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Personal profile

Research interests

My research focuses on the discovery of novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers.

Research projects in our group include:

  • Small molecules (e.g. CO2, H2O) activation and transformation
  • Carbohydrate chemistry and catalysis
  • Synthesis of novel monomers and polymers from renewable resources, in particular sugars
  • Organic and inorganic catalyst design
  • Polymerisation catalysis
  • Computational chemistry (Density Functional Theory Modelling) for mechanistic studies
  • Application of sustainable polymers (3D printing, medicine, elastomers, catalysis...)

Why?

Polymers (the molecules of plastics) are today everywhere, and there lies the problem, as their dependence on depleting fossil-fuel resources and their environmental persistence make them unsustainable. To develop sustainable polymers that are cost- and performance-competitive with the dominating oil-based polymers is a major challenge to achieve a circular and sustainable economy of plastics. Towards that goal, catalysis is a central enabling technology to develop 1) new monomers from renewable feedstock, 2) more efficient routes to produce related polymeric materials, capable of substituting petrochemicals and 3) novel end-of life options for these polymers.

Group website

www.buchardgroup.org

Biography

Originally from France, Antoine obtained his PhD from the Ecole Polytechnique in 2009, under the supervision of Prof Pascal Le Floch. He then moved to the UK and worked at Imperial College London as a postdoctoral research assistant in the group of Prof Charlotte K. Williams, in the area of CO2/epoxide copolymers and poly(lactic acid). Antoine returned to France in 2011 and gained industrial R&D experience, working for Air Liquide on Carbon Capture, Storage and Utilisation (CCSU) projects. In April 2013 Antoine began his independent research career at the CSCT as a Whorrod Research Fellow, investigating novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers. In October 2017 Antoine was awarded a Royal Society University Research Fellowship.

Education/Academic qualification

Chemistry, Doctor of Science, École Polytechnique

25 Sep 200625 Sep 2009

Chemistry, Master of Research, École Polytechnique

1 Sep 200530 Jun 2006

Engineering, Master in Science, École Polytechnique

1 Sep 200230 Jun 2005

Keywords

  • Catalysis
  • Polymers
  • Metal complexes
  • Sustainability
  • Chemistry
  • Computational chemistry
  • Carbohydrates
  • Monomers
  • Carbon Dioxide

Fingerprint Fingerprint is based on mining the text of the person's scientific documents to create an index of weighted terms, which defines the key subjects of each individual researcher.

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Projects 2016 2023

Research Output 2007 2018

Ring opening polymerization
Aluminum
polymerization
Ligands
aluminum
Open Access
File
Lanthanoid Series Elements
Bearings (structural)
Thermodynamic properties
Polymerization
Nuclear magnetic resonance

Electrochemically Driven C-H Hydrogen Abstraction Processes with the Tetrachloro-Phthalimido-N-Oxyl (Cl4PINO) Catalyst

Marken, F., Buckingham, M. A., Bull, S., Cunningham, W., Buchard, A., Folli, A. & Murphy, D., 1 Aug 2018, In : Electroanalysis. 30, 8, p. 1706-1713

Research output: Contribution to journalArticle

Hydrogen
Alcohols
Catalysts
Rate constants
Oxidation

Mechanism of CO 2 capture in nanostructured sodium amide encapsulated in porous silica

Tian, M., Buchard, A., Wells, S. A., Fang, Y., Torrente-murciano, L., Nearchou, A., Dong, Z., White, T. J., Sartbaeva, A. & Ting, V. P., 25 Sep 2018, In : Surface & Coatings Technology. 350, p. 227-233 7 p.

Research output: Contribution to journalArticle

Carbon Monoxide
Encapsulation
Amides
Silicon Dioxide
amides
1 Citations

Polymers from sugars and CS2: synthesis and ring-opening polymerisation of sulfur-containing monomers derived from 2-deoxy- d-ribose and d-xylose

López-vidal, E. M., Gregory, G. L., Kociok-Kohn, G. & Buchard, A., 7 Apr 2018, In : Polymer Chemistry. 9, p. 1577-1582

Research output: Contribution to journalArticle

Open Access
Xylose
Ribose
Ring opening polymerization
Sulfur
Sugars