Projects per year
Personal profile
Research interests
My research focuses on the discovery of novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers.
Research projects in our group include:
- Small molecules (e.g. CO2, H2O) activation and transformation
- Carbohydrate chemistry and catalysis
- Synthesis of novel monomers and polymers from renewable resources, in particular sugars
- Organic and inorganic catalyst design
- Polymerisation catalysis
- Computational chemistry (Density Functional Theory Modelling) for mechanistic studies
- Application of sustainable polymers (3D printing, packaging, elastomers, battery electrolytes, catalysis, health materials...)
Why?
Polymers (the molecules of plastics) are today everywhere, and there lies the problem, as their dependence on depleting fossil-fuel resources and their environmental persistence make them unsustainable. To develop sustainable polymers that are cost- and performance-competitive with the dominating oil-based polymers is a major challenge to achieve a circular and sustainable economy of plastics. Towards that goal, catalysis is a central enabling technology to develop 1) new monomers from renewable feedstock, 2) more efficient routes to produce related polymeric materials, capable of substituting petrochemicals and 3) novel end-of life options for these polymers.
Group website
Biography
Originally from France, Antoine obtained his PhD from the Ecole Polytechnique in 2009, under the supervision of Prof Pascal Le Floch. He then moved to the UK and worked at Imperial College London as a postdoctoral research assistant in the group of Prof Charlotte K. Williams, in the area of CO2/epoxide copolymers and poly(lactic acid). Antoine returned to France in 2011 and gained industrial R&D experience, working for Air Liquide on Carbon Capture, Storage and Utilisation (CCSU) projects. In April 2013 Antoine began his independent research career at the CSCT as a Whorrod Research Fellow, investigating novel chemical transformations and use in catalysis of renewable resources, in particular for the synthesis of sustainable polymers. In October 2017 Antoine was awarded a Royal Society University Research Fellowship.
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
Education/Academic qualification
Chemistry, Doctor of Science, Iminophosphoranes coordination chemistry and development of new catalytic systems, École Polytechnique
25 Sept 2006 → 25 Sept 2009
Award Date: 25 Sept 2009
Chemistry, Master of Research, Rhodium-catalysed acylation of vinyl silanes with acid anhydrides, École Polytechnique
1 Sept 2005 → 30 Jun 2006
Award Date: 30 Jun 2006
Engineering, Master in Science, Diplôme d'ingénieur de l'Ecole Polytechnique, École Polytechnique
1 Sept 2002 → 30 Jun 2005
Award Date: 30 Jun 2005
Keywords
- Catalysis
- Polymers
- Metal complexes
- Sustainability
- Chemistry
- Computational chemistry
- Carbohydrates
- Monomers
- Carbon Dioxide
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- 1 Similar Profiles
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UR Fellowship - Sugar-based Polymers for a New Generation of Sustainable Materials
1/10/17 → 30/09/22
Project: Research council
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A functional xylose polymer platform for sustainable plastics and biomaterials
1/10/18 → 31/03/24
Project: Research council
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Catalytic Chemical Sorting of Intractably Mixed Plastics
Engineering and Physical Sciences Research Council
1/10/23 → 30/09/26
Project: Research council
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A Highly Active and Selective Zirconium-Based Catalyst System for the Industrial Production of Poly(lactic acid)
Buchard, A., Chuck, C. J., Davidson, M. G., Gobius du Sart, G., Jones, M. D., McCormick, S. N. & Russell, A. D., 17 Feb 2023, In: ACS Catalysis. 13, 4, p. 2681-2695 15 p.Research output: Contribution to journal › Article › peer-review
Open Access3 Citations (SciVal) -
A molecular dynamics approach to modelling oxygen diffusion in PLA and PLA clay nanocomposites
Lightfoot, J., Castro Dominguez, B., Buchard, A. & Parker, S. C., 24 Apr 2023, (E-pub ahead of print) In: Materials Advances. 4, 10, p. 2281-2291 11 p.Research output: Contribution to journal › Article › peer-review
Open Access -
Catalysts for the Depolymerisation of Degradable and Sustainable Polymers
Singer, F., Buchard, A. & Williams, C. K., 8 Mar 2023, Modern Developments in Catalysis: Volume 2. Hutchings, G., Davidson, M., Catlow, R., Turner, N., Williams, C., Mulholland, A., Goodall, J. & Mitchell, C. (eds.). Singapore: World Scientific Publishing Co. Pte Ltd, p. 491-534 44 p.Research output: Chapter or section in a book/report/conference proceeding › Chapter or section
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Chemical Recycling of Commercial Poly(l-lactic acid) to l-Lactide Using a High-Performance Sn(II)/Alcohol Catalyst System
McGuire, T. M., Buchard, A. & Williams, C., 13 Sept 2023, In: Journal of the American Chemical Society. 145, 36, p. 19840-19848 9 p.Research output: Contribution to journal › Article › peer-review
Open Access -
Coordination of ϵ-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination-Insertion
Buchard, A., Davidson, M. G., Gobius du Sart, G., Jones, M. D., Kociok-Köhn, G., McCormick, S. N. & Mckeown, P., 25 Sept 2023, In: Inorganic Chemistry. 62, 38, p. 15688–15699 12 p.Research output: Contribution to journal › Article › peer-review
Open Access
Datasets
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DFT Modelling of the Initiation Step in the ROP of a mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sept 2016
DOI: 10.6084/m9.figshare.3469466
Dataset
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DFT Modelling of the Propagation Step in the ROP of a mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sept 2016
DOI: 10.6084/m9.figshare.3470105
Dataset
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DFT Modelling of Ring-opening Thermodynamics of mannose-based cyclic carbonate
Buchard, A. (Creator) & Gregory, G. (Creator), University of Bath, 21 Sept 2016
DOI: 10.6084/m9.figshare.3469373, https://doi.org/10.6084/m9.figshare.3469283
Dataset
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DFT study of the tosylation and cyclisation steps in the synthesis of cyclic carbonate (R)-4-Methyl-[1,3]-dioxan-2-one from CO2 and (R)-1,3-butanediol
Buchard, A. (Creator) & Gregory, G. (Creator), Figshare, 12 Mar 2015
DOI: 10.6084/m9.figshare.1333544
Dataset
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Advanced optimisations of fac-mer and trans-meso isomers of Zr(3)(OiPr)2
Buchard, A. (Creator), Jones, M. (Project Leader) & McKeown, P. (Project Member), Figshare, 6 Oct 2014
DOI: 10.6084/m9.figshare.1190538, http://dx.doi.org/10.6084/m9.figshare.1190538
Dataset