 Oct 2006, In : European Journal of Inorganic Chemistry. 2006, 20, p. 4068-4073 6 p.

Research output: Contribution to journalArticle

11 Citations (Scopus)

Indium triflate catalysed Ene and Friedel Crafts additions to α-imino esters: A one-pot synthesis of α-amino acid derivatives

Krakowski, M., Frost, C. G., Hartley, J. P. & Chauhan, K. K., 1 Mar 2006, In : Letters in Organic Chemistry. 3, 3, p. 228-230 3 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

Douglas, T. M., Le Notre, J., Brayshaw, S. K., Frost, C. G. & Weller, A. S., 2006, In : Chemical Communications. 2006, 32, p. 3408-3410 3 p.

Research output: Contribution to journalArticle

41 Citations (Scopus)

Rhodium-catalysed addition of organotrialkoxysilanes to α-substituted acrylic esters

Hargrave, J. D., Herbert, J., Bish, G. & Frost, C. G., 2006, In : Organic and Biomolecular Chemistry. 4, 17, p. 3235-3241 7 p.

Research output: Contribution to journalArticle

28 Citations (Scopus)

Structure and reactivity of new phosphine ligands containing the hemi-labile sulfone moiety

Chapman, C. J., Frost, C. G. & Mahon, M. F., 2006, In : Dalton Transactions. 2006, 18, p. 2251-2262 12 p.

Research output: Contribution to journalArticle

9 Citations (Scopus)

Switching stereoselectivity in rhodium-catalysed 1,4-additions: The asymmetric synthesis of 2-substituted pyrrolizidinones

Hargrave, J. D., Frost, C. G. & Bish, G., 2006, In : Chemical Communications. 2006, 42, p. 4389-4391 3 p.

Research output: Contribution to journalArticle

16 Citations (Scopus)

The α-arylation of α-bromo- and α-chloroenones using palladium-catalysed cross-coupling

Banks, J. C., Van Mele, D. & Frost, C. G., 24 Apr 2006, In : Tetrahedron Letters. 47, 17, p. 2863-2866 4 p.

Research output: Contribution to journalArticle

15 Citations (Scopus)