Projects per year
Personal profile
Research interests
My research focuses on the discovery of novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers.
Research projects in our group include:
- Small molecules (e.g. CO2, H2O) activation and transformation
- Carbohydrate chemistry and catalysis
- Synthesis of novel monomers and polymers from renewable resources, in particular sugars
- Organic and inorganic catalyst design
- Polymerisation catalysis
- Computational chemistry (Density Functional Theory Modelling) for mechanistic studies
- Application of sustainable polymers (3D printing, packaging, elastomers, battery electrolytes, catalysis, health materials...)
Why?
Polymers (the molecules of plastics) are today everywhere, and there lies the problem, as their dependence on depleting fossil-fuel resources and their environmental persistence make them unsustainable. To develop sustainable polymers that are cost- and performance-competitive with the dominating oil-based polymers is a major challenge to achieve a circular and sustainable economy of plastics. Towards that goal, catalysis is a central enabling technology to develop 1) new monomers from renewable feedstock, 2) more efficient routes to produce related polymeric materials, capable of substituting petrochemicals and 3) novel end-of life options for these polymers.
Group website
Biography
Originally from France, Antoine obtained his PhD from the Ecole Polytechnique in 2009, under the supervision of Prof Pascal Le Floch. He then moved to the UK and worked at Imperial College London as a postdoctoral research assistant in the group of Prof Charlotte K. Williams, in the area of CO2/epoxide copolymers and poly(lactic acid). Antoine returned to France in 2011 and gained industrial R&D experience, working for Air Liquide on Carbon Capture, Storage and Utilisation (CCSU) projects. In April 2013 Antoine began his independent research career at the CSCT as a Whorrod Research Fellow, investigating novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers. In October 2017 Antoine was awarded a Royal Society University Research Fellowship.
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
Education/Academic qualification
Chemistry, Doctor of Science, École Polytechnique
25 Sep 2006 → 25 Sep 2009
Award Date: 25 Sep 2009
Chemistry, Master of Research, École Polytechnique
1 Sep 2005 → 30 Jun 2006
Award Date: 30 Jun 2006
Engineering, Master in Science, École Polytechnique
1 Sep 2002 → 30 Jun 2005
Award Date: 30 Jun 2005
Keywords
- Catalysis
- Polymers
- Metal complexes
- Sustainability
- Chemistry
- Computational chemistry
- Carbohydrates
- Monomers
- Carbon Dioxide
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- 1 Similar Profiles
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UR Fellowship - Sugar-based Polymers for a New Generation of Sustainable Materials
1/10/17 → 30/09/22
Project: Research council
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A functional xylose polymer platform for sustainable plastics and biomaterials
1/10/18 → 31/03/24
Project: Research council
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URF Renewal 2022 - Sugar-based Polymers as Polysaccharide and Glycan Mimics
1/10/22 → 30/09/25
Project: Research council
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A Highly Active and Selective Zirconium-Based Catalyst System for the Industrial Production of Poly(lactic acid)
Buchard, A., Chuck, C. J., Davidson, M. G., Gobius du Sart, G., Jones, M. D., McCormick, S. N. & Russell, A. D., 17 Feb 2023, In: ACS Catalysis. 13, 4, p. 2681-2695 15 p.Research output: Contribution to journal › Article › peer-review
Open Access -
Variations around the presence and position of sulfur in sugar-derived cyclic monomers: influence on polymerisation thermodynamics, polymer sequence and thermal properties
Hardy, C., Kociok-Köhn, G. & Buchard, A., 31 Jan 2023, In: Polymer Chemistry. 14, p. 623 632 p.Research output: Contribution to journal › Article › peer-review
Open Access -
A comparative study of oxygen diffusion in PET and PEF using molecular modelling: Computational Insights into the Mechanism for Gas Transport in Bulk Polymer Systems
Lightfoot, J., Castro Dominguez, B., Parker, S. & Buchard, A., 25 Jan 2022, In: Macromolecules. 55, 2, p. 498-510 13 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile43 Downloads (Pure) -
Chemical Recycling of Poly(Cyclohexene Carbonate) Using a Di-MgII Catalyst
Singer, F. N., Deacy, A. C., McGuire, T. M., Williams, C. K. & Buchard, A., 27 Jun 2022, In: Angewandte Chemie (International ed. in English). 61, 26, e202201785.Research output: Contribution to journal › Article › peer-review
Open Access -
Crosslinked xylose-based polyester as a bio-derived and degradable solid polymer electrolyte for Li+-ion conduction
Oshinowo, M., Runge, J., Piccini, M., Marken, F. & Buchard, A., 28 Mar 2022, In: Journal of Materials Chemistry A. 10, 12, p. 6796-6808 13 p.Research output: Contribution to journal › Article › peer-review
Open Access
Datasets
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DFT Modelling of the Propagation Step in the ROP of a mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sep 2016
DOI: 10.6084/m9.figshare.3470105
Dataset
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DFT Modelling of Ring-opening Thermodynamics of mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sep 2016
DOI: 10.6084/m9.figshare.3469373, https://doi.org/10.6084/m9.figshare.3469283
Dataset
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DFT Modelling of the Initiation Step in the ROP of a mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sep 2016
DOI: 10.6084/m9.figshare.3469466
Dataset
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Advanced optimisations of fac-mer and trans-meso isomers of Zr(3)(OiPr)2
Buchard, A. (Creator), Jones, M. (Project Leader) & McKeown, P. (Project Member), Figshare, 6 Oct 2014
DOI: 10.6084/m9.figshare.1190538, http://dx.doi.org/10.6084/m9.figshare.1190538
Dataset
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DFT study of the oxidation of primary alcohols by TEMPO+ cation in presence of NaCO3- buffer: deprotonation/cyclic intermediate pathway
Buchard, A. (Creator), Figshare, 23 Apr 2016
DOI: 10.6084/m9.figshare.3079966, https://figshare.com/articles/DFT_study_of_the_oxidation_of_primary_alcohols_by_TEMPO_cation_in_presence_of_NaCO3_buffer_deprotonation_cyclic_intermediate_pathway/3079966 and one more link, http://onlinelibrary.wiley.com/doi/10.1002/elan.201600141/abstract (show fewer)
Dataset