Description
Synthetic K+ chabazite (KCHA), Cs+ chabazite (CsCHA) and Zn2+ chabazite (ZnCHA) were synthesized and compared in order to relate the differences in their crystalline structures to their thermal stability (TGA data), moisture content (TGA data) and frequency dependent alternating current (AC) conductivity (AC conductivity heating and cooling data), permittivity (permittivity heating and cooling data) and phase angle (phase angle heating and cooling data) at a range of temperatures. Cation migration activation energies for KCHA (0.66 ± 0.10) eV, CsCHA (0.88 ± 0.01) eV and ZnCHA (0.90 ± 0.01) eV were determined (activation energy data). Good thermal stability of the materials was observed up to 710 °C (TGA data) and below 200 °C the electrical properties were strongly influenced by hydration level (conductivity, permittivity and phase angle data). Overall, it was determined that when either hydrated or dehydrated, KCHA had the highest conductivity and lowest cation migration activation energy of the three studied chabazites (activation energy data).
| Date made available | 23 Nov 2017 |
|---|---|
| Publisher | University of Bath |
| Date of data production | 2017 |
Research output
- 1 Article
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Understanding the AC conductivity and permittivity of trapdoor chabazites for future development of next-generation gas sensors
Bordeneuve, H., Wales, D. J., Physick, A. J. W., Doan, H. V., Ting, V. P. & Bowen, C. R., 1 Apr 2018, In: Microporous and Mesoporous Materials. 260, p. 208-216 9 p.Research output: Contribution to journal › Article › peer-review
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Projects
- 3 Finished
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NEMESIS:Novel Energy Materials: Engineering Science and Integrated Systems
Bowen, C. (PI)
1/02/13 → 31/12/18
Project: EU Commission
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Materials for Energy Efficient Transport (MEET) - InterReg ERDF Funding
Chaudhuri, J. (PI), Allsopp, D. (CoI), Bowen, C. (CoI), Burrows, A. (CoI), Butler, R. (CoI), Edler, K. (CoI), Islam, S. (CoI), Mays, T. (CoI) & Meo, M. (CoI)
Engineering and Physical Sciences Research Council
1/09/12 → 31/01/13
Project: Research council
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UK SUSTAINABLE HYDROGEN ENERGY CONSORTIUM CORE PROGRAMME
Mays, T. (PI)
Engineering and Physical Sciences Research Council
1/07/07 → 30/06/12
Project: Research council
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